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The accretion/ejection processes in T-Tauri stars are fundamental to their physical evolution, while also impacting the properties and evolution of the circumstellar material at a time when planet formation takes place. To this date, characterization of ongoing accretion processes in stellar pairs at 5-50\,au scales has been challenging, high angular resolution spectrographs are required to extract the spectral features of each component. We present the analysis of spectroscopic observations of the tight (160mas, 25au) T-Tauri system HT Lup A/B, obtained with MUSE at VLT in March and July of 2021. We focus on constraining the accretion/ejection processes and variability of the secondary component HT Lup B, by searching for accretion tracers applying High-Resolution Spectral Differential Imaging techniques. We retrieve strong (SNR $>$ 5) $H\alpha, H\beta$ and [OI]$\lambda6300$ emission in both epochs. The $H\alpha$ and $H\beta$ line fluxes showcase high variability, with variations up to 400-500\% between epochs. The fluxes are consistent with accretion rates of $8\times10^{-9} M_\odot \, yr^{-1}$ and $2\times10^{-9} M_\odot \, yr^{-1}$ for the first and second epoch, respectively. We attribute the increased accretion activity during the first night to a "burst" like event, followed by a relaxation period more representative of the common accretion activity of the system. The [OI]$\lambda6300$ line profiles remain relatively similar between epochs and suggest ejection rates on the order of $10^{-9}-10^{-10} M_\odot \, yr^{-1}$, compatible with moderate disk winds emission. Our results also indicate that the accretion processes of HT Lup B are compatible with Classical T Tauri Stars, unlike previous classifications, Comment: 28 pages, 13 fgures, Accepted by ApJ

Characterizing the chemistry of complex organic molecules (COMs) at the epoch of planet formation provides insights into the chemical evolution of the interstellar medium (ISM) and the origin of organic materials in our Solar System. We report a detection of dimethyl ether (CH$_3$OCH$_3$) in the disk around the Herbig Ae star MWC 480 with the sensitive Atacama Large Millimeter/submillimeter Array observations. This is the first detection of CH$_3$OCH$_3$ in a non-transitional Class II disk. The spatially unresolved, compact (${\lesssim}$25 au in radius) nature, the broad line width ($\sim$30 km s$^{-1}$), and the high excitation temperature (${\sim}$200 K) indicate sublimation of COMs in the warm inner disk. Despite the detection of CH$_3$OCH$_3$, methanol (CH$_3$OH), the most abundant COM in the ISM, has not been detected, from which we constrain the column density ratio of CH$_3$OCH$_3$/CH$_3$OH ${\gtrsim}$7. This high ratio may indicate the reprocessing of COMs during the disk phase, as well as the effect of the physical structure in the inner disk. We also find that this ratio is higher than in COM-rich transition disks recently discovered. This may indicate that, in the full disk of MWC 480, COMs have experienced substantial chemical reprocessing in the innermost region, while the COM emission in the transition disks predominantly traces the inherited ice sublimating at the dust cavity edge located at larger radii (${\gtrsim}$20 au)., Comment: 16 pages, 6 figures, accepted for publication in ApJ

Ionization drives important chemical and dynamical processes within protoplanetary disks, including the formation of organics and water in the cold midplane and the transportation of material via accretion and magneto-hydrodynamic (MHD) flows. Understanding these ionization-driven processes is crucial for understanding disk evolution and planet formation. We use new and archival ALMA observations of HCO+, H13CO+, and N2H+ to produce the first forward-modeled 2D ionization constraints for the DM Tau protoplanetary disk. We include ionization from multiple sources and explore the disk chemistry under a range of ionizing conditions. Abundances from our 2D chemical models are post-processed using non-LTE radiative transfer, visibility sampling, and imaging, and are compared directly to the observed radial emission profiles. The observations are best fit by a modestly reduced CR ionization rate ($\zeta_{CR}$ ~ 10$^{-18}$ s$^{-1}$) and a hard X-ray spectrum (hardness ratio [HR] = 0.3), which we associate with stellar flaring conditions. Our best-fit model under-produces emission in the inner disk, suggesting that there may be an additional mechanism enhancing ionization in DM Tau's inner disk. Overall, our findings highlight the complexity of ionization in protoplanetary disks and the need for high resolution multi-line studies., Comment: 18 pages, 12 figures, accepted to be published in The Astrophysical Journal (June 25, 2024)

Rings and gaps are among the most widely observed forms of substructure in protoplanetary disks. A gap-ring pair may be formed when a planet carves a gap in the disk, which produces a local pressure maximum following the gap that traps inwardly drifting dust grains and appears as a bright ring due to the enhanced dust density. A dust-trapping ring would provide a promising environment for solid growth and possibly planetesimal production via the streaming instability. We present evidence of dust trapping in the bright ring of the planet-hosting disk Elias 2-24, from the analysis of 1.3 mm and 3 mm ALMA observations at high spatial resolution (0.029 arcsec, 4.0 au). We leverage the high spatial resolution to demonstrate that larger grains are more efficiently trapped and place constraints on the local turbulence ($8 \times 10^{-4} < \alpha_\mathrm{turb} < 0.03$) and the gas-to-dust ratio ($\Sigma_g / \Sigma_d < 30$) in the ring. Using a scattering-included marginal probability analysis we measure a total dust disk mass of $M_\mathrm{dust} = 13.8^{+0.7}_{-0.5} \times 10^{-4} \ M_\odot$. We also show that at the orbital radius of the proposed perturber, the gap is cleared of material down to a flux contrast of 10$^{-3}$ of the peak flux in the disk., Comment: 18 pages, 12 figures, accepted to ApJ

Most stars are born in stellar clusters and their protoplanetary disks, which are the birthplaces of planets, can therefore be affected by the radiation of nearby massive stars. However, little is known about the chemistry of externally irradiated disks, including whether or not their properties are similar to the so-far better-studied isolated disks. Motivated by this question, we present ALMA Band 6 observations of two irradiated Class II protoplanetary disks in the outskirts of the Orion Nebula Cluster (ONC) to explore the chemical composition of disks exposed to (external) FUV radiation fields: the 216-0939 disk and the binary system 253-1536A/B, which are exposed to radiation fields of $10^2-10^3$ times the average interstellar radiation field. We detect lines from CO isotopologues, HCN, H$_2$CO, and C$_2$H toward both protoplanetary disks. Based on the observed disk-integrated line fluxes and flux ratios, we do not find significant differences between isolated and irradiated disks. The observed differences seem to be more closely related to the different stellar masses than to the external radiation field. This suggests that these disks are far enough away from the massive Trapezium stars, that their chemistry is no longer affected by external FUV radiation. Additional observations towards lower-mass disks and disks closer to the massive Trapezium stars are required to elucidate the level of external radiation required to make an impact on the chemistry of planet formation in different kinds of disks., Comment: 32 pages, 22 figures, Accepted for publication in ApJ

H$_2$CO is a small organic molecule widely detected in protoplanetary disks. As a precursor to grain-surface formation of CH$_3$OH, H$_2$CO is considered an important precursor of O-bearing organic molecules that are locked in ices. Still, since gas-phase reactions can also form H$_2$CO, there remains an open question on the channels by which organics form in disks, and how much the grain versus the gas pathways impact the overall organic reservoir. We present spectrally and spatially resolved Atacama Large Millimeter/submillimeter Array observations of several ortho- and para-H$_2$CO transitions toward the bright protoplanetary disk around the Herbig Ae star HD 163296. We derive column density, excitation temperature, and ortho-to-para ratio (OPR) radial profiles for H$_2$CO, as well as disk-averaged values of $N_{\mathrm{T}}\sim4\times 10^{12}$ cm$^{-2}$, $T_{\mathrm{ex}}\sim20$ K, and $\mathrm{OPR}\sim2.7$, respectively. We empirically determine the vertical structure of the emission, finding vertical heights of $z/r\sim0.1$. From the profiles, we find a relatively constant $\mathrm{OPR}\sim2.7$ with radius, but still consistent with $3.0$ among the uncertainties, a secondary increase of $N_{\mathrm{T}}$ in the outer disk, and low $T_{\mathrm{ex}}$ values that decrease with disk radius. Our resulting radial, vertical, and OPR constraints suggest an increased UV penetration beyond the dust millimeter edge, consistent with an icy origin but also with cold gas-phase chemistry. This Herbig disk contrasts previous results for the T Tauri disk, TW Hya, which had a larger contribution from cold gas-phase chemistry. More observations of other sources are needed to disentangle the dominant formation pathway of H$_2$CO in protoplanetary disks., Comment: 21 pages, 4 tables, 10 figures; V2: minor changes, matches the published version in ApJ

