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Binary systems made by a low-mass CO WD and a He-donor represent possible progenitors of explosive events via He-detonation, producing low-luminosity thermonuclear Supernovae with a peculiar nucleosynthetis. Recently, the binary system PTF J223857.11+743015.1 has been suggested as one. We investigate the evolution of the PTF J223857.11+743015.1 system, composed by a 0.75Msun CO WD and a 0.390Msun subdwarf, capped by a thin H-rich layer, considering rotation of the WD component. We compute the evolution of two stars simultaneously, accounting for the possible evolution of the orbital parameters, as determined by mass transfer between components and by mass ejection from the system during RLOF episodes. We consider that the WD gains angular momentum due to accretion and we follow the evolution of the angular velocity profile as due to angular momentum transport via convection and rotation-induced instabilities. As the donor H-rich envelope is transferred, the WD experiences recurrent very strong H-flashes triggering RLOF episodes during which the entire accreted matter is lost from the system. Due to mixing of chemicals by rotation-induced instabilities during the accretion phase, H-flashes occur inside the original WD. Hence, pulse-by pulse, the accretor mass is reduced down to 0.7453Msun. When He-rich matter is transferred, He-detonation does not occur in the rotating WD, which undergoes 6 very strong He-flashes and subsequent RLOF episodes. Also in this case, due to rotation-induced mixing of the accreted layers with the underlying core, the WD is eroded. Finally, when the mass transfer rate from the donor decreases, a massive He-buffer is piled-up onto the accretor which ends its life as a cooling WD. The binary system PTF J2238+743015.1 as all those binaries having similar components masses and orbital parameters are not good candidates as thermonuclear explosions progenitors., Comment: 12 Pages, 9 Figures, 3 Tables. Accepted for the publication on A&A

The nature of Type Ia Supernova (SN Ia) explosions remains an open issue, with several contending progenitor scenarios actively being considered. One such scenario involves a SN Ia explosion inside a planetary nebula (PN) in the aftermath of a stellar merger triggered by a common envelope (CE) episode. We examine this scenario using hydrodynamic and non-equilibrium ionization simulations of the interaction between the SN ejecta and the PN cocoon into the supernova remnant (SNR) phase, focusing on the impact of the delay between the CE episode and the SN explosion. We compare the bulk dynamics and X-ray spectra of our simulated SNRs to the observed properties of known Type Ia SNRs in the Milky Way and the Magellanic Clouds. We conclude that models where the SN explosion happens in the immediate aftermath of the CE episode (with a delay $\lesssim$1,000 yr) are hard to reconcile with the observations, because the interaction with the dense PN cocoon results in ionization timescales much higher than those found in any known Type Ia SNR. Models with a longer delay between the CE episode and the SN explosion ($\sim$10,000 yr) are closer to the observations, and may be able to explain the bulk properties of some Type Ia SNRs., Comment: 9 pages, 5 figures

The precise progenitor system of type Ia supernovae (SNe Ia), whether it is a white dwarf (WD) close to the Chandrasekhar limit or substantially less massive, has been a matter of debate for decades. Recent research by our group on the accretion and simmering phases preceding the explosion of a massive WD has shown that the central density at thermal runaway lies in the range $(3.6-6.3)\times10^9$ g cm$^{-3}$ for reasonable choices of accretion rate onto the WD and progenitor metallicity. In this work, we have computed one-dimensional simulations of the explosion of such WDs, with special emphasis on the chemical composition of the ejecta, which in all cases is extremely rich in neutronized isotopes of chromium ($^{54}$Cr) and titanium ($^{50}$Ti). We show that, in order to reconcile such a nucleosynthesis with the isotopic abundances of the Solar System, Chandrasekhar-mass white dwarfs can account for at most 26 per cent of normal-luminosity SNe Ia, or at most 20 per cent of all SNe Ia., Comment: 5 pages, 1 table, 3 figures; Letter accepted by MNRAS

