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The chemistry in the central regions of galaxies is expected to be strongly influenced by their nuclear activity. To find the best tracers of nuclear activity is of key importance to understand the processes taking place in the most obscured regions of galactic nuclei. In this work we present multi-line observations of CS, C34S, HNCO and C18O in a sample of 11 bright galaxies prototypical for different types of activity. The 32S/34S isotopic ratio is ~10, supporting the idea of an isotopical 34S enrichment due to massive star formation in the nuclear regions of galaxies. Although C32S and C34S do not seem to be significantly affected by the activity type, the HNCO abundance appears highly contrasted among starburst. We observed HNCO abundance variations of nearly two orders of magnitude. The HNCO molecule is shown to be a good tracer of the amount of molecular material fueling the starburst and therefore can be used as a diagnostics of the evolutionary state of a nuclear starburst., Comment: 21 pages, 3 figures, Accepted by ApJ

We present the 3.5m SPICA space telescope, a proposed Japanese-led JAXA-ESA mission scheduled for launch around 2017. The actively cooled (<5 K), single aperture telescope and monolithic mirror will operate from ~3.5 to ~210 um and will provide superb sensitivity in the mid- and far-IR spectral domain (better than JWST at lambda > 18 um). SPICA is one of the few space missions selected to go to the next stage of ESA's Cosmic Vision 2015-2025 selection process. In this White Paper we present the main specifications of the three instruments currently baselined for SPICA: a mid-infrared (MIR) coronagraph (~3.5 to ~27 um) with photometric and spectral capabilities (R~200), a MIR wide-field camera and high resolution spectrometer (R~30,000), and a far-infrared (FIR ~30 to ~210 um) imaging spectrometer - SAFARI - led by a European consortium. We discuss their capabilities in the context of MIR direct observations of exo-planets (EPs) and multiband photometry/high resolution spectroscopy observations of transiting exo-planets. We conclude that SPICA will be able to characterize the atmospheres of transiting exo-planets down to the super-Earth size previously detected by ground- or space-based observatories. It will also directly detect and characterize Jupiter/Neptune-size planets orbiting at larger separation from their parent star (>5-10 AU), by performing quantitative atmospheric spectroscopy and studying proto-planetary and debris disks. In addition, SPICA will be a scientific and technological precursor for future, more ambitious, IR space missions for exo-planet direct detection as it will, for example, quantify the prevalence exo-zodiacal clouds in planetary systems and test coronographic techniques, cryogenic systems and lightweight, high quality telescopes. (abridged), Comment: A White Paper for ESA's Exo-Planet Roadmap Advisory Team, submitted on 2008 July 29

We present the first detection of CS in the Antennae galaxies towards the NGC 4038 nucleus, as well as the first detections of two high-J (5-4 and 7-6) CS lines in the center of M 82. The CS(7-6) line in M 82 shows a profile that is surprisingly different to those of other low-J CS transitions we observed. This implies the presence of a separate, denser and warmer molecular gas component. The derived physical properties and the likely location of the CS(7-6) emission suggests an association with the supershell in the centre of M 82., Comment: 10 pages, 3 figures, ApJ Letter - ACCEPTED

Context: The detection of narrow SiO lines toward the young shocks of the L1448-mm outflow has been interpreted as a signature of the magnetic precursor of C-shocks. In contrast with the low SiO abundances (<10E-12) in the ambient gas, the narrow SiO emission at almost ambient velocities reveals enhanced SiO abundances of 10E-11. This enhancement has been proposed to be produced by the sputtering of the grain mantles at the first stages of C-shocks. However, modelling of the sputtering of grains has usually averaged the SiO abundances over the dissipation region of C-shocks, which cannot explain the recent observations. Aims: To model the evolution of the gas phase abundances of SiO, CH3OH and H2O, produced by the sputtering of grains as the shock propagates through the ambient gas. Methods: We propose a parametric model to describe the physical structure of C-shocks as a function of time. Using the known sputtering yields for water mantles (with minor constituents like silicon and CH3OH) and olivine cores by collisions with H2, He, C, O, Si, Fe and CO, we follow the evolution of the abundances of silicon, CH3OH and H2O ejected from grains. Results: The evolution of these abundances shows that CO seems to be the most efficient sputtering agent in low velocity shocks. The velocity threshold for the sputtering of silicon from the grain mantles is reduced by 5-10 km s-1 by CO compared to other models. The sputtering by CO can generate SiO abundances of 10E-11 at the early stages of low velocity shocks, consistent with those observed in the magnetic precursor of L1448-mm. Our model also satisfactorily reproduce the progressive enhancement of SiO, CH3OH and H2O observed in this outflow by the coexistence of two shocks with vs=30 and 60kms-1 within the same region., Comment: 12 pages, 7 figures, accepted for publication in A&A

We present a systematic study of the HNCO, C18O, 13CS, and C34S emission towards 13 selected molecular clouds in the Galactic center region. The molecular emission in these positions are used as templates of the different physical and chemical processes claimed to be dominant in the circumnuclear molecular gas of galaxies. The relative abundance of HNCO shows a variation of more than a factor of 20 amo ng the observed sources. The HNCO/13CS abundance ratio is highly contrasted (up to a factor of 30) between the shielded molecular clouds mostly affected by shocks, where HNCO is released to gas-phase from grain mantles, and those pervaded by an intense UV radiation field, where HNCO is photo-dissociated and CS production favored via ion reactions. We propose the relative HNCO to CS abundance ratio as a highly contrasted diagnostic tool to distinguish between the influence of shocks and/or the radiation field in the nuclear regions of galaxies and their relation to the evolutionary state of their nuclear star formation bursts., Comment: 25 pages, 5 figures, Accepted for publication in ApJ

We present the first detection of complex aldehydes and isomers in three typical molecular clouds located within 200pc of the center of our Galaxy. We find very large abundances of these complex organic molecules (COMs) in the central molecular zone (CMZ), which we attribute to the ejection of COMs from grain mantles by shocks. The relative abundances of the different COMs with respect to that of CH3OH are strikingly similar for the three sources, located in very different environments in the CMZ. The similar relative abundances point toward a unique grain mantle composition in the CMZ. Studying the Galactic center clouds and objects in the Galactic disk having large abundances of COMs, we find that more saturated molecules are more abundant than the non-saturated ones. We also find differences between the relative abundance between COMs in the CMZ and the Galactic disk, suggesting different chemical histories of the grain mantles between the two regions in the Galaxy for the complex aldehydes. Different possibilities for the grain chemistry on the icy mantles in the GC clouds are briefly discussed. Cosmic rays can play an important role in the grain chemistry. With these new detections, the molecular clouds in the Galactic center appear to be one of the best laboratories for studying the formation of COMs in the Galaxy., Comment: 20 pages, 4 figures, accepted in ApJ

We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques. In spite of its weak dipole moment, 6 doublets (A and E species) plus another line from the A species have been observed with main beam temperatures above 20 mK. The derived total column density of propylene is 4 10^13 cm^-2, which corresponds to an abundance relative to H_2 of 4 10^-9, i.e., comparable to that of other well known and abundant hydrocarbons in this cloud, such as c-C_3H_2. Although this isomer of C_3H_6 could play an important role in interstellar chemistry, it has been ignored by previous chemical models of dark clouds as there seems to be no obvious formation pathway in gas phase. The discovery of this species in a dark cloud indicates that a thorough analysis of the completeness of gas phase chemistry has to be done., Comment: 13 pages, 2 figures, accepted for publication in ApJL