We present MIRI MRS observations of the large, multi-gapped protoplanetary disk around the T-Tauri star AS 209. The observations reveal hundreds of water vapor lines from 4.9 to 25.5 $\mu$m towards the inner $\sim1$ au in the disk, including the first detection of ro-vibrational water emission in this disk. The spectrum is dominated by hot ($\sim800$ K) water vapor and OH gas, with only marginal detections of CO$_2$, HCN, and a possible colder water vapor component. Using slab models with a detailed treatment of opacities and line overlap, we retrieve the column density, emitting area, and excitation temperature of water vapor and OH, and provide upper limits for the observable mass of other molecules. Compared to MIRI spectra of other T-Tauri disks, the inner disk of AS 209 does not appear to be atypically depleted in CO$_2$ nor HCN. Based on \textit{Spitzer IRS} observations, we further find evidence for molecular emission variability over a 10-year baseline. Water, OH, and CO$_2$ line luminosities have decreased by factors 2-4 in the new MIRI epoch, yet there are minimal continuum emission variations. The origin of this variability is yet to be understood., Comment: Accepted for publication in ApJ

We study the kinematics of the AS 209 disk using the J=2-1 transitions of $^{12}$CO, $^{13}$CO, and C$^{18}$O. We derive the radial, azimuthal, and vertical velocity of the gas, taking into account the lowered emission surface near the annular gap at ~1.7 (200 au) within which a candidate circumplanetary disk-hosting planet has been reported previously. In $^{12}$CO and $^{13}$CO, we find a coherent upward flow arising from the gap. The upward gas flow is as fast as $150~{\rm m~s}^{-1}$ in the regions traced by $^{12}$CO emission, which corresponds to about 50% of the local sound speed or $6\%$ of the local Keplerian speed. Such an upward gas flow is difficult to reconcile with an embedded planet alone. Instead, we propose that magnetically driven winds via ambipolar diffusion are triggered by the low gas density within the planet-carved gap, dominating the kinematics of the gap region. We estimate the ambipolar Elsasser number, Am, using the HCO$^+$ column density as a proxy for ion density and find that Am is ~0.1 at the radial location of the upward flow. This value is broadly consistent with the value at which numerical simulations find ambipolar diffusion drives strong winds. We hypothesize the activation of magnetically-driven winds in a planet-carved gap can control the growth of the embedded planet. We provide a scaling relationship which describes the wind-regulated terminal mass: adopting parameters relevant to 100 au from a solar-mass star, we find the wind-regulated terminal mass is about one Jupiter mass, which may help explain the dearth of directly imaged super-Jovian-mass planets., Comment: This paper has been accepted for publication in the Astrophysical Journal (ApJ)

ALMA observations of the disk around HD 163296 have resolved a crescent-shape substructure at around 55 au, inside and off-center from a gap in the dust that extends from 38 au to 62 au. In this work we propose that both the crescent and the dust rings are caused by a compact pair (period ratio $\simeq 4:3$) of sub-Saturn-mass planets inside the gap, with the crescent corresponding to dust trapped at the $L_5$ Lagrange point of the outer planet. This interpretation also reproduces well the gap in the gas recently measured from the CO observations, which is shallower than what is expected in a model where the gap is carved by a single planet. Building on previous works arguing for outer planets at $\approx 86$ and $\approx 137$ au, we provide with a global model of the disk that best reproduces the data and show that all four planets may fall into a long resonant chain, with the outer three planets in a 1:2:4 Laplace resonance. We show that this configuration is not only an expected outcome from disk-planet interaction in this system, but it can also help constraining the radial and angular position of the planet candidates using three-body resonances., Comment: 11 pages, 8 figures, re-submitted to ApJL, comments welcome

Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new ALMA observations of DCO$^+$ and DCN $J=2-1$ at an angular resolution of $0.5"$ (30 au) and combine them with archival data of higher energy transitions towards the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO$^+$ and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of $1.9\times10^{12}$ and $9.8\times10^{11}$ cm$^{-2}$ for DCO$^{+}$ and DCN, with typical kinetic temperatures for both molecules of 20-30K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO$^+$/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas phase C/O enhancement within $<40$ au. Observations of DCO$^+$ and DCN in other disks, as well as HCN and HCO$^+$, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks., Comment: Fixed author information

The chemical reservoir within protoplanetary disks has a direct impact on planetary compositions and the potential for life. A long-lived carbon-and nitrogen-rich chemistry at cold temperatures (<=50K) is observed within cold and evolved planet-forming disks. This is evidenced by bright emission from small organic radicals in 1-10 Myr aged systems that would otherwise have frozen out onto grains within 1 Myr. We explain how the chemistry of a planet-forming disk evolves from a cosmic-ray/X-ray-dominated regime to an ultraviolet-dominated chemical equilibrium. This, in turn, will bring about a temporal transition in the chemical reservoir from which planets will accrete. This photochemical dominated gas phase chemistry develops as dust evolves via growth, settling and drift, and the small grain population is depleted from the disk atmosphere. A higher gas-to-dust mass ratio allows for deeper penetration of ultraviolet photons is coupled with a carbon-rich gas (C/O > 1) to form carbon-bearing radicals and ions. This further results in gas phase formation of organic molecules, which then would be accreted by any actively forming planets present in the evolved disk., Comment: Accepted to Nature Astronomy, Published Dec 8th 2022

We report the discovery of a circumplanetary disk (CPD) candidate embedded in the circumstellar disk of the T Tauri star AS 209 at a radial distance of about 200 au (on-sky separation of 1."4 from the star at a position angle of $161^\circ$), isolated via $^{13}$CO $J=2-1$ emission. This is the first instance of CPD detection via gaseous emission capable of tracing the overall CPD mass. The CPD is spatially unresolved with a $117\times82$ mas beam and manifests as a point source in $^{13}$CO, indicating that its diameter is $\lesssim14$ au. The CPD is embedded within an annular gap in the circumstellar disk previously identified using $^{12}$CO and near-infrared scattered light observations, and is associated with localized velocity perturbations in $^{12}$CO. The coincidence of these features suggests that they have a common origin: an embedded giant planet. We use the $^{13}$CO intensity to constrain the CPD gas temperature and mass. We find that the CPD temperature is $\gtrsim35$ K, higher than the circumstellar disk temperature at the radial location of the CPD, 22 K, suggesting that heating sources localized to the CPD must be present. The CPD gas mass is $\gtrsim 0.095 M_{\rm Jup} \simeq 30 M_{\rm Earth}$ adopting a standard $^{13}$CO abundance. From the non-detection of millimeter continuum emission at the location of the CPD ($3\sigma$ flux density $\lesssim26.4~\mu$Jy), we infer that the CPD dust mass is $\lesssim 0.027 M_{\rm Earth} \simeq 2.2$ lunar masses, indicating a low dust-to-gas mass ratio of $\lesssim9\times10^{-4}$. We discuss the formation mechanism of the CPD-hosting giant planet on a wide orbit in the framework of gravitational instability and pebble accretion., Comment: Accepted for publication in the ApJ Letters (July 7, 2022), 19 pages, 13 figures, interactive figures (Figure 7, 8, 9) are available at http://jaehanbae.com/as209/

