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Your search keyword '"Jarava‐Barrera, Carlos"' showing total 1 results
Start Over Author "Jarava‐Barrera, Carlos" Topic asymmetric synthesis
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1. Highly Enantioselective Construction of Tricyclic Derivatives by the Desymmetrization of Cyclohexadienones.

Author

Martín ‐ Santos, Cecilia, Jarava ‐ Barrera, Carlos, del Pozo, Sandra, Parra, Alejandro, Díaz ‐ Tendero, Sergio, Mas ‐ Ballesté, Rubén, Cabrera, Silvia, and Alemán, José

Subjects
*CYCLOHEXADIENONES, *ENANTIOSELECTIVE catalysis, *ASYMMETRIC synthesis, *HETEROCYCLIC compound derivatives, *RING formation (Chemistry), *DENSITY functional theory
Abstract

The asymmetric synthesis of tricyclic compounds by the desymmetrization of cyclohexadienones is presented. The reaction tolerated a large variety of substituents at different positions of the cyclohexadienone, and heterocyclic rings of different sizes were accessible. Density functional theory calculations showed that the reaction proceeds through an asynchronous [4+2] cycloaddition. [ABSTRACT FROM AUTHOR]

Published
2014
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