The detection of the very early gamma-emission of a Type Ia supernova (SNIa) could provide a deep insight on the explosion mechanism and nature of the progenitor. However this has not been yet possible as a consequence of the expected low luminosity and the distance at which all the events have occurred up to now. A SNIa occurring in our Galaxy could provide a unique opportunity to perform such measurement. The problem is that the optical flux would probably be so attenuated by interstellar extinction that would prevent triggering the observations with gamma-spectrometers at the due time. In this paper we analyse the possibility of using the anticoincidence system (ACS) of the spectrometer SPI on board of the INTEGRAL space observatory for detecting the early gamma-ray emission of a SNIa as a function of the explosion model and distance as well as of pointing direction. Our results suggest that such detection is possible at about 6 - 12 days after the explosion and, at the same time, we can discard missing any hidden explosion during the lifetime of INTEGRAL.

In accreting WDs approaching the Chandrasekhar limit, hydrostatic carbon burning precedes the dynamical breakout. During this \textit{simmering} phase, $e-$captures are energetically favored in the central region of the star, while $\beta-$decays are favored more outside, and the two zones are connected by a growing convective instability. We analyze the interplay between weak interactions and convection, the so-called convective URCA process, during the simmering phase of SNe Ia progenitors and its effects on the physical and chemical properties at the explosion epoch. At variance with previous studies, we find that the convective core powered by the carbon burning remains confined within the ${^{21}(Ne,F)}$ URCA shell. As a result, a much larger amount of carbon has to be consumed before the explosion which eventually occurs at larger density than previously estimated. In addition, we find that the extension of the convective core and its average neutronization depend on the the WD progenitor initial metallicity. For the average neutronization in the convective core at the explosion epoch we obtain ${\overline{\eta}_{exp}} = (1.094\pm 0.143)\times 10^{-3} + (9.168\pm 0.677)\times 10^{-2}\times Z$. Outside the convective core, the neutronization is instead determined by the initial amount of C+N+O in the progenitor star. Since S, Ca, Cr and Mn, the elements usually exploited to evaluate the pre-explosive neutronization, are mainly produced outside the heavily neutronized core, the problem of too high metallicity estimated for the progenitors of the historical Tycho and Kepler SNe Ia remains unsolved., Comment: Accepted for the publication on ApJ. 26 pages, 11 figures, 5 Tables. Modified acknowledgments

Recent observational evidence has demonstrated that white dwarf (WD) mergers are a highly efficient mechanism for mass accretion onto WDs in the galaxy. In this paper, we show that WD mergers naturally produce highly-magnetized, uniformly-rotating WDs, including a substantial population within a narrow mass range close to the Chandrasekhar mass ($M_{\rm Ch}$). These near-$M_{\rm Ch}$ WD mergers subsequently undergo rapid spin up and compression on a $\sim 10^2$ yr timescale, either leading to central ignition and a normal SN Ia via the DDT mechanism, or alternatively to a failed detonation and SN Iax through pure deflagration. The resulting SNe Ia and SNe Iax will have spectra, light curves, polarimetry, and nucleosynthetic yields similar to those predicted to arise through the canonical near-$M_{\rm Ch}$ single degenerate (SD) channel, but with a $t^{-1}$ delay time distribution characteristic of the double-degenerate (DD) channel. Furthermore, in contrast to the SD channel, WD merger near-$M_{\rm Ch}$ SNe Ia and SNe Iax will not produce observable companion signatures. We discuss a range of implications of these findings, from SNe Ia explosion mechanisms, to galactic nucleosynthesis of iron peak elements including manganese., Comment: 20 pages, 4 figures, nucleosynthetic yields included as ancillary data files. Accepted to The Astrophysical Journal. Comments welcome