High spatial resolution CO observations of mid-inclination (30-75{\deg}) protoplanetary disks offer an opportunity to study the vertical distribution of CO emission and temperature. The asymmetry of line emission relative to the disk major axis allows for a direct mapping of the emission height above the midplane, and for optically-thick, spatially-resolved emission in LTE, the intensity is a measure of the local gas temperature. Our analysis of ALMA archival data yields CO emission surfaces, dynamically-constrained stellar host masses, and disk atmosphere gas temperatures for the disks around: HD 142666, MY Lup, V4046 Sgr, HD 100546, GW Lup, WaOph 6, DoAr 25, Sz 91, CI Tau, and DM Tau. These sources span a wide range in stellar masses (0.50-2.10 M$_{\odot}$), ages (${\sim}$0.3-23 Myr), and CO gas radial emission extents (${\approx}$200-1000 au). This sample nearly triples the number of disks with mapped emission surfaces and confirms the wide diversity in line emitting heights ($z/r\approx0.1$ to ${\gtrsim}0.5$) hinted at in previous studies. We compute radial and vertical CO gas temperature distributions for each disk. A few disks show local temperature dips or enhancements, some of which correspond to dust substructures or the proposed locations of embedded planets. Several emission surfaces also show vertical substructures, which all align with rings and gaps in the millimeter dust. Combining our sample with literature sources, we find that CO line emitting heights weakly decline with stellar mass and gas temperature, which, despite large scatter, is consistent with simple scaling relations. We also observe a correlation between CO emission height and disk size, which is due to the flared structure of disks. Overall, CO emission surfaces trace ${\approx}2$-$5\times$ gas pressure scale heights (H$_{\rm{g}}$) and could potentially be calibrated as empirical tracers of H$_{\rm{g}}$., Comment: 31 pages, 17 figures, accepted for publication in ApJ. Image cubes available at https://zenodo.org/record/6410045

UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects, however to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N=1-0 transitions at 0.3'' resolution towards five disk systems. All disks show bright CN emission within $\sim$50-150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions, and also means that CN is the dominant carrier of the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

During the main phase of evolution of a protoplanetary disk, accretion regulates the inner-disk properties, such as the temperature and mass distribution, and in turn, the physical conditions associated with planet formation. The driving mechanism behind accretion remains uncertain; however, one promising mechanism is the removal of a fraction of angular momentum via a magnetohydrodynamic (MHD) disk wind launched from the inner tens of astronomical units of the disk. This paper utilizes CO isotopologue emission to study the unique molecular outflow originating from the HD 163296 protoplanetary disk obtained with the Atacama Large Millimeter/submillimeter Array. HD~163296 is one of the most well-studied Class II disks and is proposed to host multiple gas-giant planets. We robustly detect the large-scale rotating outflow in the 12CO J=2-1 and the 13CO J=2-1 and J=1-0 transitions. We constrain the kinematics, the excitation temperature of the molecular gas, and the mass-loss rate. The high ratio of the rates of ejection to accretion (5 - 50), together with the rotation signatures of the flow, provides solid evidence for an MHD disk wind. We find that the angular momentum removal by the wind is sufficient to drive accretion through the inner region of the disk; therefore, accretion driven by turbulent viscosity is not required to explain HD~163296's accretion. The low temperature of the molecular wind and its overall kinematics suggest that the MHD disk wind could be perturbed and shocked by the previously observed high-velocity atomic jet. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: Accepted ApJ July 30th 2021 This paper is part of the MAPS special issue of the Astrophysical Journal Supplement

Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about the deuteration processes operating during the planet formation era. We aim to study these processes by radially resolving the DCN/HCN (at 0.3" resolution) and N$_2$D$^+$/N$_2$H$^+$ (0.3 to 0.9") column density ratios toward the five protoplanetary disks observed by the Molecules with ALMA at Planet-forming scales (MAPS) Large Program. DCN is detected in all five sources, with one newly reported detection. N$_2$D$^+$ is detected in four sources, two of which are newly reported detections. We derive column density profiles that allow us to study the spatial variation of the DCN/HCN and N$_2$D$^+$/N$_2$H$^+$ ratios at high resolution. DCN/HCN varies considerably for different parts of the disks, ranging from $10^{-3}$ to $10^{-1}$. In particular, the inner disk regions generally show significantly lower HCN deuteration compared with the outer disk. In addition, our analysis confirms that two deuterium fractionation channels are active, which can alter the D/H ratio within the pool of organic molecules. N$_2$D$^+$ is found in the cold outer regions beyond $\sim$50 au, with N$_2$D$^+$/N$_2$H$^+$ ranging between $10^{-2}$ and 1 across the disk sample. This is consistent with the theoretical expectation that N$_2$H$^+$ deuteration proceeds via the low-temperature channel only. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: Accepted for publication in the Astrophysical Journal Supplement. 55 pages, 30 figures. Replacement of earlier version with updated references

Constraining dust properties of planet-forming disks via high angular resolution observations is fundamental to understanding how solids are trapped in substructures and how dust growth may be favored or accelerated therein. We use ALMA dust continuum observations of the Molecules with ALMA at Planet-forming Scales (MAPS) disks and explore a large parameter space to constrain the radial distribution of solid mass and maximum grain size in each disk, including or excluding dust scattering. In the nonscattering model, the dust surface density and maximum grain size profiles decrease from the inner disks to the outer disks, with local maxima at the bright ring locations, as expected from dust trapping models. The inferred maximum grain sizes from the inner to outer disks decrease from ~1 cm to 1 mm. For IM Lup, HD 163296, and MWC 480 in the scattering model, two solutions are compatible with their observed inner disk emission: one solution corresponding to a maximum grain size of a few millimeters (similar to the nonscattering model), and the other corresponding to a few hundred micrometer sizes. Based on the estimated Toomre parameter, only IM Lup -- which shows a prominent spiral morphology in millimeter dust -- is found to be gravitationally unstable. The estimated maximum Stokes number in all the disks lies between 0.01 and 0.3, and the estimated turbulence parameters in the rings of AS 209 and HD 163296 are close to the threshold where dust growth is limited by turbulent fragmentation. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

We observed HCO$^+$ $J=1-0$ and H$^{13}$CO$^+$ $J=1-0$ emission towards the five protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 as part of the MAPS project. HCO$^+$ is detected and mapped at 0.3\arcsec\,resolution in all five disks, while H$^{13}$CO$^+$ is detected (SNR$>6 \sigma$) towards GM Aur and HD 163296 and tentatively detected (SNR$>3 \sigma$) towards the other disks by a matched filter analysis. Inside a radius of $R\sim 100$ au, the HCO$^+$ column density is flat or shows a central dip. At outer radii ($\gtrsim 100$ au), the HCO$^+$ column density decreases outwards, while the column density ratio of HCO$^+$/CO is mostly in the range of $\sim 10^{-5}-10^{-4}$. We derived the HCO$^+$ abundance in the warm CO-rich layer, where HCO$^+$ is expected to be the dominant molecular ion. At $R\gtrsim 100$ au, the HCO$^+$ abundance is $\sim 3 \times 10^{-11} - 3\times 10^{-10}$, which is consistent with a template disk model with X-ray ionization. At the smaller radii, the abundance decreases inwards, which indicates that the ionization degree is lower in denser gas, especially inside the CO snow line, where the CO-rich layer is in the midplane. Comparison of template disk models with the column densities of HCO$^+$, N$_2$H$^+$, and N$_2$D$^+$ indicates that the midplane ionization rate is $\gtrsim 10^{-18}$ s$^{-1}$ for the disks around IM Lup, AS 209, and HD 163296. We also find hints of an increased HCO$^+$ abundance around the location of dust continuum gaps in AS 209, HD 163296, and MWC 480. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: accepted to ApJS, 33 pages, 20 figures

Small organic molecules, such as C2H, HCN, and H2CO, are tracers of the C, N, and O budget in protoplanetary disks. We present high angular resolution (10-50 au) observations of C2H, HCN, and H2CO lines in five protoplanetary disks from the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program. We derive column density and excitation temperature profiles for HCN and C2H, and find that the HCN emission arises in a temperate (20-30 K) layer in the disk, while C2H is present in relatively warmer (20-60 K) layers. In the case of HD 163296, we find a decrease in column density for HCN and C2H inside one of the dust gaps near 83 au, where a planet has been proposed to be located. We derive H2CO column density profiles assuming temperatures between 20 and 50 K, and find slightly higher column densities in the colder disks around T Tauri stars than around Herbig Ae stars. The H2CO column densities rise near the location of the CO snowline and/or millimeter dust edge, suggesting an efficient release of H2CO ices in the outer disk. Finally, we find that the inner 50 au of these disks are rich in organic species, with abundances relative to water that are similar to cometary values. Comets could therefore deliver water and key organics to future planets in these disks, similar to what might have happened here on Earth. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 23 pages, 10 figures, 4 tables. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement

The precursors to larger, biologically-relevant molecules are detected throughout interstellar space, but determining the presence and properties of these molecules during planet formation requires observations of protoplanetary disks at high angular resolution and sensitivity. Here we present 0.3" observations of HC$_3$N, CH$_3$CN, and $c$-C$_3$H$_2$ in five protoplanetary disks observed as part of the Molecules with ALMA at Planet-forming Scales (MAPS) Large Program. We robustly detect all molecules in four of the disks (GM Aur, AS 209, HD 163296 and MWC 480) with tentative detections of $c$-C$_3$H$_2$ and CH$_3$CN in IM Lup. We observe a range of morphologies -- central peaks, single or double rings -- with no clear correlation in morphology between molecule nor disk. Emission is generally compact and on scales comparable with the millimetre dust continuum. We perform both disk-integrated and radially-resolved rotational diagram analysis to derive column densities and rotational temperatures. The latter reveals 5-10 times more column density in the inner 50-100 au of the disks when compared with the disk-integrated analysis. We demonstrate that CH$_3$CN originates from lower relative heights in the disks when compared with HC$_3$N, in some cases directly tracing the disk midplane. Finally, we find good agreement between the ratio of small to large nitriles in the outer disks and comets. Our results indicate that the protoplanetary disks studied here are host to significant reservoirs of large organic molecules, and that this planet- and comet-building material can be chemically similar to that in our own Solar System. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement Series., Comment: 24 pages, 11 figures, 5 tables. Accepted for publication in ApJSS. Updated to cross-reference other MAPS publications

Sulfur-bearing molecules play an important role in prebiotic chemistry and planet habitability. They are also proposed probes of chemical ages, elemental C/O ratio, and grain chemistry processing. Commonly detected in diverse astrophysical objects, including the Solar System, their distribution and chemistry remain, however, largely unknown in planet-forming disks. We present CS ($2-1$) observations at $\sim0."3$ resolution performed within the ALMA-MAPS Large Program toward the five disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. CS is detected in all five disks, displaying a variety of radial intensity profiles and spatial distributions across the sample, including intriguing apparent azimuthal asymmetries. Transitions of C$_2$S and SO were also serendipitously covered but only upper limits are found. For MWC 480, we present complementary ALMA observations at $\sim0."5$, of CS, $^{13}$CS, C$^{34}$S, H$_2$CS, OCS, and SO$_2$. We find a column density ratio N(H$_{2}$CS)/N(CS)$\sim2/3$, suggesting that a substantial part of the sulfur reservoir in disks is in organic form (i.e., C$_x$H$_y$S$_z$). Using astrochemical disk modeling tuned to MWC 480, we demonstrate that $N$(CS)/$N$(SO) is a promising probe for the elemental C/O ratio. The comparison with the observations provides a super-solar C/O. We also find a depleted gas-phase S/H ratio, suggesting either that part of the sulfur reservoir is locked in solid phase or that it remains in an unidentified gas-phase reservoir. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: Accepted for publication in The Astrophysical Journal Supplement (27 pages, 13 figures, 5 tables)

Planets form and obtain their compositions in dust and gas-rich disks around young stars, and the outcome of this process is intimately linked to the disk chemical properties. The distributions of molecules across disks regulate the elemental compositions of planets, including C/N/O/S ratios and metallicity (O/H and C/H), as well as access to water and prebiotically relevant organics. Emission from molecules also encodes information on disk ionization levels, temperature structures, kinematics, and gas surface densities, which are all key ingredients of disk evolution and planet formation models. The Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program was designed to expand our understanding of the chemistry of planet formation by exploring disk chemical structures down to 10 au scales. The MAPS program focuses on five disks - around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 - in which dust substructures are detected and planet formation appears to be ongoing. We observed these disks in 4 spectral setups, which together cover ~50 lines from over 20 different species. This paper introduces the ApJS MAPS Special Issue by presenting an overview of the program motivation, disk sample, observational details, and calibration strategy. We also highlight key results, including discoveries of links between dust, gas, and chemical sub-structures, large reservoirs of nitriles and other organics in the inner disk regions, and elevated C/O ratios across most disks. We discuss how this collection of results is reshaping our view of the chemistry of planet formation., Comment: Accepted for publication in the ApJS MAPS Special Issue. v2 has updated MAPS references and a correction to Fig. 3

Here we present high resolution (15-24 au) observations of CO isotopologue lines from the Molecules with ALMA on Planet-forming Scales (MAPS) ALMA Large Program. Our analysis employs $^{13}$CO and C$^{18}$O ($J$=2-1), (1-0), and C$^{17}$O (1-0) line observations of five protoplanetary disks. We retrieve CO gas density distributions, using three independent methods: (1) a thermo-chemical modeling framework based on the CO data, the broadband spectral energy distribution, and the mm-continuum emission; (2) an empirical temperature distribution based on optically thick CO lines; and (3) a direct fit to the C$^{17}$O hyperfine lines. Results from these methods generally show excellent agreement. The CO gas column density profiles of the five disks show significant variations in the absolute value and the radial shape. Assuming a gas-to-dust mass ratio of 100, all five disks have a global CO-to-H$_2$ abundance of 10-100 times lower than the ISM ratio. The CO gas distributions between 150-400 au match well with models of viscous disks, supporting the long-standing theory. CO gas gaps appear to be correlated with continuum gap locations, but some deep continuum gaps do not have corresponding CO gaps. The relative depths of CO and dust gaps are generally consistent with predictions of planet-disk interactions, but some CO gaps are 5-10 times shallower than predictions based on dust gaps. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: This paper is part of the MAPS special issue of the Astrophysical Journal Supplement. 36 pages, 21 figures, accepted for publication in ApJS

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a unique opportunity to study the vertical distribution of gas, chemistry, and temperature in the protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. By using the asymmetry of molecular line emission relative to the disk major axis, we infer the emission height ($z$) above the midplane as a function of radius ($r$). Using this method, we measure emitting surfaces for a suite of CO isotopologues, HCN, and C$_2$H. We find that $^{12}$CO emission traces the most elevated regions with $z/r > 0.3$, while emission from the less abundant $^{13}$CO and C$^{18}$O probes deeper into the disk at altitudes of $z/r \lesssim 0.2$. C$_2$H and HCN have lower opacities and SNRs, making surface fitting more difficult, and could only be reliably constrained in AS 209, HD 163296, and MWC 480, with $z/r \lesssim 0.1$, i.e., relatively close to the planet-forming midplanes. We determine peak brightness temperatures of the optically thick CO isotopologues and use these to trace 2D disk temperature structures. Several CO temperature profiles and emission surfaces show dips in temperature or vertical height, some of which are associated with gaps and rings in line and/or continuum emission. These substructures may be due to local changes in CO column density, gas surface density, or gas temperatures, and detailed thermo-chemical models are necessary to better constrain their origins and relate the chemical compositions of elevated disk layers with those of planet-forming material in disk midplanes. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 31 pages, 20 figures, accepted for publication in ApJS, MAPS cross-references updated