We present VLA and PdBI subarcsecond images (0.15"-0.6") of the radiocontinuum emission at 7 mm and of the SO2 J=19_{2,18}-18_{3,15} and J=27_{8,20}-28_{7,21} lines toward the Cepheus A HW2 region. The SO2 images reveal the presence of a hot core internally heated by an intermediate mass protostar, and a circumstellar rotating disk around the HW2 radio jet with size 600AUx100AU and mass of 1M_sun. Keplerian rotation for the disk velocity gradient of 5 kms-1 requires a 9 M_sun central star, which cannot explain the total luminosity observed in the region. This may indicate that the disk does not rotate with a Keplerian law due to the extreme youth of this object. Our high sensitivity radiocontinuum image at 7 mm shows in addition to the ionized jet, an extended emission to the west (and marginally to the south) of the HW2 jet, filling the south-west cavity of the HW2 disk. From the morphology and location of this free-free continuum emission at centimeter and millimeter wavelengths (spectral index of 0.4-1.5), we propose that the disk is photoevaporating due to the UV radiation from the central star. All this indicates that the Cepheus A HW2 region harbors a cluster of massive stars. Disk accretion seems to be the most plausible way to form massive stars in moderate density/luminosity clusters., Comment: 4 pages, 2 figures, accepted for publication in ApJL

Due to its relatively small distance (725 pc), the Cepheus A East star-forming region is an ideal laboratory to study massive star formation processes. Based on its morphology, it has been suggested that the flattened molecular gas distribution around the YSO HW2 may be a 350-AU-radius massive protostellar disk. Goal of our work is to ascertain the nature of this structure. We have employed the Plateau de Bure Interferometer to acquire (sub-)arcsecond-resolution imaging of high-density and shock tracers, such as methyl cyanide (CH3CN) and silicon monoxide (SiO), towards the HW2 position. On the 1-arcsecond (about 725 AU) scale, the flattened distribution of molecular gas around HW2 appears to be due to the projected superposition, on the plane of the sky, of at least three protostellar objects, of which at least one is powering a molecular outflow at a small angle with respect to the line of sight. The presence of a protostellar disk around HW2 is not ruled out, but such structure is likely to be detected on a smaller spatial scale, or using different molecular tracers., Comment: 6 pages, 5 figures, accepted for publication in Astronomy & Astrophysics

We present high sensitivity observations of the complex organic molecules (COMs) CH3OH, C2H5OH, HCOOCH3, HCOOH and H2CO and of SiO toward the quiescent dark cloud L183 and the molecular outflow L1448-mm. We have not detected C2H5OH, HCOOCH3 and SiO in L183 and in the quiescent gas of L1448-mm. The abundances of CH3OH, H2CO and SiO are enhanced by factors 4-20 in the shock precursor component, and those of CH3OH and SiO by 3 and 4 orders of magnitude in the shocked gas, without substantial changes (< factor of 2) in the abundances of C2H5OH and HCOOCH3 relative to that of CH3OH. The large enhancements of SiO and CH3OH can be explained by the shock ejection of an important fraction of the grain mantle material into gas phase. Our upper limits to the C2H5OH/CH3OH and HCOOCH3/CH3OH ratios are consistent with the rather constant ratios measured in hot cores and Galactic center clouds. However, the upper limits to the HCOOCH3/CH3OH and the HCOOH/CH3OH ratios are at least one order of magnitude smaller than those found in"hot corinos" surrounding low mass protostars. We speculate that the observed abundances of COMs in different objects are consistent with a sort of "universal" grain mantle composition which is locally changed by the processes of low mass star formation., Comment: 10 pages, 1 figure. Accepted ApJ Letters

Magnetic precursors of C-shocks accelerate, compress and heat molecular ions, modifying the kinematics and the physical conditions of the ion fluid with respect to the neutral one. Electron densities are also expected to be significantly enhanced in shock precursors. In this Letter, we present observations of strongly polar ion and neutral molecules such as SiO, H13CO+, HN13C and H13CN, which reveal the electron density enhancements associated with the precursor of the young L1448-mm outflow. While in the ambient gas the excitation of the ions and neutrals is explained by collisional excitation by H2 with a single density of 10E5cmE-3, H13CO+ shows an over excitation in the shock precursor component that requires H2 densities of a factor of >10 larger than those derived from the neutral species. This over excitation in H13CO+ can be explained if we consider an additional excitation by collisions with electrons and an electron density enhancement in the precursor stage by a factor of 500, i.e. a fractional ionization of 5x10E-5. These results show that multiline observations can be used to study the evolution of the ion and electron fluids at the first stages of the C-shock interaction., Comment: 4 pages, 1 figures, accepted for publication in ApJL

Observational constraints provided by high resolution and high sensitivity observations of external galaxies made in the millimeter and submillimeter range have started to put on a firm ground the study of extragalactic chemistry of molecular gas. In particular, the availability of multi-species and multi-line surveys of nearby galaxies is central to the interpretation of existent and forthcoming millimeter observations of the high redshift universe. Probing the physical and chemical status of molecular gas in starbursts and active galaxies (AGN) requires the use of specific tracers of the relevant energetic phenomena that are known to be at play in these galaxies: large-scale shocks, strong UV fields, cosmic rays and X-rays. We present below the first results of an ongoing survey, allying the IRAM 30m telescope with the Plateau de Bure interferometer(PdBI), devoted to study the chemistry of molecular gas in a sample of starbursts and AGN of the local universe. These observations highlight the existence of a strong chemical differentiation in the molecular disks of starbursts and AGN., Comment: Accepted for publication in Faraday Discussions 133, The Royal Society of Chemistry, 2006, 14 pages, 4 figures

We study the origin of large abundances of complex organic molecules in the Galactic center (GC). We carried out a systematic study of the complex organic molecules CH3OH, C2H5OH, (CH3)2O, HCOOCH3, HCOOH, CH3COOH, H2CO, and CS toward 40 GC molecular clouds. Using the LTE approximation, we derived the physical properties of GC molecular clouds and the abundances of the complex molecules.The CH3OH abundance between clouds varies by nearly two orders of magnitude from 2.4x10^{-8} to 1.1x10^{-6}. The abundance of the other complex organic molecules relative to that of CH3OH is basically independent of the CH3OH abundance, with variations of only a factor 4-8. The abundances of complex organic molecules in the GC are compared with those measured in hot cores and hot corinos, in which these complex molecules are also abundant. We find that both the abundance and the abundance ratios of the complex molecules relative to CH3OH in hot cores are similar to those found in the GC clouds. However, hot corinos show different abundance ratios than observed in hot cores and in GC clouds. The rather constant abundance of all the complex molecules relative to CH3OH suggests that all complex molecules are ejected from grain mantles by shocks. Frequent (similar 10^{5}years) shocks with velocities >6km/s are required to explain the high abundances in gas phase of complex organic molecules in the GC molecular clouds. The rather uniform abundance ratios in the GC clouds and in Galactic hot cores indicate a similar average composition of grain mantles in both kinds of regions. The Sickle and the Thermal Radio Arches, affected by UV radiation, show different relative abundances in the complex organic molecules due to the differentially photodissociation of these molecules., Comment: 18 pages, 10 Postscript figures, uses aa.cls, aa.bst, 10pt.rtx, natbib.sty, revsymb.sty revtex4.cls, aps.rtx and aalongtabl.sty. Accepted in A&A 2006. version 2. relocated figures and tables. Language editor suggestions. added references