At present, there are strong indications that white dwarf (WD) stars with masses well below the Chandrasekhar limit (MCh ~ 1.4 Msun) contribute a significant fraction of SN Ia progenitors. The relative fraction of stable iron-group elements synthesized in the explosion has been suggested as a possible discriminant between MCh and sub-MCh events. In particular, it is thought that the higher-density ejecta of MCh WDs, which favours the synthesis of stable isotopes of nickel, results in prominent [Ni II] lines in late-time spectra. We study the explosive nucleosynthesis of stable nickel in SNe Ia resulting from MCh and sub-MCh progenitors. We explore the potential for lines of [Ni II] at 7378 \AA\ and 1.94 microns in late-time spectra to serve as a diagnostic of the exploding WD mass, using nonlocal thermodynamic equilibrium radiative-transfer simulations with the CMFGEN code. We find that the radiative proton-capture reaction 57Co(p,gamma)58Ni is the dominant production mode for 58Ni in both MCh and sub-MCh models, while the alpha-capture reaction on 54Fe has a negligible impact on the final 58Ni yield. More importantly, we demonstrate that the lack of [Ni II] lines in late-time spectra of sub-MCh events is not always due to an under-abundance of stable Ni; rather, it results from the higher ionization of Ni in the inner ejecta. Conversely, the strong [Ni II] lines predicted in our 1D MCh models are completely suppressed when 56Ni is sufficiently mixed with the innermost layers, which are rich in stable iron-group elements. [Ni II] lines in late-time SN Ia spectra have a complex dependency on the abundance of stable Ni, which limits their use in distinguishing among MCh and sub-MCh progenitors. However, we argue that a low-luminosity SN Ia displaying strong [Ni II] lines would most likely result from a Chandrasekhar-mass progenitor. [Abridged], Comment: Accepted for publication in A&A, replaced with accepted version (+ corrected a typo in the conclusions: "overabundance" replaced with "over abundance"). 20 pages, 10 figures. Model spectra available at https://zenodo.org/record/5528088

{\it Chandra} X-ray observations of Kepler's supernova remnant indicate the existence of a high speed Fe-rich ejecta structure in the southwestern region. We report strong K-shell emission from Fe-peak elements (Cr, Mn, Fe, Ni), as well as Ca, in this Fe-rich structure, implying that those elements could be produced in the inner area of the exploding white dwarf. We found Ca/Fe, Cr/Fe, Mn/Fe and Ni/Fe mass ratios of 1.0--4.1\%, 1.0--4.6\%, 1--11\% and 2--30\%, respectively. In order to constrain the burning regime that could produce this structure, we compared these observed mass ratios with those in 18 one-dimensional Type Ia nucleosynthesis models (including both near-$M_{\rm Ch}$ and sub-$M_{\rm Ch}$ explosion models). The observed mass ratios agree well with those around the middle layer of incomplete Si-burning in Type Ia nucleosynthesis models with a peak temperature of $\sim$(5.0--5.3)$\times$10$^{9}$ K and a high metallicity, Z $>$ 0.0225. Based on our results, we infer the necessity for some mechanism to produce protruding Fe-rich clumps dominated by incomplete Si-burning products during the explosion. We also discuss the future perspectives of X-ray observations of Fe-rich structures in other Type Ia supernova remnants., Comment: 17 pages, 12 figures, accepted for publication in ApJ