The concentric gaps and rings commonly observed in protoplanetary disks in millimeter continuum emission have lent the impression that planet formation generally proceeds within orderly, isolated systems. While deep observations of spatially resolved molecular emission have been comparatively limited, they are increasingly suggesting that some disks interact with their surroundings while planet formation is underway. We present an analysis of complex features identified around GM Aur in $^{12}$CO $J=2-1$ images at a spatial resolution of $\sim40$ au. In addition to a Keplerian disk extending to a radius of $\sim550$ au, the CO emission traces flocculent spiral arms out to radii of $\sim$1200 au, a tail extending $\sim1800$ au southwest of GM Aur, and diffuse structures extending from the north side of the disk up to radii of $\sim1900$ au. The diffuse structures coincide with a "dust ribbon" previously identified in scattered light. The large-scale asymmetric gas features present a striking contrast with the mostly axisymmetric, multi-ringed millimeter continuum tracing the pebble disk. We hypothesize that GM Aur's complex gas structures result from late infall of remnant envelope or cloud material onto the disk. The morphological similarities to the SU Aur and AB Aur systems, which are also located in the L1517 cloud, provide additional support to a scenario in which interactions with the environment are playing a role in regulating the distribution and transport of material in all three of these Class II disk systems. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 34 pages, 21 figures, in press at ApJS, cross-references updated

Constraining the distribution of gas and dust in the inner 20 au of protoplanetary disks is difficult. At the same time, this region is thought to be responsible for most planet formation, especially around the water ice line at 3-10 au. Under the assumption that the gas is in a Keplerian disk, we use the exquisite sensitivity of the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA large program to construct radial surface brightness profiles with a ~3 au effective resolution for the CO isotopologue J=2-1 lines using the line velocity profile. IM Lup reveals a central depression in 13CO and C18O that is ascribed to a pileup of ~500 $M_\oplus$ of dust in the inner 20 au, leading to a gas-to-dust ratio of around <10. This pileup is consistent with efficient drift of grains ($\gtrsim$ 100 $M_\oplus$ Myr$^{-1}$) and a local gas-to-dust ratio that suggests that the streaming instability could be active. The CO isotopologue emission in the GM Aur disk is consistent with a small (~15 au), strongly depleted gas cavity within the ~40 au dust cavity. The radial surface brightness profiles for both the AS 209 and HD 163296 disks show a local minimum and maximum in the C18O emission at the location of a known dust ring (~14 au) and gap (~10 au), respectively. This indicates that the dust ring has a low gas-to-dust ratio ($>$ 10) and that the dust gap is gas-rich enough to have optically thick C18O., Comment: 22 pages, 14 figures, accepted by ApJS. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement. Update with correct references to other MAPS papers

The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of the gas at the locations of potentially forming planets. The elemental abundances are inferred by comparing source-specific gas-grain thermochemical models, with variable C/O ratios and small-grain abundances, from the DALI code with CO and C2H column densities derived from the high-resolution observations of the disks of AS 209, HD 163296, and MWC 480. Elevated C/O ratios (~2.0), even within the CO ice line, are necessary to match the inferred C2H column densities, over most of the pebble disk. Combined with constraints on the CO abundances in these systems, this implies that both the O/H and C/H ratios in the gas are substellar by a factor of 4-10, with the O/H depleted by a factor of 20-50, resulting in the high C/O ratios. This necessitates that even within the CO ice line, most of the volatile carbon and oxygen is still trapped on grains in the midplane. Planets accreting gas in the gaps of the AS 209, HD 163296, and MWC 480 disks will thus acquire very little carbon and oxygen after reaching the pebble isolation mass. In the absence of atmosphere-enriching events, these planets would thus have a strongly substellar O/H and C/H and superstellar C/O atmospheric composition., Comment: 19 pages, 8 figures This paper is part of the MAPS special issue of the Astrophysical Journal Supplement. Updates references for other MAPS papers

We explore the dynamical structure of the protoplanetary disks surrounding HD 163296 and MWC 480 as part of the Molecules with ALMA at Planet Forming Scales (MAPS) large program. Using the $J = 2-1$ transitions of $^{12}$CO, $^{13}$CO and C$^{18}$O imaged at spatial resolutions of $\sim 0.^{\prime \prime}15$ and with a channel spacing of $200$ ${\rm m\,s^{-1}}$, we find perturbations from Keplerian rotation in the projected velocity fields of both disks ($\lesssim\!5\%$ of the local Keplerian velocity), suggestive of large-scale (10s of au in size), coherent flows. By accounting for the azimuthal dependence on the projection of the velocity field, the velocity fields were decomposed into azimuthally averaged orthogonal components, $v_{\phi}$, $v_r$ and $v_z$. Using the optically thick $^{12}$CO emission as a probe of the gas temperature, local variations of $\approx\! 3$ K ($\approx\! 5 \%$ relative changes) were observed and found to be associated with the kinematic substructures. The MWC 480 disk hosts a suite of tightly wound spiral arms. The spirals arms, in conjunction with the highly localized perturbations in the gas velocity structure (kinematic planetary signatures), indicate a giant planet, $\sim\! 1$ $M_{\rm Jup}$, at a radius of $\approx 245$ au. In the disk of HD 163296, the kinematic substructures were consistent with previous studies of Pinte et al. (2018a) and Teague et al. (2018a) advocating for multiple $\sim\! 1$ $M_{\rm Jup}$ planets embedded in the disk. These results demonstrate that molecular line observations that characterize the dynamical structure of disks can be used to search for the signatures of embedded planets. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 32 pages, 21 figures, accepted for publication in ApJS, MAPS cross-references updated

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high resolution (${\sim}$10-20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here, we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies - including rings, gaps, and plateaus - is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially-varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 62 pages, 31 figures, accepted for publication in ApJS, MAPS cross-references updated, corrected Figure 21, updated gas disk sizes (Table 2, Figures 15-16) from associated Erratum

Understanding the temperature structure of protoplanetary disks is key to interpreting observations, predicting the physical and chemical evolution of the disk, and modeling planet formation processes. In this study, we constrain the two-dimensional thermal structure of the disk around Herbig Ae star HD 163296. Using the thermo-chemical code RAC2D, we derive a thermal structure that reproduces spatially resolved ALMA observations (~0.12 arcsec (13 au) - 0.25 arcsec (26 au)) of CO J = 2-1, 13CO J = 1-0, 2-1, C18O J = 1-0, 2-1, and C17O J = 1-0, the HD J = 1-0 flux upper limit, the spectral energy distribution (SED), and continuum morphology. The final model incorporates both a radial depletion of CO motivated by a time scale shorter than typical CO gas-phase chemistry (0.01 Myr) and an enhanced temperature near the surface layer of the the inner disk (z/r <= 0.21). This model agrees with the majority of the empirically derived temperatures and observed emitting surfaces derived from the J = 2-1 CO observations. We find an upper limit for the disk mass of 0.35 Msun, using the upper limit of the HD J = 1-0 and J = 2-1 flux. With our final thermal structure, we explore the impact that gaps have on the temperature structure constrained by observations of the resolved gaps. Adding a large gap in the gas and small dust additionally increases gas temperature in the gap by only 5-10%. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: 15 pages + 11 pages of appendix, accepted to ApJS, part of MAPS collaboration

The Molecules with ALMA at Planet-forming Scales large program (MAPS LP) surveyed the chemical structures of five protoplanetary disks across more than 40 different spectral lines at high angular resolution (0.15" and 0.30" beams for Bands 6 and 3, respectively) and sensitivity (spanning 0.3 - 1.3 mJy/beam and 0.4 - 1.9 mJy/beam for Bands 6 and 3, respectively). In this article, we describe our multi-stage workflow -- built around the CASA tclean image deconvolution procedure -- that we used to generate the core data product of the MAPS LP: the position-position-velocity image cubes for each spectral line. Owing to the expansive nature of the survey, we encountered a range of imaging challenges; some are familiar to the sub-mm protoplanetary disk community, like the benefits of using an accurate CLEAN mask, and others less well-known, like the incorrect default flux scaling of the CLEAN residual map first described in Jorsater & van Moorsel 1995 (the "JvM effect"). We distill lessons learned into recommended workflows for synthesizing image cubes of molecular emission. In particular, we describe how to produce image cubes with accurate fluxes via the "JvM correction," a procedure that is generally applicable to any image synthesized via CLEAN deconvolution but is especially critical for low S/N emission. We further explain how we used visibility tapering to promote a common, fiducial beam size and contextualize the interpretation of signal to noise ratio when detecting molecular emission from protoplanetary disks. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: ApJS accepted. Part of the MAPS ALMA large program series: http://www.alma-maps.info/. Updated bibliography with MAPS LP arXiv references