We present a multilevel study of the emission of methanol, detected for the first time in this galaxy, and discuss the origin of its emission. The high observed methanol abundance of a few 10^-9 can only be explained if injection of methanol from dust grains is taken into account. While the overall [CH3OH]/[NH3] ratio is much larger than observed towards other starbursts, the dense high excitation component shows a similar value to that found in NGC 253 and Maffei 2. Our observations suggest the molecular material in M 82 to be formed by dense warm cores, shielded from the UV radiation and similar to the molecular clouds in other starbursts, surrounded by a less dense photodissociated halo. The dense warm cores are likely the location of recent and future star formation within M 82., Comment: Accepted for publication in A&A Letters

We present the first unbiased molecular line survey towards an extragalactic source, namely the nuclear region of the starburst galaxy NGC 253. The scan covers the frequency band from 129.1 to 175.2 GHz, i.e. most of the 2mm atmospheric window. We identify 111 spectral features as transitions from 25 different molecular species. Eight of which (three tentatively) are detected for the first time in the extragalactic interstellar medium. Among these newly detected species, we detected the rare isotopomers 34SO and HC18O+. Tentative detections of two deuterated species, DNC and N2D+, are reported for the first time from a target beyond the Magellanic Clouds. Additionally, three hydrogen recombination lines are identified, while no organic molecules larger than methanol are detected. Column densities and rotation temperatures are calculated for all the species, including an upper limit to the ethanol abundance. A comparison of the chemical composition of the nuclear environment of NGC 253 with those of selected nearby galaxies demonstrates the chemical resemblance of IC 342 and NGC 4945 to that of NGC 253. On the other hand, the chemistries characterizing NGC 253 and M 82 are clearly different. We also present a comparison of the chemical composition of NGC 253 with those observed in Galactic prototypical sources. The chemistry of NGC 253 shows a striking similarity with the chemistry observed toward the Galactic center molecular clouds, which are thought to be dominated by low-velocity shocks. This resemblance strongly suggests that the heating in the nuclear environment of NGC 253 is dominated by the same mechanism as that in the central region of the Milky Way., Comment: Accepted for publication in ApJS

(Abridged) We present the first high-resolution (5.6''x5.1'') images of the emission of silicon monoxide (SiO) in the nearby spiral IC342, obtained with the IRAM Plateau de Bure Interferometer. We have mapped the emission of the SiO(2-1) and H13CO+(1-0) lines in a 0.9kpcx1.3kpc region around the nucleus of IC342. The bulk of the line emission comes from a 290pc spiral arm and a r~80pc nuclear ring. The distribution of SiO clouds is mostly anticorrelated with the continuum emission at 87GHz, dominated by thermal free-free bremsstrahlung. The SiO/H13CO+ intensity ratio increases by an order of magnitude from the nuclear ring to the spiral arm. Furthermore the gas kinematics show significant differences between SiO and H13CO+ over the spiral arm, where the linewidths of SiO are 2 times larger than that of H13CO+. The average abundance of SiO in the inner r~320pc, X(SiO)>2x10^{-10}, evidences that shock chemistry is at work in IC342. We have compared the emission of SiO with another tracer of molecular shocks: the emission of methanol (CH3OH). The significant difference of the X(SiO) measured between the spiral arm (~a few 10^{-9}) and the nuclear ring (~10^{-10}) is not echoed by a comparable variation in the SiO/CH3OH intensity ratio. This implies that the typical shock velocities should be similar in both regions. In contrast, the fraction of shocked molecular gas should be 5-7 times larger in the spiral arm (up to ~10% of the available molecular gas mass over the arm region) compared to the nuclear ring. We conclude that the large-scale shocks revealed by the SiO map of IC342 are mostly unrelated with star formation and arise instead in a pre-starburst phase. Shocks are driven by cloud-cloud collisions along the potential well of the IC342 bar. The general implications for the current understanding of galaxy evolution are discussed., Comment: 15 pages, including 9 figures (6 color) and 3 tables; accepted in Astronomy & Astrophysics

We present the discovery of the first molecular hot core associated with an intermediate mass protostar in the CepA HW2 region. The hot condensation was detected from single dish and interferometric observations of several high excitation rotational lines (from 100 to 880K above the ground state) of SO2 in the ground vibrational state and of HC3N in the vibrationally excited states v7=1 and v7=2. The kinetic temperature derived from both molecules is 160K. The high-angular resolution observations (1.25'' x 0.99'') of the SO2 J=28(7,21)-29(6,24) line (488K above the ground state) show that the hot gas is concentrated in a compact condensation with a size of 0.6''(430AU), located 0.4'' (300AU) east from the radio-jet HW2. The total SO2 column density in the hot condensation is 10E18cm-2, with a H2 column density ranging from 10E23 to 6 x 10E24cm-2. The H2 density and the SO2 fractional abundance must be larger than 10E7cm-3 and 2 x 10E-7 respectively. The most likely alternatives for the nature of the hot and very dense condensation are discussed. From the large column densities of hot gas, the detection of the HC3N vibrationally excited lines and the large SO2 abundance, we favor the interpretation of a hot core heated by an intermediate mass protostar of 10E3 Lo. This indicates that the CepA HW2 region contains a cluster of very young stars.

The recent detection of shock-precursors toward the very young L1448-mm outflow offers us the possibility to study the grain chemistry during the first stages of the shock evolution, constraining the molecules ejected from grains and the species formed in gas phase. Observations of key molecules in the grain chemistry such as SiO, CH3OH, SO, CS, H2S, OCS, and SO2 toward this outflow are presented. The line profiles and the derived abundances show three distinct velocity regimes that trace the shock evolution: the preshock, the shock-precursor and the postshock gas. The SiO, CH3OH, SO, and CS abundances are enhanced with respect to the quiescent gas by 1 order of magnitude in the shock-precursor component, and by 3 orders of magnitude in the postshock gas. The derived SiO and CH3OH abundances are consistent with the recent ejection of these molecules from grains. Since H2S is only enhanced in the shock-precursor component, and OCS and SO2 are undetected, SO and CS are the most abundant sulfur-bearing species in the grain mantles of L1448-mm. The ejection of mainly SO and CS rather than H2S or OCS from grains, suggests that the sulfur chemistry will depend on the chemical "history" of the grain mantles in outflows and hot cores., Comment: 4 pages, 2 figures, accepted for publication in ApJL

Based on additional interferometric observations, we reanalysed the CO(2-1) and 3mm continuum emission of Q0957+561, a lensed QSO at a redshift of z=1.4141. The emission in the CO(2-1) lines reveals a gas-rich host galaxy with a peculiar double-peaked profile at one of the two lensed images. Our new interferometric CO maps of the host galaxy agree well with HST images obtained by Keeton et al. (2000) and we thus argue that the two velocity components arise from molecular gas in the disk of the host galaxy. We also present new model calculations, all in excellent agreement with recent time delay measurements and simulations., Comment: 8 pages, 5 figures, accepted for publication in A&A, Table1 corrected

