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A better understanding of background tropospheric ozone delivers multiple benefits. Robust estimates of regional background ozone are required to understand the limits of anthropogenic emissions controlling ozone reduction. Long-term estimates of background ozone assist in characterising changes in atmospheric composition and can help quantify the influence of human activity on the atmosphere. Background tropospheric ozone measurements representative of continental air masses are scarce in Australia. Here, we use k-means clustering to identify a cluster of measurements from the long-term air quality monitoring station at Oakdale, NSW, which are likely to be representative of background air. The cluster is associated with NOx-limited air masses of continental origin. From this analysis, we estimate background ozone representative of Eastern Australia. We find recent (2017–2022) mean ozone mixing ratios of 28.5 ppb and identify a statistically significant (α = 0.05) trend in the mean of +1.8 (1.0–2.8) ppb/decade. Our methods demonstrate that some long-term monitoring stations within or near urban areas can provide suitable conditions and datasets for regional Global Atmosphere Watch monitoring. [ABSTRACT FROM AUTHOR]