M-stars are the most common hosts of planetary systems in the Galaxy. Protoplanetary disks around M-stars thus offer a prime opportunity to study the chemistry of planet-forming environments. We present an ALMA survey of molecular line emission toward a sample of five protoplanetary disks around M4-M5 stars (FP Tau, J0432+1827, J1100-7619, J1545-3417, and Sz 69). These observations can resolve chemical structures down to tens of AU. Molecular lines of $^{12}$CO, $^{13}$CO, C$^{18}$O, C$_2$H, and HCN are detected toward all five disks. Lines of H$_2$CO and DCN are detected toward 2/5 and 1/5 disks, respectively. For disks with resolved C$^{18}$O, C$_2$H, HCN, and H$_2$CO emission, we observe substructures similar to those previously found in disks around solar-type stars (e.g., rings, holes, and plateaus). C$_2$H and HCN excitation conditions estimated interior to the pebble disk edge for the bright disk J1100-7619 are consistent with previous measurements around solar-type stars. The correlation previously found between C$_2$H and HCN fluxes for solar-type disks extends to our M4-M5 disk sample, but the typical C$_2$H/HCN ratio is higher for the M4-M5 disk sample. This latter finding is reminiscent of the hydrocarbon enhancements found by previous observational infrared surveys in the innermost ($<$10AU) regions of M-star disks, which is intriguing since our disk-averaged fluxes are heavily influenced by flux levels in the outermost disk, exterior to the pebble disk edge. Overall, most of the observable chemistry at 10-100AU appears similar for solar-type and M4-M5 disks, but hydrocarbons may be more abundant around the cooler stars., Comment: 46 pages (20 pages in the main document, 26 pages in the appendix), 48 figures, 7 tables. Accepted in ApJ (February 2021)

Connecting the composition of planet-forming disks with that of gas giant exoplanet atmospheres, in particular through C/O ratios, is one of the key goals of disk chemistry. Small hydrocarbons like $\rm C_2H$ and $\rm C_3H_2$ have been identified as tracers of C/O, as they form abundantly under high C/O conditions. We present resolved $\rm C_3H_2$ observations from the TW Hya Rosetta Stone Project, a program designed to map the chemistry of common molecules at $15-20$ au resolution in the TW Hya disk. Augmented by archival data, these observations comprise the most extensive multi-line set for disks of both ortho and para spin isomers spanning a wide range of energies, $E_u=29-97$ K. We find the ortho-to-para ratio of $\rm C_3H_2$ is consistent with 3 throughout extent of the emission, and the total abundance of both $\rm C_3H_2$ isomers is $(7.5-10)\times10^{-11}$ per H atom, or $1-10$% of the previously published $\rm C_2H$ abundance in the same source. We find $\rm C_3H_2$ comes from a layer near the surface that extends no deeper than $z/r=0.25$. Our observations are consistent with substantial radial variation in gas-phase C/O in TW Hya, with a sharp increase outside $\sim30$ au. Even if we are not directly tracing the midplane, if planets accrete from the surface via, e.g., meridonial flows, then such a change should be imprinted on forming planets. Perhaps interestingly, the HR 8799 planetary system also shows an increasing gradient in its giant planets' atmospheric C/O ratios. While these stars are quite different, hydrocarbon rings in disks are common, and therefore our results are consistent with the young planets of HR 8799 still bearing the imprint of their parent disk's volatile chemistry., Comment: 15 pages, 8 figures, Accepted in ApJ

The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line ratios might therefore offer a unique opportunity to probe the properties of the emitting gas. Using the 2D thermochemical code DALI, we ran a set of disk models accounting for different stellar and disk properties, with an updated chemical network for the nitrogen chemistry. These modeling results were then compared with observations, including new ALMA observations of HNC $J=3-2$ for the TW Hya disk and HNC $J=1-0$ for 29 disks in Lupus. Similar to CN, HCN and HNC have brighter line emission in models with larger disk flaring angles and higher UV fluxes. HNC and HCN are predicted to be abundant in the warm surface layer and outer midplane region, which results in ring-shaped emission patterns. However, the precise emitting regions and emission morphology depend on the probed transition, as well as on other parameters such as C and O abundances. The modeled HNC-to-HCN line intensity ratio increases from $<0.1$ in the inner disk to up to 0.8 in the outer disk regions, which can be explained by efficient HNC destruction at high temperatures. Disk-integrated HNC line fluxes from current scarce observations and its radial distribution in the TW Hya disk are broadly consistent with our model predictions. The HNC-to-HCN flux ratio robustly increases with radius (decreasing temperature), but its use as a chemical thermometer in disks is affected by other factors, including UV flux and C and O abundances. High-spatial resolution ALMA disk observations of HNC and HCN that can locate the emitting layers would have the great potential to constrain both the disk thermal and UV radiation structures, and also to verify our understanding of the nitrogen chemistry., Comment: accepted for publication in A&A

In this era of Gaia and ALMA, dynamical stellar mass measurements provide benchmarks that are independent of observations of stellar characteristics and their uncertainties. These benchmarks can then be used to validate and improve stellar evolutionary models, which can lead to both imprecise and inaccurate mass predictions for pre-main-sequence, low-mass stars. We present the dynamical stellar masses derived from disks around three M-stars (FP Tau, J0432+1827, and J1100-7619) using ALMA observations of $^{12}$CO (J=2--1) and $^{13}$CO (J=2--1) emission. These are the first dynamical stellar mass measurements for J0432+1827 and J1100-7619 and the most precise measurement for FP Tau. Fiducial stellar evolutionary model tracks, which do not include any treatment of magnetic activity, agree with the dynamical measurement of J0432+1827 but underpredict the mass by $\sim$60\% for FP Tau and $\sim$80\% for J1100-7619. Possible explanations for the underpredictions include inaccurate assumptions of stellar effective temperature, undetected binarity for J1100-7619, and that fiducial stellar evolutionary models are not complex enough to represent these stars. In the former case, the stellar effective temperatures would need to be increased by $\sim$40K to $\sim$340K to reconcile the fiducial model predictions with the dynamically-measured masses. In the latter case, we show that the dynamical masses can be reproduced using results from stellar evolutionary models with starspots, which incorporate fractional starspot coverage to represent the manifestation of magnetic activity. Folding in low-mass M-stars from the literature and assuming that the stellar effective temperatures are imprecise but accurate, we find tentative evidence of a relationship between fractional starspot coverage and observed effective temperature for these young, cool stars., Comment: 37 pages (14 pages in the main document, 23 pages in the appendix), 35 figures, 5 tables. Accepted in ApJ (December 2020)

Formaldehyde (H$_2$CO) is an important precursor to organics like methanol (CH$_3$OH). It is important to understand the conditions that produce H$_2$CO and prebiotic molecules during star and planet formation. H$_2$CO possesses both gas-phase and solid-state formation pathways, involving either UV-produced radical precursors or CO ice and cold ($\lesssim 20$ K) dust grains. To understand which pathway dominates, gaseous H$_2$CO's ortho-to-para ratio (OPR) has been used as a probe, with a value of 3 indicating "warm" conditions and $<3$ linked to cold formation in the solid-state. We present spatially resolved ALMA observations of multiple ortho- and para-H$_2$CO transitions in the TW Hya protoplanetary disk to test H$_2$CO formation theories during planet formation. We find disk-averaged rotational temperatures and column densities of $33\pm2$ K, ($1.1\pm0.1)\times10^{12}$ cm$^{-2}$ and $25\pm2$ K, $(4.4\pm0.3)\times10^{11}$ cm$^{-2}$ for ortho- and para-H$_2$CO, respectively, and an OPR of $2.49\pm0.23$. A radially resolved analysis shows that the observed H$_2$CO emits mostly at rotational temperatures of 30-40 K, corresponding to a layer with $z/R\ge0.25$. The OPR is consistent with 3 within 60 au, the extent of the pebble disk, and decreases beyond 60 au to $2.0\pm0.5$. The latter corresponds to a spin temperature of 12 K, well below the rotational temperature. The combination of relatively uniform emitting conditions, a radial gradient in the OPR, and recent laboratory experiments and theory on OPR ratios after sublimation, lead us to speculate that gas-phase formation is responsible for the observed H$_2$CO across the TW Hya disk.

