5 results on '"negative poisson ratio"'
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2. MECHANICAL AND STRUCTURAL PROPERTIES OF POLY(PHENYLETHYLENE) SYSTEMS: A PRELIMINARY STUDY
- Author
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ZACHARY FARRUGIA and JOSEPH N. GRIMA
- Subjects
auxetics ,negative Poisson ratio ,organic networked polymers ,Information technology ,T58.5-58.64 - Abstract
The structural and mechanical properties of various types of poly(phenylacetylene) crystalline networked polymers which stack in the third direction in a graphite-like manner have been the subject of extensive research over the past few years. These studies have suggested that depending on the particular manner of substitution of the phenyls, it is possible to achieve some very interesting mechanical properties, which include, in some cases, negative Poisson’s ratio (NPR) and/or negative linear compressibility (NLC). The current study investigated how alternatives to these systems can be designed, and specifically tailor-made to exhibit desirable anomalous properties, such as NPR and NLC, through the replacement of the acetylene chains with ethylene chains, so as to produce the poly(phenylethylene) equivalents. Using force field-based simulations, via the use of the polymer consistent force-field (PCFF) it was noted that, to a first approximation, these systems mirror some of the analogous properties exhibited by their poly(phenylacetylene) counterparts. In particular, poly(phenylethylene) systems built from 1234- and 1245-substituted phenyls exhibited negative Poisson’s ratios, with the latter also exhibiting negative linear compressibility. This anomalous behaviour, mirrors, to some extent, that exhibited by their poly(phenylacetylene) counterparts, albeit some differences were noted, such as a reduction in the degrees of auxeticity. It was also noted that the poly(phenylethylene) systems modelled here tend to stack in the third direction, in a different manner than their poly(phenylacetylene) analogues, which difference is likely to be the factor for such reduction in auxeticity.
- Published
- 2019
- Full Text
- View/download PDF
3. Revealing rutherfordine mineral as an auxetic material
- Author
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Francisco Colmenero
- Subjects
Materials science ,Auxetics ,Uranyl-containing material ,Plane wave ,Mechanical properties ,02 engineering and technology ,mechanical properties ,010402 general chemistry ,01 natural sciences ,lcsh:Technology ,negative poisson ratio ,Uranyl carbonate ,lcsh:Chemistry ,chemistry.chemical_compound ,symbols.namesake ,Perpendicular ,General Materials Science ,Negative poisson ratio ,Anisotropy ,Instrumentation ,lcsh:QH301-705.5 ,Fluid Flow and Transfer Processes ,Condensed matter physics ,lcsh:T ,Process Chemistry and Technology ,General Engineering ,021001 nanoscience & nanotechnology ,Poisson's ratio ,lcsh:QC1-999 ,0104 chemical sciences ,Computer Science Applications ,chemistry ,lcsh:Biology (General) ,lcsh:QD1-999 ,lcsh:TA1-2040 ,Rutherfordine ,symbols ,Density functional theory ,0210 nano-technology ,lcsh:Engineering (General). Civil engineering (General) ,lcsh:Physics - Abstract
The mechanical behavior of the uranyl carbonate mineral, rutherfordine, UO2CO3, was studied by means of theoretical solid-state methods based in Density Functional Theory using plane waves and pseudopotentials. The results of the computations reported in this work show that this mineral exhibits the important negative Poisson ratio (NPR) phenomenon. In order to show that this feature is not an artifact associated to the theoretical treatment employed, additional calculations were carried out using very large calculation parameters. These calculations improved the mechanical description of this mineral and confirmed its auxeticity, i.e., it shows NPR values. Rutherfordine is a highly anisotropic material showing a maximum value of the NPR of the order of &minus, 0.3 ±, 0.1 for applied stresses directed along the X axis, the transverse direction being the Y axis perpendicular to the structural sheets in rutherfordine structure. The underlying reason for this observation is that under the effect of applied positive pressures, the interlayer space between the sheets of rutherfordine vary in the opposite way to the expected behavior, that is, it decreases instead of increasing.
- Published
- 2018
4. Behavior of Elastoplastic Auxetic Microstructural Arrays
- Author
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Rivka Gilat and Jacob Aboudi
- Subjects
Materials science ,Auxetics ,Composite number ,homogenization ,Poisson distribution ,lcsh:Technology ,negative Poisson ratio ,Homogenization (chemistry) ,Article ,symbols.namesake ,General Materials Science ,microstructural architectures ,composite ,Composite material ,lcsh:Microscopy ,lcsh:QC120-168.85 ,lcsh:QH201-278.5 ,lcsh:T ,business.industry ,Structural engineering ,Physics::Classical Physics ,Microstructure ,Micromechanical model ,lcsh:TA1-2040 ,symbols ,lcsh:Descriptive and experimental mechanics ,lcsh:Electrical engineering. Electronics. Nuclear engineering ,lcsh:Engineering (General). Civil engineering (General) ,business ,lcsh:TK1-9971 - Abstract
A continuum-based micromechanical model is employed for the prediction of the elasto-plastic behavior of periodic microstructural arrays that can generate negative values of Poisson’s ratios. The combined effects of the negative Poisson’s ratio generated by the array microstructure and the elastoplastic behavior of the constituents are studied. A design methodology for the determination of the constituents’ properties of two-phase arrays that generate required values of negative Poisson’s ratio is considered.
- Published
- 2013
- Full Text
- View/download PDF
5. Wave Propagation in Auxetic Tetrachiral Honeycombs
- Author
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Kong Fah Tee, Massimo Ruzzene, Alessandro Spadoni, and Fabrizio Scarpa
- Subjects
Behavior ,Materials science ,Auxetics ,Wave propagation ,Modal Densities ,General Engineering ,Systems ,Tangent ,Geometry ,Finite-Element ,Sandwich panel ,Poisson's ratio ,Periodic Structures ,symbols.namesake ,Honeycomb structure ,Negative Poisson Ratio ,symbols ,Honeycomb ,Composite material ,Bloch wave - Abstract
This paper describes a numerical and experimental investigation on the flexural wave propagation properties of a novel class of negative Poisson's ratio honeycombs with tetrachiral topology. Tetrachiral honeycombs are structures defined by cylinders connected by four tangent ligaments, leading to a negative Poisson's ratio (auxetic) behavior in the plane due to combined cylinder rotation and bending of the ribs. A Bloch wave approach is applied to the representative unit cell of the honeycomb to calculate the dispersion characteristics and phase constant surfaces varying the geometric parameters of the unit cell. The modal density of the tetrachiral lattice and of a sandwich panel having the tetrachiral as core is extracted from the integration of the phase constant surfaces, and compared with the experimental ones obtained from measurements using scanning laser vibrometers. [DOI: 10.1115/1.4000785]
- Published
- 2010
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