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Solid state SiS2 is proposed as the material responsible for the recently discovered 21 micrometer emission feature that is observed in the carbon-rich circumstellar shells of certain protoplanetary nebulae. Sulfurized SiC, or SiS2 mantles on grains of either SiC or a:C-H are discussed as possible forms for which no spectroscopic laboratory observations yet exist. The identification with a relatively minor species and required special abundance ratios are consistent with the low incidence rate that the 21 micrometer feature presents in the population of carbon rich objects. It is also consistent with the lack of a good correlation between the 21 micrometer feature and the other solid-state spectroscopic features that have been observed in protoplanetaries that would be expected if the feature arose from molecules composed of H, C, N, and O. SiS2 condensate is consistent with the circumstellar shell temperature range, T(sub CS) approximately equal to or less than 150 K, at which the feature appears, and the available mass of SiS2, M(sub SiS2) approx. = 5 x 10(exp -6) solar mass, that is possible in the circumstellar shell.

Results of observations of the carbon star TX Psc at high resolution in the 4000/cm spectral region and at moderate resolution from 2500 to 8000/cm are reported. The opacity sampling technique is employed to present model atmospheres of carbon stars with normal solar oxygen abundance and deep envelope composition that include HCN and C2H2. The oxygen abundance of TX Psc is found to be more accurately represented by a deep envelope composition depleted in oxygen by roughly two orders of magnitude than by a solar oxygen abundance. Polyatomic opacities influence the CO line depths and the derived oxygen abundance as a second-order effect. Polyatomic bands appear to be far too strong in the models, implying the need for another source of opacity to backwarm the outer atmosphere and thereby limit the polyatomic band depths. Dust, rather than polyatomic molecules, is a candidate for the backwarming opacity.

The availability of a reclassification of the IRAS LRS Atlas of spectra using a new Bayesian classification procedure (AutoClass) is announced. The classes of objects which result from the application of the AutoClass algorithm include many of the previously known LRS classes. New classes which have interesting astronomical and astrophysical interpretations were also found. Techniques, such as the AutoClass algorithm, have a bright future in the arena of astronomical classification problems.

Motivated by recent work which hints at a possible deficiency of hydrogen in non-Mira N-type carbon stars and to further explore the parameter space of chemical composition, computations have been made of a series of hydrogen-deficient models for carbon stars. For these models Teff = 3000 K, and log g = 0.0. Solar abundances are used for all elements except for carbon (which is enhanced to give C/O = 1.05), hydrogen, and helium. As the fractional abundance of hydrogen is decreased, being replaced by helium, the temperature-optical depth relation is affected only slightly, but the temperature-pressure relation is changed. The most striking change in the emergent flux is the decrease of the H(-) peak at 1.65 micron compared with the blackbody peak at 1.00 micron.

In this letter, far-infrared spectrophotometry (30-55 microns) and photometry (53-200 microns) are presented which define, for the first time, the long wavelength limit of the previously unidentified 30 micron emission feature found in certain extreme carbon star spectra. The spectral similarities are sufficiently similar to those of solid MgS that MgS is proposed to be the band carrier. This is interpreted as the first direct evidence that chemical surface reactions occur on dust grains in circumstellar environments. The presence of MgS indicates that either the oxygen abundance is relatively low and/or the sulfur abundance is high in extreme carbon stars.

Laboratory spectra and mass absorption coefficients of MgS, CaS, FeS, SiS2, FeS2, Fe3C, and a commercial iron carbide are presented over the wavelength range 125-15 microns. These spectra confirm that MgS is the most likely source of the unidentified 30-micron emission in carbon-rich sources and that FeS, Fe3C, and 'iron carbide' cannot be responsible for this feature although they could contribute to the continuum in this region. CaS and FeS2 may contribute to the 30-micron feature; however, both higher resolution and higher precision astronomical observations are needed before their presence can be established. SiS2 has a peak near 22 microns and therefore cannot be a significant component of the dust in such regions.

For galactic N and late R type irregularly variable carbon stars, a comparison is made of airborne infrared spectrophotometry to spectral flux distributions derived from model atmospheres. Although the agreement is good in several respects, the H(-) emission peak at 1.6 microns, so prominent in the models, is significantly weakened in the stellar spectrophotometry. It seems unlikely that molecular bands in the stars can completely obliterate this peak. A plausible explanation is that hydrogen is deficient in these stars, most probably from an episode of mass loss. The resultant cold shells surrounding these stars should be amenable to observation by IRAS, or other far-infrared observatories.

The spectra of carbon stars is discussed. Spectral flux curves, molecular bands, molecular absorptions, stellar temperatures, and comparison of emission features in various carbon stars are among the topics considered.

High signal-to-noise ratio spectra in the range of 5-8 microns of four sources embedded in molecular clouds are examined using low-temperature laboratory measurements of the 5-8-micron spectra of simple molecules and their mixtures. The absorption, apparent in all four sources, is characterized by highly distinct features ranging from two relatively narrow bands at 6.0 and 6.8 microns in W33A to a broad, shallow, and partially structured feature extending from 5.2 to 7.8 microns in Mon R2-IRS2, BN, and NGC2264. The first feature (W33A) is explained by the OH bending mode in H2O and the CH deformation modes in saturated hydrocarbons; while the second feature (Mon R2-IRS2-type) is explained by the presence of a mixture of saturated and unsaturated hydrocarbons possibly containing strongly electronegative groups.