The volatile composition of a planet is determined by the inventory of gas and ice in the parent disk. The volatile chemistry in the disk is expected to evolve over time, though this evolution is poorly constrained observationally. We present ALMA observations of C18O, C2H, and the isotopologues H13CN, HC15N, and DCN towards five Class 0/I disk candidates. Combined with a sample of fourteen Class II disks presented in Bergner et al. (2019b), this data set offers a view of volatile chemical evolution over the disk lifetime. Our estimates of C18O abundances are consistent with a rapid depletion of CO in the first ~0.5-1 Myr of the disk lifetime. We do not see evidence that C2H and HCN formation are enhanced by CO depletion, possibly because the gas is already quite under-abundant in CO. Further CO depletion may actually hinder their production by limiting the gas-phase carbon supply. The embedded sources show several chemical differences compared to the Class II stage, which seem to arise from shielding of radiation by the envelope (impacting C2H formation and HC15N fractionation) and sublimation of ices from infalling material (impacting HCN and C18O abundances). Such chemical differences between Class 0/I and Class II sources may affect the volatile composition of planet-forming material at different stages in the disk lifetime., Comment: Accepted to ApJ

H$_2$CO is one of the most abundant organic molecules in protoplanetary disks and can serve as a precursor to more complex organic chemistry. We present an ALMA survey of H$_2$CO towards 15 disks covering a range of stellar spectral types, stellar ages, and dust continuum morphologies. H$_2$CO is detected towards 13 disks and tentatively detected towards a 14th. We find both centrally-peaked and centrally-depressed emission morphologies, and half of the disks show ring-like structures at or beyond expected CO snowline locations. Together these morphologies suggest that H$_2$CO in disks is commonly produced through both gas-phase and CO-ice-regulated grain-surface chemistry. We extract disk-averaged and azimuthally-averaged H$_2$CO excitation temperatures and column densities for four disks with multiple H$_2$CO line detections. The temperatures are between 20-50K, with the exception of colder temperatures in the DM Tau disk. These temperatures suggest that H$_2$CO emission in disks is generally emerging from the warm molecular layer, with some contributions from the colder midplane. Applying the same H$_2$CO excitation temperatures to all disks in the survey, we find that H$_2$CO column densities span almost three orders of magnitude ($\sim 5 \times 10^{11} - 5 \times 10^{14} \mathrm{cm}^{-2}$). The column densities appear uncorrelated with disk size and stellar age, but Herbig Ae disks may have less H$_2$CO compared to T Tauri disks, possibly because of less CO freeze-out. More H$_2$CO observations towards Herbig Ae disks are needed to confirm this tentative trend, and to better constrain under which disk conditions H$_2$CO and other oxygen-bearing organics efficiently form during planet formation., Comment: 20 pages, 14 figures, 3 figure sets, 9 tables. Published in ApJ (February 2020)

We present an analysis of ALMA 1.25 millimeter continuum observations of spiral structures in three protoplanetary disks from the Disk Substructures at High Angular Resolution Project. The disks around Elias 27, IM Lup, and WaOph 6 were observed at a resolution of $\sim40-60$ mas ($\sim6-7$ au). All three disks feature $m=2$ spiral patterns in conjunction with annular substructures. Gas kinematics established by $^{12}$CO $J=2-1$ observations indicate that the continuum spiral arms are trailing. The arm-interarm intensity contrasts are modest, typically less than 3. The Elias 27 spiral pattern extends throughout much of the disk, and the arms intersect the gap at $R\sim69$ au. The spiral pattern in the IM Lup disk is particularly complex-it extends about halfway radially through the disk, exhibiting pitch angle variations with radius and interarm features that may be part of ring substructures or spiral arm branches. Spiral arms also extend most of the way through the WaOph 6 disk, but the source overall is much more compact than the other two disks. We discuss possible origins for the spiral structures, including gravitational instability and density waves induced by a stellar or planetary companion. Unlike the millimeter continuum counterparts of many of the disks with spiral arms detected in scattered light, these three sources do not feature high-contrast crescent-like asymmetries or large ($R>20$ au) emission cavities. This difference may point to multiple spiral formation mechanisms operating in disks., Comment: 19 pages, 9 figures, minor typos corrected

ALMA observations of protoplanetary disks acquired by the Disk Substructure at High Angular Resolution Project (DSHARP) resolve the dust and gas emission on angular scales as small as 3 astronomical units, offering an unprecedented detailed view of the environment where planets form. In this article, we present and discuss observations of the HD 163296 protoplanetary disk that imaged the 1.25 mm dust continuum and $^{12}$CO J=2-1 rotational line emission at a spatial resolution of 4 and 10 au, respectively. The continuum observations resolve and allow us to characterize the previously discovered dust rings at radii of 67 and 100 au. They also reveal new small scale structures, such as a dark gap at 10 au, a bright ring at 15 au, a dust crescent at a radius of 55 au, and several fainter azimuthal asymmetries. The observations of the CO and dust emission inform about the vertical structure of the disk and allow us to directly constrain the dust extinction optical depth at the dust rings. Furthermore, the observed asymmetries in the dust continuum emission corroborate to the hypothesis that the complex structure of the HD 163296 disk is the result of the gravitational interaction with yet unseen planets., Comment: ApJ Letters, in press. 19 pages, 11 figures

A large fraction of the protoplanetary disks observed with ALMA display multiple well-defined and nearly perfectly circular rings in the continuum, in many cases with substantial peak-to-valley contrast. The DSHARP campaign shows that several of these rings are very narrow in radial extent. In this paper we test the hypothesis that these dust rings are caused by dust trapping in radial pressure bumps, and if confirmed, put constraints on the physics of the dust trapping mechanism. We model this process analytically in 1D, assuming axisymmetry. By comparing this model to the data, we find that all rings are consistent with dust trapping. Based on a plausible model of the dust temperature we find that several rings are narrower than the pressure scale height, providing strong evidence for dust trapping. The rings have peak absorption optical depth in the range between 0.2 and 0.5. The dust masses stored in each of these rings is of the order of tens of Earth masses, though much ambiguity remains due to the uncertainty of the dust opacities. The dust rings are dense enough to potentially trigger the streaming instability, but our analysis cannot give proof of this mechanism actually operating. Our results show, however, that the combination of very low alpha_turb << 5e-4 and very large grains a_grain >> 0.1 cm can be excluded by the data for all the rings studied in this paper., Comment: Accepted for publication in ApJ Letters

The Disk Substructures at High Angular Resolution Project used ALMA to map the 1.25 millimeter continuum of protoplanetary disks at a spatial resolution of ~5 au. We present a systematic analysis of annular substructures in the 18 single-disk systems targeted in this survey. No dominant architecture emerges from this sample; instead, remarkably diverse morphologies are observed. Annular substructures can occur at virtually any radius where millimeter continuum emission is detected and range in widths from a few au to tens of au. Intensity ratios between gaps and adjacent rings range from near-unity to just a few percent. In a minority of cases, annular substructures co-exist with other types of substructures, including spiral arms (3/18) and crescent-like azimuthal asymmetries (2/18). No clear trend is observed between the positions of the substructures and stellar host properties. In particular, the absence of an obvious association with stellar host luminosity (and hence the disk thermal structure) suggests that substructures do not occur preferentially near major molecular snowlines. Annular substructures like those observed in DSHARP have long been hypothesized to be due to planet-disk interactions. A few disks exhibit characteristics particularly suggestive of this scenario, including substructures in possible mean-motion resonance and "double gap" features reminiscent of hydrodynamical simulations of multiple gaps opened by a planet in a low-viscosity disk., Comment: 33 pages, 12 figures, captions corrected