Based on observations of the most abundant sulfur-bearing molecules (H2S, CS, NS, SO, H2CS, OCS, and SO2) carried out with the IRAM 30m telescope and SEST, we present the first analysis of the sulfur chemistry of an extragalactic source, the nuclear region of the starburst galaxy NGC 253. This is the first time that H2S and, tentatively, H2CS are detected towards the nucleus of a starburst galaxy. Source averaged fractional abundances of these molecules are a few 10^-9, except for CS and OCS which are more abundant (10^-8). Sulfur isotopic ratios, 32S/34S~8+-2 and 34S/33S>9, are measured through observations of 13CS, C34S, and C33S. A comparison with the observed relative abundances towards different prototypical Galactic sources suggests that the chemical composition of NGC 253 is similar to that found towards the molecular clouds complexes like Sgr B2 in the nuclear region of the Milky Way. The large overabundance of OCS compared to the predictions of time-dependent sulfur chemistry models supports the idea that OCS is likely injected into the gas phase from the grain mantles by low velocity shocks., Comment: Accepted for publication in ApJ. 19 pages, 3 figures

(Abridged) We present fine structure and recombination lines observations of the ionized gas toward a sample of 18 sources located within 300 pc of the center of the Galaxy (GC). The fine structure lines from [NII] and [SIII] have been detected in 16 sources. In 10 sources we have even detected the [OIII] 88 $\mu$m line. The measured N, S and Ne abundances are similar to those measured in the HII regions in the 5-kpc ring and in the nuclei of starburst galaxies. The fine structure lines ratios measured for all the sources can be explained by photo-ionization with an effective temperature of 32000-37000 K and an ionization parameter, $U$, of $-1>\log U > -3$. The highest excitation is found in the Radio Arc region but there must be more ionizing sources distributed over the Galactic center than the known clusters of massive stars. Most of the clouds are located far from the prominent continuum complexes (Sgr C, B ...). However, it is possible that the clouds are ionized by escaped photons from those complexes. The excitation ratios, effective temperature and ionization parameter measured in the GC are similar to those found in some low excitation starburst galaxies. The [NeIII]/[NeII] line ratios measured in the GC sources are consistent with the results of the Thornely et al. (2000) model for a short burst of massive star formation less than 8 Myr ago. We have also found that the [NeII] 13 $\mu$m ~ to far-infrared continuum ratio measured for the GC sources is similar to that of external galaxies, supporting the idea by Sturm et al. (2002) that the far-infrared continuum in Active Galaxies is dominated by dust heated by stellar radiation rather than by the AGN., Comment: Accepted by A&A

The 500 central pc of the Galaxy (hereafter GC) exhibit a widespread gas component with a kinetic temperature of 100-200 K. The bulk of this gas is not associated to the well-known thermal radio continuum or far infrared sources like Sgr A or Sgr B. How this gas is heated has been a longstanding problem. With the aim of studying the thermal balance of the neutral gas and dust in the GC, we have observed 18 molecular clouds located at projected distances far from thermal continuum sources with the Infrared Space Observatory (ISO). In this paper we present observations of several fine structure lines and the full continuum spectra of the dust between 40 and 190 microns. A warm dust component with a temperature between 27 and 42 K is needed to fit the spectra. We have compared the gas and the dust emission with the predictions from J-type and C-type shocks and photodissociation region (PDRs) models. We conclude that the dust and the fine structure lines observations are best explained by a PDR with a density of 10$^3$ cm^-3 and an incident far-ultraviolet field 10$^3$ times higher than the local interstellar radiation field. PDRs can naturally explain the discrepancy between the gas and the dust temperatures. However, these PDRs can only account for 10-30% of the total H2 column density with a temperature of ~ 150 K. We discuss other possible heating mechanisms (short version)., Comment: Accepted for publication by A&A

There is observational evidence that nuclear winds and X-rays can heavily influence the physical conditions and chemical abundances of molecular gas in the circumnuclear disks (CND) of Active Galactic Nuclei (AGN). In this paper we probe the chemical status of molecular gas in the CND of NGC1068, a prototypical Seyfert 2 galaxy. Precedent claims that the chemistry of molecular gas in the nucleus of NGC1068 is abnormal by galactic standards were based on the high HCN/CO luminosity ratio measured in the CND. Results from new observations obtained in this survey have served to derive abundances of molecular species such as SiO, CN, HCO+, HOC+, H13CO+ and HCO. These estimates are complemented by a re-evaluation of molecular abundances for HCN, CS and CO, based on previously published single-dish and interferometer observations of NGC1068. We report on the first detection of SiO emission in the CND of NGC1068. The estimated large abundance of SiO in the CND, X(SiO)~5-10x10^{-9}, cannot be attributed to shocks related to star formation, as there is little evidence of a recent starburst in the nucleus of NGC1068. Alternatively, we propose that silicon chemistry is driven by intense X-ray processing of molecular gas. We also report on the first extragalactic detection of the reactive ion HOC+. Most remarkably, the estimated HCO+/HOC+ abundance ratio in the nucleus of NGC1068, ~30-80, is the smallest ever measured in molecular gas. The abundances derived for all molecules that have been the subject of this survey are compared with the predictions of models invoking either oxygen-depletion or X-ray chemistry in molecular gas. Our conclusions favour an overall scenario where the CND of NGC1068 has become a giant X-ray Dominated Region (XDR)., Comment: 16 pages (including 9 figures and 6 tables); accepted by A&A

This paper deals with the heating and the ionization of the interstellar medium (ISM) in the 500 central pc of the Milky Way (hereafter Galactic center, GC). We review the results of the Infrared Space Observatory (ISO) observations of a sample of GC molecular clouds located far from thermal radiocontinuum or far-infrared sources. For the first time, we have been able to study in detail the dust continuum spectra from 40 to 190 microns founding a warm (30-40 K) dust component in addition to the well known 15-20 K component. Fine-structure lines observations have revealed the presence of diffuse ionized gas associated with the molecular clouds. The effective temperature of the ionizing radiation is higher than 33000 K. ISO has also allow us to measure the fraction of warm (~ 150 K) H2 in the GC clouds, which is on average of 30 %. The observations of the warm (a few 100 K) neutral gas are compatible with a Photon Dominated Region (PDR) scenario., Comment: 4 pages, 3 figures. To appear in the Proceedings of the 4th Cologne-Bonn-Zermatt-Symposium "The Dense Interstellar Medium in Galaxies" eds. S. Pfalzner, C. Kramer, C. Straubmeier, & A. Heithausen (Springer: Berlin)