Even though the main nucleosynthetic products of type Ia supernovae belong to the iron-group, intermediate-mass alpha-nuclei (silicon, sulfur, argon, and calcium) stand out in their spectra up to several weeks past maximum brightness. Recent measurements of the abundances of calcium, argon, and sulfur in type Ia supernova remnants have been interpreted in terms of metallicity-dependent oxygen burning, in accordance with previous theoretical predictions. It is known that $\alpha$-rich oxygen burning results from $^{16}$O$\rightarrow^{12}$C followed by efficient $^{12}$C+$^{12}$C fusion reaction, as compared to oxygen consumption by $^{16}$O fusion reactions, but the precise mechanism of dependence on the progenitor metallicity has remained unidentified so far. I show that the chain $^{16}$O(p,$\alpha$)$^{13}$N($\gamma$,p)$^{12}$C boosts $\alpha$-rich oxygen burning when the proton abundance is large, increasing the synthesis of argon and calcium with respect to sulfur and silicon. For high-metallicity progenitors, the presence of free neutrons leads to a drop in the proton abundance and the above chain is not efficient. Although the rate of $^{16}$O(p,$\alpha$)$^{13}$N can be found in astrophysical reaction rate libraries, its uncertainty is unconstrained. Assuming that all reaction rates other than $^{16}$O(p,$\alpha$)$^{13}$N retain their standard values, an increase by a factor of approximately seven of the $^{16}$O(p,$\alpha$)$^{13}$N rate at temperatures in the order $3-5\times10^9$ K is enough to explain the whole range of calcium-to-sulfur mass ratios measured in Milky Way and LMC supernova remnants. These same measurements provide a lower limit to the $^{16}$O(p,$\alpha$)$^{13}$N rate in the mentioned temperature range, on the order of a factor of 0.5 with respect to the rate reported in widely used literature tabulations., Comment: 5 pages, 6 figures, accepted for Astronomy & Astrophysics

The thermonuclear explosion of massive white dwarfs is believed to explain at least a fraction of Type Ia supernovae (SNIa). After thermal runaway, electron captures on the ashes left behind by the burning front determine a loss of pressure, which impacts the dynamics of the explosion and the neutron excess of matter. Indeed, overproduction of neutron-rich species such as $^{54}$Cr has been deemed a problem of Chandrasekhar-mass models of SNIa for a long time. I present the results of a sensitivity study of SNIa models to the rates of weak interactions, which have been incorporated directly into the hydrodynamic explosion code. The weak rates have been scaled up/down by a factor ten, either globally for a common bibliographical source, or individually for selected isotopes. In line with previous works, the impact of weak rates uncertainties on sub-Chandrasekhar models of SNIa is almost negligible. The impact on the dynamics of Chandrasekhar-mass models and on the yield of $^{56}$Ni is also scarce. The strongest effect is found on the nucleosynthesis of neutron-rich nuclei, such as $^{48}$Ca, $^{54}$Cr, $^{58}$Fe, and $^{64}$Ni. The species with the highest influence on nucleosynthesis do not coincide with the isotopes that contribute most to the neutronization of matter. Among the last ones, there are protons, $^{54,55}$Fe, $^{55}$Co, and $^{56}$Ni, while the main influencers are $^{54,55}$Mn and $^{55-57}$Fe, in disagreement with Parikh et al (2013), who found that SNIa nucleosynthesis is most sensitive to the $\beta^+$-decay rates of $^{28}$Si, $^{32}$S, and $^{36}$Ar. An eventual increase in all weak rates on pf-shell nuclei would affect the dynamical evolution of hot bubbles, running away at the beginning of the explosion, and the yields of SNIa., Comment: accepted for Astronomy and Astrophysics

Gamma-ray astronomy explores the most energetic photons in nature to address some of the most pressing puzzles in contemporary astrophysics. It encompasses a wide range of objects and phenomena: stars, supernovae, novae, neutron stars, stellar-mass black holes, nucleosynthesis, the interstellar medium, cosmic rays and relativistic-particle acceleration, and the evolution of galaxies. MeV gamma-rays provide a unique probe of nuclear processes in astronomy, directly measuring radioactive decay, nuclear de-excitation, and positron annihilation. The substantial information carried by gamma-ray photons allows us to see deeper into these objects, the bulk of the power is often emitted at gamma-ray energies, and radioactivity provides a natural physical clock that adds unique information. New science will be driven by time-domain population studies at gamma-ray energies. This science is enabled by next-generation gamma-ray instruments with one to two orders of magnitude better sensitivity, larger sky coverage, and faster cadence than all previous gamma-ray instruments. This transformative capability permits: (a) the accurate identification of the gamma-ray emitting objects and correlations with observations taken at other wavelengths and with other messengers; (b) construction of new gamma-ray maps of the Milky Way and other nearby galaxies where extended regions are distinguished from point sources; and (c) considerable serendipitous science of scarce events -- nearby neutron star mergers, for example. Advances in technology push the performance of new gamma-ray instruments to address a wide set of astrophysical questions., Comment: 14 pages including 3 figures

