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We have detected CH$^{+}$ and CH molecular absorption lines from the young compact planetary nebula IC 4997 from high resolution optical spectra. A high-resolution infra-red (H and K bands) spectrum provides detection of H$_2$ emission lines amongst many other lines. The H$_2$ lines provide an excitation temperature of 2100 K which may result from UV fluorescence in the envelope or from shocks formed at the interface between an expanding outflow of ionized gas and the neutral envelope ejected when the star was on the AGB. It is suggested that the CH$^+$ may result from the endothermic reaction C + H$_2$ $\rightarrow$ CH$^+$ + H. Intriguingly, CH$^{+}$ and also CH show a higher expansion velocity than H$_{\rm 2}$ emission suggesting they may be part of the post-shocked gas., Comment: 12 pages, 2 tables, 6 figures, accepted for publication in Publications of the Astronomical Society of the Pacific (PASP)

We aim to study the main properties of a volume-limited unbiased sample of well-characterized semi-regular variables (SRs) in order to clarify important issues, such as the formation of axially symmetric planetary nebulae (PNe) from spherical circumstellar envelopes (CSEs), which takes place during the mass-loss process along the AGB phase. We present new high-S/N IRAM 30m observations of the 12CO J=2-1, J=1-0, and 13CO J=1-0 lines, in a volume-limited sample of SRs. We analyzed the data by characterizing the main properties of the CSEs. The 12CO J=2-1 data were used to study the profiles, while the 12CO J=1-0 data were used to estimate mass-loss rates for the complete sample. We have classified the sources into four groups according to the different profiles and final gas expansion velocities. Type 1 and 2 profiles are broad and narrow symmetric lines, respectively. Type 3 profiles on the contrary are strange profiles with very pronounced asymmetries. Finally, type 4 profiles are those showing two different components: a narrow line profile superimposed on a broad pedestal component. Interestingly, we report a moderate correlation between mass-loss rates and 12CO J=1-0/J=2-1 line intensity ratios for O-rich SRs, suggesting a different behaviour between C- and O-rich SRs. Using SHAPE+shapemol, we find a unified simple model based on an oblate spheroid placed in different orientations that may explain all the 12CO profiles in the sample, indicating that the gas expansion is in general predominantly equatorial. Moreover, in order to explain the type 4 profiles, we define an extra component which may somehow be a biconical structure or similar. Type 1 and 2 profiles, curiously, may also be explained by standard spherically symmetric envelopes. We conclude that most circumstellar shells around SRs show axial, strongly nonspherical symmetry., Comment: 32 pages, 28 figures, and 10 tables, accepted for publication in A&A

The main goal of this thesis is to unveil some questions related to the formation of complex fullerene-based molecules in space, with the aim of resolving some key problems in astrophysics. The unexpected detections of fullerenes and graphene (possible C24) in the H-rich circumstellar environments of evolved stars indicate that these complex molecules are not so rare and bring the idea that other forms of carbon such as hydrogenated fullerenes (fulleranes), buckyonions, and carbon nanotubes may be widespread in the Universe, being closely involved in many aspects of circumstellar/interstellar chemistry and physics. We explore this new and fertile field of research by focusing our study on some Galactic planetary nebulae (PNe) that contain fullerenes. In order to do this, we make use of laboratory spectra of several fullerene-related compounds and compare them with astronomical data. This work is a first step to open up a new field of interdisciplinary research, crossing the boundaries between astronomers, chemists, and physicists, and understand the significant presence of fullerene structures in circumstellar/interstellar environments., Comment: Accepted for publication in PASP (Dissertation Summary), 2 pages, 2 figures

The mass loss process along the AGB phase is crucial for the formation of circumstellar envelopes (CSEs), which in the post-AGB phase will evolve into planetary nebulae (PNe). There are still important issues that need to be further explored in this field; in particular, the formation of axially symmetric PNe from spherical CSEs. To address the problem, we have conducted high S/N IRAM 30m observations of 12CO J=1-0 and J=2-1, and 13CO J=1-0 in a volume-limited unbiased sample of semi-regular variables (SRs). We also conducted Yebes 40m SiO J=1-0 observations in 1/2 of the sample in order to complement our 12CO observations. We report a moderate correlation between mass loss rates and the 12CO(1-0)-to-12CO(2-1) intensity ratio, introducing a possible new method for determining mass loss rates of SRs with short analysis time. We also find that for several stars the SiO profiles are very similar to the 12CO profiles, a totally unexpected result unless these are non-standard envelopes., Comment: 4 pages, 4 figures, to appear in proceedings of IAU Symposium 343: "Why Galaxies Care About AGB Stars: A Continuing Challenge through Cosmic Time"

We present seeing-limited narrow-band mid-IR GTC/CanariCam images of the spatially extended fullerene-containing planetary nebula (PN) IC 418. The narrow-band images cover the C60 fullerene band at 17.4 {\mu}m, the polycyclic aromatic hydrocarbon like (PAH-like) feature at 11.3 {\mu}m, the broad 9-13 {\mu}m feature, and their adjacent continua at 9.8 and 20.5 {\mu}m. We study the relative spatial distribution of these complex species, all detected in the Spitzer and Infrared Space Observatory (ISO) spectra of IC 418, with the aim of getting observational constraints to the formation process of fullerenes in H-rich circumstellar environments. A similar ring-like extended structure is seen in all narrow-band filters, except in the dust continuum emission at 9.8 {\mu}m, which peaks closer to the central star. The continuum-subtracted images display a clear ring-like extended structure for the carrier of the broad 9-13 {\mu}m emission, while the spatial distribution of the (PAH-like) 11.3 {\mu}m emission is not so well defined. Interestingly, a residual C60 17.4 {\mu}m emission (at about 4-{\sigma} from the sky background) is seen when subtracting the dust continuum emission at 20.5 {\mu}m. This residual C60 emission, if real, might have several interpretations; the most exciting being perhaps that other fullerene-based species like hydrogenated fullerenes with very low H-content may contribute to the observed 17.4 {\mu}m emission. We conclude that higher sensitivity mid-IR images and spatially resolved spectroscopic observations (especially in the Q-band) are necessary to get some clues about fullerene formation in PNe., Comment: Accepted for publication in Astronomical Journal (15 pages, 9 figures, and 2 Tables)

Detections of C60 and C70 fullerenes in planetary nebulae (PNe) of the Magellanic Clouds and of our own Galaxy have raised the idea that other forms of carbon such as hydrogenated fullerenes (fulleranes like C60H36 and C60H18), buckyonions, and carbon nanotubes, may be widespread in the Universe. Here we present VLT/ISAAC spectra (R ~600) in the 2.9-4.1 microns spectral region for the Galactic PNe Tc 1 and M 1-20, which have been used to search for fullerene-based molecules in their fullerene-rich circumstellar environments. We report the non-detection of the most intense infrared bands of several fulleranes around ~3.4-3.6 microns in both PNe. We conclude that if fulleranes are present in the fullerene-containing circumstellar environments of these PNe, then they seem to be by far less abundant than C60 and C70. Our non-detections together with the (tentative) fulleranes detection in the proto-PN IRAS 01005+7910 suggest that fulleranes may be formed in the short transition phase between AGB stars and PNe but they are quickly destroyed by the UV radiation field from the central star., Comment: Accepted for publication in Astronomy & Astrophysics (7 pages, 3 figures, and 3 Tables)