We present the detection of the SiO v=0 J=2-1 and J=3-2 lines, and of the HCO 101-000 J=3/2-1/2 F=2-1 line at ambient velocities towards the molecular outflows in L1448-mm and L1448-IRS3. This is the first detection of HCO in a dark cloud. We have also measured lines of H13CO+, H13CN, HN13C, CH3OH, and N2H+. While the HCO and the SiO lines have the narrowest profiles with linewidths of 0.5 km s-1, the other lines have widths of 1km s-1. Towards L1448-mm, all lines except those of SiO and HCO, show two distinct velocity components centered at 4.7 and 5.2 km s-1. HCO is only observed in the 4.7 km s-1 cloud, and SiO in the 5.2 km s-1 component. The SiO abundance is 10E-11 in the 5.2 km s-1 clouds, one order of magnitude larger than in the 4.7 km s-1 component and in other dark clouds. The HCO abundance is 10E-11, similar to that predicted by the ion-molecule reactions models for the quiescent gas in dark clouds. The large change in the SiO/HCO abundance ratio (>150) from the 4.7 to the 5.2 km s-1 component, and the distribution and kinematics of the SiO emission towards L1448-mm suggest that the ambient SiO is associated with the molecular outflows. We propose that the narrow linewidths and the abundances of SiO in the ambient gas are produced by the interaction of the magnetic and/or radiative precursors of the shocks with the clumpy pre-shocked ambient gas., Comment: 4 pages, 2 figures; accepted for publication by ApJ Letters

In recent years large efforts have been made to detect molecular gas towards high redshifted objects. Up to now the literature reports on only two cases of CO-detection in quasars at a redshift between 1 and 2 - Q0957+561, a gravitationally lensed system at z=1.41 (Planesas et al. 1999), and HR10 at z=1.44 (Andreani et al. 2000). According to Planesas et al. (1999), 12CO(2-1) emission was detected towards both the lensed images of Q0957+561 with the IRAM Plateau de Bure Interferometer (PdBI). In contrast to the optical spectra of the two images which support the idea that they are images of one and the same object, the CO-spectra were surprisingly different: the southern image (named CO-B) shows a single blueshifted line whereas a double-peaked line profile with a blue- and a redshifted part appears towards the northern image (CO-A). Based on the observations and on simulations with a gravitational lens program, we are tempted to argue that the line profile traces the presence of molecular gas of a disk in the host galaxy around the quasar. We have now new observations with the PdBI providing the necessary sensitivity to corroborate our disk model., Comment: 4 pages, 1 figure, to appear in "Proceedings of the 4th Cologne-Bonn-Zermatt-Symposium", ed. S. Pfalzner, C. Kramer, C. Straubmeier, and A. Heithausen (Springer Verlag)

We have studied the feedback influence that the central engine of the Seyfert 2 galaxy NGC 1068 may have on the chemistry of the 200 pc circumnuclear gas disk (CND). With this purpose, we have conducted a multi-species/multi-transition survey of molecular gas in the CND of NGC 1068 using the IRAM 30m telescope. Abundances of several molecular species have been estimated, including HCN, CN, CS, HCO+, SiO and HOC+. We report on the detection of significant SiO emission in this galaxy, as well as on the first extragalactic detection of the active radical HOC+. We conclude that the chemistry of the molecular gas reservoir in the CND can be best explained in the framework of X-rays Dominated Regions (XDR) models., Comment: 2 pages, 1 figure; poster presented at "The Neutral ISM in Starburst Galaxies", workshop held in Marstrand (Sweden), June 23-27, 2003; to be published in ASP Conference Series

We present the main results of an extragalactic survey aiming to study the chemistry of molecular gas in a limited sample of starburst galaxies (SB) and AGN hosts. Observations have been carried out with the IRAM 30m telescope and the Plateau de Bure Interferometer (PdBI). The high resolution/sensitivity of the PdBI has made possible to obtain high quality images of the galaxies using specific molecular gas tracers of Shock Chemistry, Photon Dominated Regions (PDR) and X-ray Dominated Regions (XDR). The occurrence of large-scale shocks and the propagation of PDR chemistry in starbursts can be studied. We also discuss the onset of XDR chemistry in AGN., Comment: 4 pages, 2 figures; contributed talk at "The Neutral ISM in Starburst Galaxies", workshop held in Marstrand (Sweden), June 23-27, 2003; to be published in ASP Conference Series

We report the first detections of SO_2, NS and NO in an extragalactic source, the nucleus of the starburst galaxy NGC 253. Five SO_2 transitions, three groups of hyperfine components of NO and five of NS were detected. All three species show large abundances averaged over the inner 200 pc of NGC 253. With a relative abundance of a few 10^-7, the emission of the NO molecule is similar or even larger than that found in Galactic star forming regions. The derived relative molecular abundances for each molecule have been compared with those of prototypical Galactic molecular clouds. These results seem to confirm that large scale shocks dominate the chemistry of these molecules in the nucleus of NGC 253, ruling out a chemistry dominated by PDRs for the bulk of the gas., Comment: Accepted by A&A, 4 pages, 6 figures

NGC 2359 is a Wolf-Rayet (W-R) nebula partially bound by a rather dense and warm molecular cloud. We present the results derived from CO and $^{13}$CO fully sampled maps of the molecular material with angular resolutions up to 12". We have detected three different velocity components, and determined their spatial distribution and physical properties. The kinematics, morphology, mass and density are clearly stratified with respect to the W-R star. These features allow us to learn about the recent evolutionary history of HD 56925, because the multiple layers could be associated to several energetic events which have acted upon the surrounding circumstellar medium. Hence, a careful study of the different shockfronts contain clues in determining the present and past interaction of this evolved massive star with its surroundings. From the analysis of the mass-loss history in massive stars like HD 56925, we suggest that the multiple layers of shocked molecular gas are likely to be produced during the earlier LBV phase and/or the actual W-R stage of HD 56925., Comment: Accepted by A&A. 12 pages, 7 figures

We present infrared and millimeter observations of molecular gas, dust and ionized gas towards a sample of clouds distributed along the 500 central pc of the Galaxy. The clouds were selected to investigate the physical state, in particular the high gas temperatures, of the Galactic center region (GCr) clouds located far from far-infrared of thermal radio continuum sources. We have found that there is ionized gas associated with the molecular gas. The ionizing radiation is hard (~35000 K) but diluted due to the inhomogeneity of the medium. We estimate that ~30 % of the warm molecular gas observed in the GCr clouds is heated by ultra-violet radiation in photo-dissociation regions., Comment: 5 pages, to be published in: Astron. Nachr., Vol. 324, No. S1 (2003), Special Supplement "The central 300 parsecs of the Milky Way", Eds. A. Cotera, H. Falcke, T. R. Geballe, S. Markoff

We present a high-resolution (~ 5'') image of the nucleus of M82 showing the presence of widespread emission of the formyl radical (HCO). The HCO map, the first obtained in an external galaxy, reveals the existence of a structured disk of ~ 650 pc full diameter. The HCO distribution in the plane mimics the ring morphology displayed by other molecular/ionized gas tracers in M82. More precisely, rings traced by HCO, CO and HII regions are nested, with the HCO ring lying in the outer edge of the molecular torus. Observations of HCO in galactic clouds indicate that the abundance of HCO is strongly enhanced in the interfaces between the ionized and molecular gas. The surprisingly high overall abundance of HCO measured in M82 (X(HCO) ~ 4x10^{-10}) indicates that its nuclear disk can be viewed as a giant Photon Dominated Region (PDR) of ~ 650 pc size. The existence of various nested gas rings, with the highest HCO abundance occurring at the outer ring (X(HCO) ~ 0.8x10^{-9}), suggests that PDR chemistry is propagating in the disk. We discuss the inferred large abundances of HCO in M82 in the context of a starburst evolutionary scenario, picturing the M82 nucleus as an evolved starburst., Comment: 13 pages, 3 figures, to appear in ApJ Letters; corrected list of authors