Current Type Ia supernova (SN Ia) models can reproduce most visible+IR+UV observations. In the X-ray band, the determination of elemental abundance ratios in supernova remnants (SNRs) through their spectra has reached enough precision to constrain SN Ia models. Mart\'inez-Rodr\'iguez et al have shown that the Ca/S mass ratio in SNRs cannot be reproduced with the standard nuclear reaction rates for a wide variety of SN Ia models, and suggested that the 12C+16O reaction rate could be overestimated by a factor as high as ten. We show that the same Ca/S ratio can be obtained by simultaneously varying the rates of the reactions 12C+16O, 12C+12C, 16O+16O, and 16O({\gamma},{\alpha})12C within the reported uncertainties. We also show that the yields of the main products of SN Ia nucleosynthesis do not depend on the details of which rates are modified, but can be parametrized by an observational quantity such as Ca/S. Using this SNR-calibrated approach, we then proceed to compute a new set of SN Ia models and nucleosynthesis for both Chandrasekhar and sub-Chandrasekhar mass progenitors with a one-dimensional hydrodynamics and nucleosynthesis code. We discuss the nucleosynthesis of the models as a function of progenitor metallicity, mass, and deflagration-to-detonation transition density. The yields of each model are almost independent on the reaction rates modified for a common Ca/S ratio., Comment: 19 pages, published in Monthly Notices of the Royal Astronomical Society (https://academic.oup.com/mnras/article-abstract/482/4/4346/5159491). Online supplemental material, tables 3 to 6 and A1 to A4, presented in the auxiliary directory included in the source of this manuscript listed under "Other formats"

Type Ia supernovae originate from the explosion of carbon-oxygen white dwarfs in binary systems, but the exact nature of their progenitors remains elusive. The bulk properties of Type Ia supernova remnants, such as the radius and the centroid energy of the Fe K$\alpha$ blend in the X-ray spectrum, are determined by the properties of the supernova ejecta and the ambient medium. We model the interaction between Chandrasekhar and sub-Chandrasekhar models for Type Ia supernova ejecta and a range of uniform ambient medium densities in one dimension up to an age of 5000 years. We generate synthetic X-ray spectra from these supernova remnant models and compare their bulk properties at different expansion ages with X-ray observations from \textit{Chandra} and \textit{Suzaku}. We find that our models can successfully reproduce the bulk properties of most observed remnants, suggesting that Type Ia SN progenitors do not modify their surroundings significantly on scales of a few pc. Ambient medium density and expansion age are the main contributors to the diversity of the bulk properties in our models. Chandrasekhar and sub-Chandrasekhar progenitors make similar predictions for the bulk remnant properties, but detailed fits to X-ray spectra have the power to discriminate explosion energetics and progenitor scenarios., Comment: 22 pages, 14 figures, published in the ApJ