We present a detailed analysis of new ALMA observations of the disk around the T-Tauri star HD 143006, which at 46 mas (7.6 au) resolution reveal new substructures in the 1.25 mm continuum emission. The disk resolves into a series of concentric rings and gaps together with a bright arc exterior to the rings that resembles hydrodynamics simulations of a vortex, and a bridge-like feature connecting the two innermost rings. Although our $^{12}$CO observations at similar spatial resolution do not show obvious substructure, they reveal an inner disk depleted of CO emission. From the continuum emission and the CO velocity field we find that the innermost ring has a higher inclination than the outermost rings and the arc. This is evidence for either a small ($\sim8^{\circ}$) or moderate ($\sim41^{\circ}$) misalignment between the inner and outer disk, depending on the specific orientation of the near/far sides of the inner/outer disk. We compare the observed substructures in the ALMA observations with recent scattered light data from VLT/SPHERE of this object. In particular, the location of narrow shadow lanes in the SPHERE image combined with pressure scale height estimates, favor a large misalignment of about $41^{\circ}$. We discuss our findings in the context of a dust-trapping vortex, planet-carved gaps, and a misaligned inner disk due to the presence of an inclined companion to HD 143006., Comment: 15 pages, 8 figures, accepted for publication at ApJ Letters

The Disk Substructures at High Angular Resolution Project (DSHARP) provides a large sample of protoplanetary disks having substructures which could be induced by young forming planets. To explore the properties of planets that may be responsible for these substructures, we systematically carry out a grid of 2-D hydrodynamical simulations including both gas and dust components. We present the resulting gas structures, including the relationship between the planet mass and 1) the gaseous gap depth/width, and 2) the sub/super-Keplerian motion across the gap. We then compute dust continuum intensity maps at the frequency of the DSHARP observations. We provide the relationship between the planet mass and 1) the depth/width of the gaps at millimeter intensity maps, 2) the gap edge ellipticity and asymmetry, and 3) the position of secondary gaps induced by the planet. With these relationships, we lay out the procedure to constrain the planet mass using gap properties, and study the potential planets in the DSHARP disks. We highlight the excellent agreement between observations and simulations for AS 209 and the detectability of the young Solar System analog. Finally, under the assumption that the detected gaps are induced by young planets, we characterize the young planet population in the planet mass-semimajor axis diagram. We find that the occurrence rate for $>$ 5 $M_J$ planets beyond 5-10 au is consistent with direct imaging constraints. Disk substructures allow us probe a wide-orbit planet population (Neptune to Jupiter mass planets beyond 10 au) that is not accessible to other planet searching techniques., Comment: 36 pages, 22 figures, ApJ Letters, in press

We introduce the Disk Substructures at High Angular Resolution Project (DSHARP), one of the initial Large Programs conducted with the Atacama Large Millimeter/submillimeter Array (ALMA). The primary goal of DSHARP is to find and characterize substructures in the spatial distributions of solid particles for a sample of 20 nearby protoplanetary disks, using very high resolution (0.035 arcsec, or 5 au FWHM) observations of their 240 GHz (1.25 mm) continuum emission. These data provide a first homogeneous look at the small-scale features in disks that are directly relevant to the planet formation process, quantifying their prevalence, morphologies, spatial scales, spacings, symmetry, and amplitudes, for targets with a variety of disk and stellar host properties. We find that these substructures are ubiquitous in this sample of large, bright disks. They are most frequently manifested as concentric, narrow emission rings and depleted gaps, although large-scale spiral patterns and small arc-shaped azimuthal asymmetries are also present in some cases. These substructures are found at a wide range of disk radii (from a few au to more than 100 au), are usually compact ($<$10 au), and show a wide range of amplitudes (brightness contrasts). Here we discuss the motivation for the project, describe the survey design and the sample properties, detail the observations and data calibration, highlight some basic results, and provide a general overview of the key conclusions that are presented in more detail in a series of accompanying articles. The DSHARP data -- including visibilities, images, calibration scripts, and more -- are released for community use at https://almascience.org/alma-data/lp/DSHARP., Comment: ApJ Letters, in press; some figure resolutions reduced, full-res version at https://www.cfa.harvard.edu/~sandrews/DSHARP_I.pdf ; Data Release at https://almascience.org/alma-data/lp/DSHARP

We present a detailed analysis of the high-angular resolution (0.''037, corresponding to 5 au) observations of the 1.25 mm continuum and $^{12}$CO $2-1$ emission from the disk around the T Tauri star AS 209. AS 209 hosts one of the most unusual disks from the DSHARP sample, the first high angular resolution ALMA survey of disks (Andrews et al. 2018), as nearly all of the emission can be explained with concentric Gaussian rings. In particular, the dust emission consists of a series of narrow and closely spaced rings in the inner $\sim$60 au, two well-separated bright rings in the outer disk, centered at 74 and 120 au, and at least two fainter emission features at 90 and 130 au. We model the visibilities with a parametric representation of the radial surface brightness profile, consisting of a central core and 7 concentric Gaussian rings. Recent hydro-dynamical simulations of low viscosity disks show that super-Earth planets can produce the multiple gaps seen in AS 209 millimeter continuum emission. The $^{12}$CO line emission is centrally peaked and extends out to $\sim$300 au, much farther than the millimeter dust emission. We find axisymmetric, localized deficits of CO emission around four distinct radii, near 45, 75, 120 and 210 au. The outermost gap is located well beyond the edge of the millimeter dust emission, and therefore cannot be due to dust opacity and must be caused by a genuine CO surface density reduction, due either to chemical effects or depletion of the overall gas content., Comment: ApJ Letters, in press

The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the stages of star and planet formation. We present ALMA observations at $\sim0.6"$ resolution of DCO$^+$, H$^{13}$CO$^+$, DCN, and H$^{13}$CN in the full disks around T Tauri stars AS 209 and IM Lup, the transition disks around T Tauri stars V4046 Sgr and LkCa 15, and the full disks around Herbig Ae stars MWC 480 and HD 163296. We also present ALMA observations of HCN in the IM Lup disk. DCN, DCO$^+$, and H$^{13}$CO$^+$ are detected in all disks, and H$^{13}$CN in all but the IM Lup disk. We find efficient deuterium fractionation for the sample, with estimates of disk-averaged DCO$^+$/HCO$^+$ and DCN/HCN abundance ratios ranging from $\sim0.02-0.06$ and $\sim0.005-0.08$, respectively, which is comparable to values reported for other ISM environments. The relative distributions of DCN and DCO$^+$ vary between disks, suggesting that multiple formation pathways may be needed to explain the diverse emission morphologies. In addition, gaps and rings observed in both H$^{13}$CO$^+$ and DCO$^+$ emission provide new evidence that DCO$^+$ bears a complex relationship with the location of the midplane CO snowline., Comment: 36 pages, 14 figures, updated to match figure order of published version in ApJ

Observations of comets and asteroids show that the Solar Nebula that spawned our planetary system was rich in water and organic molecules. Bombardment brought these organics to the young Earth's surface, seeding its early chemistry. Unlike asteroids, comets preserve a nearly pristine record of the Solar Nebula composition. The presence of cyanides in comets, including 0.01% of methyl cyanide (CH3CN) with respect to water, is of special interest because of the importance of C-N bonds for abiotic amino acid synthesis. Comet-like compositions of simple and complex volatiles are found in protostars, and can be readily explained by a combination of gas-phase chemistry to form e.g. HCN and an active ice-phase chemistry on grain surfaces that advances complexity[3]. Simple volatiles, including water and HCN, have been detected previously in Solar Nebula analogues - protoplanetary disks around young stars - indicating that they survive disk formation or are reformed in situ. It has been hitherto unclear whether the same holds for more complex organic molecules outside of the Solar Nebula, since recent observations show a dramatic change in the chemistry at the boundary between nascent envelopes and young disks due to accretion shocks[8]. Here we report the detection of CH3CN (and HCN and HC3N) in the protoplanetary disk around the young star MWC 480. We find abundance ratios of these N-bearing organics in the gas-phase similar to comets, which suggests an even higher relative abundance of complex cyanides in the disk ice. This implies that complex organics accompany simpler volatiles in protoplanetary disks, and that the rich organic chemistry of the Solar Nebula was not unique., Comment: Definitive version of the manuscript is published in Nature, 520, 7546, 198, 2015. This is the author's version