We present images of the J=10-9 rotational lines of HC3N in the vibrationally excited levels 1v7, 1v6 and 1v5 of the hot core (HC) in Orion KL. The images show that the spatial distribution and the size emission from the 1v7 and 1v5 levels are different. While the J=10-9 1v7 line has a size of 4''x 6'' and peaks 1.1'' NE of the 3 mm continuum peak, the J=10--9 1v5 line emission is unresolved (<3'') and peaks 1.3'' south of the 3 mm peak. This is a clear indication that the HC is composed of condensations with very different temperatures (170 K for the 1v7 peak and $>230$ K for the 1v5 peak). The temperature derived from the 1v7 and 1v5 lines increases with the projected distance to the suspected main heating source I. Projection effects along the line of sight could explain the temperature gradient as produced by source I. However, the large luminosity required for source I, >5 10^5 Lsolar, to explain the 1v5 line suggests that external heating by this source may not dominate the heating of the HC. Simple model calculations of the vibrationally excited emission indicate that the HC can be internally heated by a source with a luminosity of 10^5 Lsolar, located 1.2'' SW of the 1v5 line peak (1.8'' south of source I). We also report the first detection of high-velocity gas from vibrationally excited HC3N emission. Based on excitation arguments we conclude that the main heating source is also driving the molecular outflow. We speculate that all the data presented in this letter and the IR images are consistent with a young massive protostar embedded in an edge-on disk., Comment: 13 pages, 3 figures, To be published in Ap.J. Letters

We present some recent studies on the physical conditions and the chemistry of the interstellar medium (ISM) in the Galactic center region (GCR). Large scale shocks in the context of a bar potential can play a role in explaining the observed properties, at least in some particular regions. Alternatively, we propose that the observed properties (inhomogeneity, high temperatures of the molecular gas, rich chemistry,...) of the GCR ISM can be the consequence of the recent past ($10^6-10^7$ years ago) of massive star formation in the GCR., Comment: Slightly enlarged version of the Contribution to the conference "The evolution of galaxies II: basic building blocks", Eds. Sauvage, Vigroux, Schaerer, Madden. 2 pages

We present Infrared Space Observatory (ISO) observations of fine structure lines toward the Radio Arc region, close to Sgr A, in the Galactic center region (GCR). The ionization at large scale is dominated by the clusters of massive stars in this region: the Quintuplet and the Arches cluster. Any other possible mechanism as interaction with the magnetic fields revealed by the Non-Thermal Filaments (NTFs) must play a minor role. The radiation in this area is relatively hard ($T_\mathrm{eff}\sim 33-35$ kK) but diluted. It reaches large distances due to the inhomogeneity of the medium., Comment: 2 pages, 2 figures. Contribution to the conference "The evolution of galaxies II: basic building blocks", Eds. Sauvage, Vigroux, Schaerer, Madden, Use kluwer.cls

In this Letter we present the first images of the emission of SiO and H13CO+ in the nucleus of the starburst galaxy M82. Contrary to other molecular species that mainly trace the distribution of the star-forming molecular gas within the disk, the SiO emission extends noticeably out of the galaxy plane. The bulk of the SiO emission is restricted to two major features. The first feature, referred to as the SiO supershell, is an open shell of 150 pc diameter, located 120 pc west from the galaxy center. The SiO supershell represents the inner front of a molecular shell expanding at 40 km/s, produced by mass ejection around a supercluster of young stars containing supernova remnant SNR 41.95+57.5. The second feature is a vertical filament, referred to as the SiO chimney, emanating from the disk at 200 pc east from the galaxy center. The SiO chimney reaches a 500 pc vertical height, and it is associated with the most prominent chimney identified in radio continuum maps. The kinematics, morphology, and fractional abundances of the SiO gas features in M82 can be explained in the framework of shocked chemistry driven by local episodes of gas ejection from the starburst disk., Comment: 10 pages, 2 figures, published in ApJLetters, 2001

(Short version) We present an analysis of selected fine structure lines observed ISO toward the Radio Arc in the Galactic center region (GCR). We study the density of the ionized gas and the large scale ionization structure in a region of ~30x30 pc^2 by means of the NeIII 15.6 mum/NeII 12.8 mum and NIII 57 mum/NII 122 mum line ratios. The electron densities (n_e) derived from the OIII lines ratio indicate the presence of diffuse ionized material with n_e of \~10^{1.8-2.6} cm^{-3}. The NIII/NII ratio show two clear gradients, one pointing toward the Quintuplet cluster and the other pointing toward the Arches cluster. The model used to explain the ionization structure shows that the large scale ionization of the whole region can be accounted for by the UV radiation produced by the Quintuplet and the Arches cluster. Any other ionization mechanism should play a minor role. We also investigate the influence of the clusters on the bubble of warm dust seen in the MSX infrared images. The warm dust is well correlated with the ionized gas indicating that the dust is also heated by the radiation from both clusters. Furthermore, the elliptical rather than circular symmetry of some structures like the Thermal Filaments can also be explained when one considers the combined effects of both the Arches and the Quintuplet clusters. The bubble is filled with continuum emission of hard X rays and with emision from the 6.4 keV line of neutral or low ionized Fe., Comment: 13 pages, 5 figures included in the paper and two independent PNG figures, to be published in A&A

We present HHT observations in the N=3-2 rotational transition of the CN radical toward selected positions of the Trapezium region and of the molecular Ridge in the Orion molecular cloud. Two of the positions in the Ridge were also observed in the N=2-1 line of CN and 13CN. The N=3-2 CN lines have been combined with observations of the N=2-1 and N=1-0 transitions of CN, and of the N=2-1 of 13CN to estimate the physical conditions and CN abundances in the molecular gas. We analyze in detail the excitation of the CN lines and find that the hyperfine ratios of the N=3-2 line are always close to the Local Thermodynamic Equilibrium (LTE) optically thin values even in the case of optically thick emission. This is due to different excitation temperatures for the different hyperfine lines. From the line intensity ratios between the different CN transitions we derive H_2 densities of ~10^5cm^-3 for the molecular Ridge and of ~3x10^6cm^-3 for the Trapezium region. The CN column densities are one order of magnitude larger in the Ridge than in the Trapezium region, but the CN to H_2 ratio is similar both in the Trapezium and in the Ridge. The combination of the low CN column densities, high H_2 densities and relatively high CN abundances toward the Trapezium region requires that the CN emission arises from a thin layer with a depth along the line of sight of only \~5x10^15cm. This high density thin layer of molecular gas seems to be related with material that confines the rear side of the HII region Orion A. However the molecular layer is not moving as expected from the expansion of the HII region, but it is ``static'' with respect to the gas in the molecular cloud. We discuss the implication of a high density ``static'' layer in the evolution of an HII region., Comment: 16 pages, 5 figures,accepted for ApJ