A longstanding problem is identifying the elusive progenitors of Type Ia supernovae (SNe Ia), which can roughly be split into Chandraksekhar and sub-Chandrasekhar mass events. An important difference between these two cases is the nucleosynthetic yield, which is altered by the increased neutron excess in Chandrasekhar progenitors due to their pre-explosion simmering and high central density. From comparison with theoretical nucleosynthesis yields, we show that the chemical composition of the most metal-rich star in the Ursa Minor dwarf galaxy, COS 171, is dominated by nucleosynthesis from a low-metallicity, low-mass, sub-Chandrasekhar mass SN Ia. Key diagnostic abundance ratios include C/Fe, {\alpha}/Fe, Mn/Fe and Ni/Fe ratios, which could not have been produced by Chandrasekhar-mass SNe Ia, Core-Collapse Type II supernovae or Pair-Instsability supernovae. Strong deficiencies of Ni/Fe, Cu/Fe and Zn/Fe also suggest the absence of alpha-rich freeze-out nucleosynthesis, favoring low-mass WD progenitor SNe Ia. Based on comparisons of the measured Mn/Fe and Si/Fe ratios with detonation models, we estimate a WD mass near 0.95Msun. We also compare Mn/Fe and Ni/Fe ratios to the recent theoretical yields predicted by Shen et al., finding consistent results. To explain the COS 171 [Fe/H], at -1.35 dex, requires dilution of the ejecta from a single SNIa event with ~10^4 Msun of material; this is expected for a SN Ia remnant expanding into a warm interstellar medium with n~1 /cm^3. In the future, finding more stars with the unique chemical signatures we highlight here will be important for constraining the rate and environments of sub-Chandrasekhar SNe Ia., Comment: submitted to The Astrophysical Journal. 16 pages, 10 figures, 7 tables

The physical process whereby a carbon--oxygen white dwarf explodes as a Type Ia supernova (SN Ia) remains highly uncertain. The degree of neutronization in SN Ia ejecta holds clues to this process because it depends on the mass and the metallicity of the stellar progenitor, and on the thermodynamic history prior to the explosion. We report on a new method to determine ejecta neutronization using Ca and S lines in the X-ray spectra of Type Ia supernova remnants (SNRs). Applying this method to \textit{Suzaku} data of Tycho, Kepler, 3C 397 and G337.2$-$0.7 in the Milky Way, and N103B in the Large Magellanic Cloud, we find that the neutronization of the ejecta in N103B is comparable to that of Tycho and Kepler, which suggests that progenitor metallicity is not the only source of neutronization in SNe Ia. We then use a grid of SN Ia explosion models to infer the metallicities of the stellar progenitors of our SNRs. The implied metallicities of 3C 397, G337.2$-$0.7, and N103B are major outliers compared to the local stellar metallicity distribution functions, indicating that progenitor metallicity can be ruled out as the origin of neutronization for these SNRs. Although the relationship between ejecta neutronization and equivalent progenitor metallicity is subject to uncertainties stemming from the $^{12}$C$\,$+$^{16}$O reaction rate, which affects the Ca/S mass ratio, our main results are not sensitive to these details., Comment: 12 pages, 7 figures, accepted for publication in the ApJ

The ultimate understanding of Type Ia Supernovae diversity is one of the most urgent issues to exploit thermonuclear explosions of accreted White Dwarfs (WDs) as cosmological yardsticks. In particular, we investigate the impact of the progenitor system metallicity on the physical and chemical properties of the WD at the explosion epoch. We analyze the evolution of CO WDs through the accretion and simmering phases by using evolutionary models based on time-dependent convective mixing and an extended nuclear network including the most important electron captures, beta decays and URCA processes. We find that, due to URCA processes and electron-captures, the neutron excess and density at which the thermal runaway occurs are substantially larger than previously claimed. Moreover, we find that the higher the progenitor metallicity, the larger the neutron excess variation during the accretion and simmering phases and the higher the central density and the convective velocity at the explosion. Hence, the simmering phase acts as an amplifier of the differences existing in SNe Ia progenitors. When applying our results to the neutron excess estimated for the Tycho and Kepler young Supernova remnants, we derive that the metallicity of the progenitors should be in the range Z=0.030-0.032, close to the average metallicity value of the thin disk of the Milky Way. As the amount of ${^{56}}$Ni produced in the explosion depends on the neutron excess and central density at the thermal runaway, our results suggest that the light curve properties depend on the progenitor metallicity., Comment: 7 pages, 3 figures, 2 tables, accepted for the publication on ApJ Letter

