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Start Over Author "Kamlar, Martin" Topic asymmetric synthesis Topic enantioselective catalysis
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1. Asymmetric Allylic Amination of Morita–Baylis–Hillman Carbonates with Silylated tert-Butylhydroxycarbamate Derivatives.

Author

Kamlar, Martin, Císařová, Ivana, Hybelbauerová, Simona, and Veselý, Jan

Subjects
*ALLYLIC amination, *BAYLIS-Hillman reaction, *CARBONATES, *CARBAMATE derivatives, *ORGANOCATALYSIS, *ENANTIOSELECTIVE catalysis
Abstract

The enantioselective amination of Morita–Baylis–Hillman carbonates with silylated derivatives of tert-butylhydroxycarbamates using β-isocupreidine as an organocatalyst was investigated. The corresponding products were obtained in good yields with high enantioselectivities. The scope and limitations of the reported protocol were explored, and representative transformations of the adducts toward heterocyclic compounds were highlighted. [ABSTRACT FROM AUTHOR]

Published
2017
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