We report the detection of the (1,1) and (2,2) metastable lines of ammonia (NH_3) in the molecular cloud associated with the Wolf--Rayet (WR) nebula NGC 2359. Besides the CO and H_2, this is the first molecule detected in the environs of a WR star. Width (3 km/s) and radial velocity (54 km/s) indicate that the NH$_3$ lines arises from the molecular cloud which is interacting with the WR star. The rotational temperature derived from the (1,1) and (2,2) line intensity ratios is about 30 K, significantly larger than the typical kinetic temperature of the ambient gas of 10 K. The derived NH_3 abundance is 10^{-8}. Linewidth, abundance and kinetic temperature can be explained if NH_3 is released from dust grain mantles to the gas phase by shocks produced by the expansion of the bubble created by the WR stellar wind. We briefly discuss the implications of the detection of warm NH_3 associated with a WR star in connection to the hot NH_3 emission detected in the Galactic Center and in the nuclei of external galaxies., Comment: Accepted by ApJ Letters. 4 pages, 1 PS figure. Uses aastex.cls

The Infrared Space Observatory (ISO) has shown the complexity of the Galactic center (GC) Interstellar medium (ISM) detecting, not only large column densities of warm molecular gas (H2), but the emission of neutral atoms and ions of low ionization potential (CII, OI, SiII,...) that should arise in shocked or photon-dominated regions (PDRs). In addition, ISO has also detected emission from ions like SIII, NeII, ArII, or NII (in some clouds we have even detected NeIII and OIII) that should arise from HII regions that were previously unsuspected due to the non-detection of Hydrogen recombination lines. Here we review some ISO results on the large scale study of the GC ISM and in particular, on the heating mechanisms of the clouds. Although, shocks should play an important role on the physics and chemistry of the GC ISM, ISO shows that the effect of radiation on the heating of the gas cannot be ruled out with the simple argument that the dust temperature is lower than that of the gas., Comment: 4 pages, 1 figure included in the paper and two independentGIF figures, to be published in the proc. of 'The Promise of FIRST' symposium. ESA SP-460

We present observations of C2H5OH toward molecular clouds in Sgr A, Sgr B2 and associated with thermal and non-thermal features in the Galactic center. C2H5OH emission in Sgr A and Sgr B2 is widespread, but not uniform. C2H5OH emission is much weaker or it is not detected in some molecular clouds in both complexes, in particular those with radial velocities between 70 and 120 km/s. While most of the clouds associated with the thermal features do not show C2H5OH emission, that associated with the Non-Thermal Radio Arc shows emission. The fractional abundance of C2H5OH in most of the clouds with radial velocities between 0 and 70 km/s in Sgr A and Sgr B2 is relatively high, of few 1e-8. The C2H5OH abundance decreases by more than one order of magnitude (aprox. 1e-9) in the clouds associated with the thermal features. The large abundance of C2H5OH in the gas-phase indicates that C2H5OH has formed in grains and released to gas-phase by shocks in the last aprox. 1e5 years., Comment: In press in Astrophysical Journal Letters 7 pages, 1 table, 1 figure

NGC 2359 is an optical nebula excited by the powerful wind and the radiation of the Wolf-Rayet star HD 56925. We have investigated the interaction between this massive star and the surrounding neutral gas by analyzing the large-scale 21cm-HI emission and by mapping the nebula in the J = 1-0 and the J = 2-1 lines of CO. We found a conspicuous (70 x 37 pc) HI shell, expanding at 12 km/s, likely produced during the main-sequence phase of the star. The molecular gas towards NGC 2359 shows three velocity components. Two of these components, A1 and A2, have narrow linewidths (1-2 km/s) and radial velocities of 35-38 and 64-68 km/s, respectively. The third component is detected at radial velocities between 50 and 58 km/s and has a broader profile (up to 5.5 km/s). Furthermore, this component is morphologicaly related with the nebula and has a velocity gradient of a few km/s. We have also estimated the physical parameters of the molecular gas by means of a LVG modelling of the CO emission. The gas projected onto the southern HII region of the nebula has low CO column density and is rather hot, probably up to 80 K. Several profiles of the 13CO J = 1-0 line near the peak of the emission, together with a weak emission bridge between the broad and one of the narrow components (component A2), suggest the presence of a shock front acting in the southern part of the nebula. This shock was likely produced in a previous RSG/LBV phase of HD 56925., Comment: Accepted by A&A. 10 pages, 5 figures

We present ISO observations of several H2 pure-rotational lines (from S(0) to S(5)) towards a sample of 16 molecular clouds distributed along the central ~ 500 pc of the Galaxy. We also present C18O and 13CO J=1->0 and J=2->1 observations of these sources made with the IRAM-30m telescope. With the CO data we derive H2 densities of 10e(3.5-4.0) cm-3 and H2 column densities of a few 10e22 cm-2. We have corrected the H2 data for ~ 30 magnitudes of visual extinction using a self-consistent method. In every source, we find that the H2 emission exhibits a large temperature gradient. The S(0) and S(1) lines trace temperatures (T) of ~150 K while the S(4) and S(5) lines indicate temperatures of ~ 600K. The warm H2 column density is typically ~1-2 x 10e22 cm-2, and is predominantly gas with T=150 K. This is the first direct estimate of the total column density of the warm molecular gas in the Galactic center region. These warm H2 column densities represent a fraction of ~ 30 % of the gas traced by the CO isotopes emission. The cooling by H2 in the warm component is comparable to that by CO. Comparing our H2 and CO data with available ammonia NH3 observations from literature one obtains relatively high NH3 abundances of a few 10e(-7) in both the warm and the cold gas. A single shock or Photo-Dissociation Region (PDR) cannot explain all the observed H2 lines. Alternatives for the heating mechanisms are discussed., Comment: 14 pages including figures, to be published in A&A

We present single dish and interferometric maps of several rotational transitions of HC3N vibrationally excited levels towards Sgr B2. The single dish maps show, for the first time, new four bright clumps (Sgr B2R1 to B2R4) in the ridge connecting the main cores Sgr B2M and Sgr B2N, and a low brightness extended region to the west of the ridge (Sgr B2W). The physical properties and the kinematics of all hot cores have been derived from the HC3N* lines. Our high angular resolution images show that the Sgr B2N hot core breaks in two different hot cores, Sgr B2N1 and N2, with different radial velocities and separated by 2 arcsec in declination. We find that the excitation of the HC3N* emission in all hot cores can be represented by a single temperature and that the linewidth of the HC3N* rotational lines arising from different vibrational levels systematically decreases as the energy of the vibrational level increases. The systematic trend in the linewidth is likely related to the increase of the velocity as the distance to the exciting source increases. The different HC3N abundances in the hot cores reflect different stages of evolution due to time dependent chemistry and/or photo-dissociation by UV radiation from nearby HII regions. We propose that Sgr B2M and B2N contain a cluster of 20-30 hot cores and that the Sgr B2R1-B2R4 hot cores represent isolated formation of massive stars., Comment: 15 pages, 9 figures, in press in Astronomy and Astrophysics