X-ray observations of supernova remnants (SNRs) allow us to investigate the chemical inhomogeneity of ejecta, offering unique insight into the nucleosynthesis in supernova explosions. Here we present detailed imaging and spectroscopic studies of the "Fe knot" located along the eastern rim of the Type Ia SNR Tycho (SN 1572) using Suzaku and Chandra long-exposure data. Surprisingly, the Suzaku spectrum of this knot shows no emission from Cr, Mn, or Ni, which is unusual for the Fe-rich regions in this SNR. Within the framework of the canonical delayed-detonation models for SN Ia, the observed mass ratios M_Cr/M_Fe < 0.023, M_Mn/M_Fe < 0.012, and M_Ni/M_Fe < 0.029 (at 90% confidence) can only be achieved for a peak temperature of (5.3-5.7) x 10^9 K and a neutron excess of < 2.0 x 10^-3. These constraints rule out the deep, dense core of a Chandrasekhar-mass white dwarf as the origin of the Fe knot, and favors either incomplete Si burning or the alpha-rich freeze-out regime, probably close to their boundary. An explosive He burning regime is a possible alternative, although this hypothesis is in conflict with the main properties of this SNR., Comment: 13 pages, 13 figures, accepted for publication in ApJ

Despite decades of intense efforts, many fundamental aspects of Type Ia supernova (SNe Ia) remain elusive. One of the major open questions is whether the mass of the exploding white dwarf (WD) is close to the Chandrasekhar limit. Here we report the detection of strong K-shell emission from stable Fe-peak elements in the Suzaku X-ray spectrum of the Type Ia supernova remnant (SNR) 3C 397. The high Ni/Fe and Mn/Fe mass ratios (0.11-0.24 and 0.018-0.033, respectively) in the hot plasma component that dominates the K-shell emission lines indicate a degree of neutronization in the SN ejecta which can only be achieved by electron captures in the dense cores of exploding WDs with a near-Chandrasekhar mass. This suggests a single-degenerate origin for 3C 397, since Chandrasekhar mass progenitors are expected naturally if the WD accretes mass slowly from a companion. Together with other results supporting the double-degenerate scenario, our work adds to the mounting evidence that both progenitor channels make a significant contribution to the SN Ia rate in star-forming galaxies., Comment: Accepted by ApJL; 6 pages with 4 figures and 1 table

We have performed deep X-ray observations of the remnant of Kepler's supernova (SN 1604) as a Key Project of the Suzaku Observatory. Our main goal is to detect secondary Fe-peak elements in the SN ejecta to gain insights into the Type Ia supernova explosion mechanism and the nature of the progenitor. Here we report our initial results. We made a conclusive detection of X-ray emission lines from highly ionized Mn, Cr, and Ni as well as Fe. The observed Mn-to-Cr line flux ratio is ~0.60, ~30% larger than that measured in Tycho's remnant. We estimate a Mn-to-Cr mass ratio of ~0.77, which is strongly suggestive of a large neutron excess in the progenitor star before the onset of the thermonuclear runaway. The observed Ni-to-Fe line flux ratio (~0.03) corresponds to a mass ratio of ~0.06, which is generally consistent with the products of explosive Si-burning regime in Type Ia explosion models, and rules out contamination from the products of neutron-rich nuclear statistical equilibrium in the shocked ejecta. Together with the previously suggested luminous nature of the explosion, these mass ratios provide strong evidence for a super-solar metallicity in the SN progenitor (~3 Z_sun). Kepler's supernova was likely the thermonuclear explosion of a white dwarf formed in the recent past that must have exploded through a relatively prompt channel., Comment: Total 12 pages including 2 tables and 2 color figures. Accepted by ApJL