In this letter we present a map of the GC in the 1-0 line of SiO covering the same region than the ASCA observations of the Fe 6.4 keV line. The SiO emission is restricted to molecular clouds with radial velocity between 10 and 60 km/s in the Sgr A and Sgr B complexes. We find a correlation between the SiO morphology and the spatial distribution of the Fe 6.4 keV line, on the large scale and also within Sgr A and Sgr B. The SiO abundance increases by a factor of 20 in the regions with strong Fe 6.4 keV line. This indicates that the Fe 6.4 keV line mainly arises from molecular clouds with large gas phase abundance of refractory elements. We discuss the implications of the correlation on the origin of the hard X-rays, and the heating and the chemistry of the molecular clouds in the GC, Comment: 4 pages, 2 figures

We present ISO observations of the S(0), S(1), S(2), and S(3) rotational lines of molecular hydrogen from two molecular clouds near the Galactic Center (GC). We have also measured continuum dust emission at infrared wavelengths with ISO and the rotational radio lines J=1-0 of 13CO and C18O and J=2-1 of C18O with the IRAM-30m telescope. Using the dust continuum spectra and the CO lines we derive a total visual extinction of 15-20 magnitudes toward these GC clouds. After correcting the H2 data for extinction, the gas temperatures are \~250 K and the column densities of warm gas are ~2e21 cm-2. This is the first direct measure of the H2 column densities of the warm component; with this, we estimate an NH3 abundance in the warm gas of ~ 2e-7. The column density of warm gas is, at least, a factor of 100 larger than the corresponding column densities derived from the warm dust. The observed ortho-to-para ratio (OTPR) is ~ 1, clearly below the local thermodynamical equilibrium (LTE) OTPR for gas at 250 K of ~3. Low velocity shocks (~ 10 km/s) are the most likely explanation for the column densities of warm gas and dust and the non-LTE H2 OTPR., Comment: 12 pages, 5 figures, accepted by A&A

This paper presents the first high-resolution SiO map made in an external galaxy. The nucleus of the nearby barred spiral NGC253 has been observed simultaneously in the v=0, J=2-1 line of SiO and in the J=1-0 line of H13CO+ with the IRAM interferometer, with a resolution of 7.5"x2.6". Emission from SiO and H13CO+ is extended in the nucleus of NGC253. The bulk of the SiO/H13CO+ emission arises from a 600pcx250pc circumnuclear disk (CND) with a double ringed structure. The inner ring, of radius r=60pc, viewed edge-on along PA=51deg, hosts the nuclear starburst; the outer pseudo-ring opens out as a spiral-like arc up to r=300pc. The kinematics of the gaseous disk, characterized by strong non-circular motions, is interpreted in terms of the resonant response of the gas to the barred potential. The inner ring would correspond to the inner Inner Lindblad Resonance(iILR), whereas the outer region is linked to the onset of a trailing spiral wave across the outer ILR (oILR). Most notably, we report the detection of a molecular gas counterpart of the giant outflow of hot gas, previously seen in X-ray and optical lines, and tentatively identified as a dust chimney in the the 450mu continuum band.The SiO shows a high average fractional abundance in the CND of X(SiO)=1.5x10E-10. This is more than an order of magnitude above the predicted value of a PDR. Moreover, X(SiO) varies at least by an order of magnitude between the inner starburst region, which dominates the global emission, where we derive X(SiO)=1--2x10E-10, and the outer region, where X(SiO) reaches a few 10E-9. SiO abundance is also significantly enhanced in the outflow (X(SiO)=3--5x10E-10). Different mechanisms are explored to explain the unlike chemical processing of molecular gas within the nucleus., Comment: 10 pages (.tex) 8 figures (.fx) 1 table (.t1)

We present SWS and LWS ISO observations towards a strip across the photodissociation region (PDR) in the reflection nebula NGC 7023. SWS02 and LWS01 spectra have been taken towards the star and the brightest infrared filaments located NW and SW from the star (hereafter NW and SW PDRs). In addition, SWS02 spectra have been taken towards two intermediate positions. While all the PDR tracers (the [CII] 157.7$\mic$, [OI] 63.2 and 145.6$\mic$, [HI] 21cm and the H$_2$ rotational lines) present a ring-like morphology with the peaks toward the NW and SW PDRs and a minimum around the star, the SiII emission is filling the hole of this ring with the peak towards the star. This morphology can only be explained if the SiII emission arise in the lowest extinction layers of the PDR (A$_v$ $<$ 2 mag) and the HII region. At least 20% -- 30% of the Si must be in gas phase in these layers. For A$_v$ $\geq$ 2 mag, the Si is mainly in solid form ($\delta$ Si = -1.3). In both, the NW and SW PDRs, the intensities of the H$_2$ rotational lines can only be fitted by assuming an ortho-to-para-H$_2$ ratio lower than 3 in gas with rotation temperatures from 400 to 700 K. Therefore, there is a non-equilibrium OTP ratio in the region. The comparison between the OTP ratio derived from H$_2$ vibrational lines and the pure H$_2$ rotational lines, shows that the OTP ratio increases from $\sim$ 1.5 to 3 across the photodissociation region with larger values in the less shielded gas (A$_v$$<$ 0.7 mag). This behavior is interpreted as a consequence of an advancing photodissociation front., Comment: 14 pages, 6 figures, other comments

We present high sensitivity and high angular resolution images of the high velocity (vLSR>30kms^-1) CO emission in the J=1-0 and J=2-1 lines of the Orion KL region. These results reveal the morphology of the high-velocity CO emission at the most extreme velocities. High velocity emission have been only detected in two regions: BN/KL (IRc2/I) and Orion-S. The Orion-S region contains a very young (dynamical age of 10^3years), very fast (~110kms^-1) and very compact (<0.16pc) bipolar outflow. From the morphology of the high-velocity gas we estimate that the position of the powering source must be ~20'' north of FIR4. For the IRc2/I molecular outflow the morphology of the moderate velocity (<60kms^-1) gas shows a weak bipolarity around IRc2/I. The gas at the most extreme velocities does not show any bipolarity around IRc2/I, if any, it is found ~30'' north from these sources. The blue and redshifted gas at moderate velocities shows similar spatial distribution with a systematic trend for the size of the high-velocity gas to decrease as the terminal radial velocity increases. The size-velocity relationship is fitted with a simple velocity law which considers a highly collimated jet and entrained material outside the jet moving in the radial direction. We also find that most of the CO outflowing at moderate velocities is located at the head of the jet. Our results and the spatial distribution and kinematics of the shock tracers in this outflow can be explained if the IRc2/I outflow is driven by a precessing jet oriented along the line of sight., Comment: 15 pages, 10 figures

We present high angular resolution (12"-24") and high sensitivity 12CO and 13CO J=2-1 and J=1-0 observations of the HH 1-2 outflow. The observations show the molecular counterpart, moving with a velocity of approx. 30 km/s, of the optical bipolar system driven by the VLA 1 embedded source. Along the optical jet there are certain regions where the molecular gas reaches deprojected velocities of 100-200 km/s, and that we interpret as the molecular jet. The bipolar CO outflow has a length of approx. 260" with a curved morphology towards the North where it extends beyond the HH 1 object (approx. 120") . Two new molecular outflows have been detected, one arising from IRAS 05339-0647 which excites the HH 147 optical flow and another powered by VLA 2 which drives the HH 144 optical outflow. The molecular outflow driven by the VLA 3 source is also clearly detected and spatially resolved from the VLA 1 main outflow., Comment: 14 pages, 4 figures, accepted ApJLett