Techniques for determining the composition of small dust grains in interstellar matter are discussed. The best way to study the composition of interstellar grain mantles is by infrared spectroscopy. The absorption features in a complete infrared spectrum from 2 to 15 microns can be used as fingerprints to identify the absorbing molecule. Ground-based observations around 3 microns confirmed the presence of H2O ice in interstellar grain mantles, through the detection of the 3.08 micron OH stretching vibration. The detection of other molecules, in particular the carbon bearing molecules, is however hampered by atmospheric absorption in the 5-8 micron region and the presence of the strong ice and silicate bands, which dominate the 3 and 10 micron region respectively. Kuiper Airborne Observatory observations of the 5-8 micron region of the spectrum are therefore extremely important to determine the composition of interstellar grain mantles. The 5 to 8 micron spectra of molecular cloud sources was obtained using a 24 detector grating spectrometer. An important characteristic of this spectrometer is that the whole spectrum is obtained simultaneously. It is therefore relatively easy to correct for atmospheric transmission.

NGC 7027 was observed with a multichannel grating spectrometer from 5.2 to 7.5 microns at a spectral resolving power of 120-200. Two new dust emission features are resolved at 5.62 and 6.95 microns, and for the first time the Ni II fine-structure line at 6.64 microns is detected. It is shown that a single molecular dust constituent might account for six of the nine observed dust features between 2 and 14 microns. The strength of the Ni II line indicates either that Ni is not depleted in the neutral gas, or that the line is formed at high density.

Infrared spectrophotometry of the R-type carbon star HD 19557 is presented. Two unusual spectroscopic features are seen: a 3.1 micron band is lacking and a 2.8 micron band is present. Identifications are proposed for three previously unreported stellar absorption bands with electronic sequences of C2, CN, and C2H. The latter is proposed to be responsible for the 2.8 micron feature. The atmospheric structure of the star is studied with synthetic spectra, and an effective temperature between 2600 K and 3000 K is suggested. No SiC emission is seen at 11.3 microns, indicating that grain formation is not a viable process around the star. The lack of dust in R stars may suggest a salient difference between R and N types.

Spectra of several carbon stars in the two micron region are examined and compared with synthetic spectra from model atmospheres. Molecular hydrogen has been directly observed in carbon stars for the first time through the quadrupole 1-0 S(1) line at 4712.9/cm. It is definitely present in several Mira variables, and is definitely not present in several irregular variables and one Mira variable. A discrepancy between the predicted and observed line depths at different temperatures is shown. Resolution of the discrepancy by change of temperature alone would require an upward revision of the present effective temperature scale by at least 600 K. Several possible resolutions of the dilemma are briefly examined.

The water ice absorption band at 3.1 microns has been observed in HD 29647, which is a late B type star with an anomalous ultraviolet extinction curve. The interpretation is that ice mantles are present on the dust grains in the intervening cloud and that these mantles are responsible for suppressing the 2200 A interstellar absorption feature. This is the first observation of both the 2200 A region and the 3.1 micron interstellar absorption feature toward the same star. A comparison of recent UV laboratory data of water ice with the UV spectrum of HD 29647 further supports the presence of water ice mantles in the same column density as that observed in the infrared. The diffuse interstellar features have been reported to be weakened in this star, consistent with their origin being on grain core surfaces, rather than in mantles or gaseous molecules.

Complete 0.75-13 micron spectrometry of a carbon-rich, Mira-class variable star is presented for the first time. It is noted that although the near-infrared is dominated by photospheric absorption bands of the CN red system, the infrared becomes progressively dominated by the bands of the polyatomic molecules HCN and C2H2. Since the band at 3.1 microns is known to be due to HCN and C2H2, it is possible to associate bands at 1.04, 1.53, 1.85, 2.5, 2.7, 3.56, 3.85, 4.8, and 7.1 microns with HCN and C2H2. The spectrum suggests that radiative transfer in the carbon Mira class cannot be discussed quantitatively without the inclusion of HCN and C2H2 opacity. On the basis of the carbon star models of Querci and Querci (1974), it is deduced that the abundance ratio of HCN to C2H2 can be used to indicate whether 3-alpha-processed or CNO-processed material is in the outer atmosphere. An 11.3 micron SiC dust-emission feature is present, although it differs significantly from the 11.7 micron SiC feature in Y CVn. A featureless emission is present from 4 to 13 microns and can be ascribed to optically thin graphite grains having a temperature of 450 K.

The spectra of carbon stars have been synthesized from the models of Querci, Querci, and Tsuji and Querci and Querci in the region of the 1-0 S(1) vibration-rotation quadrupole line of H2. The line is shown to be sufficiently strong to be seen against the numerous lines of the CN red system for models with effective temperatures less than about 2700 K. The usefulness of the line as a diagnostic of the atmosphere is discussed, and a comparison with the measured spectra of UU Aur and S Cep is made. It is concluded that the outer atmospheric layers of carbon stars are significantly warmer than the models predict. An additional opacity source in the outer layers is required.

Low-resolution spectra of IRC + 10216 have been obtained from 2 to 8.5 microns from NASA's Kuiper Airborne Observatory at an altitude of 12.5 km (41,000 feet). Observations were made during 1976 January and 1977 February. In both sets of data, the spectral flux reaches its maximum between 6.0 and 6.6 microns and the previously reported 3.1-micron feature is observed; no obvious new absorption features have been found. The new data together with other spectral data and measurements of the spatial extent of IRC + 10216 impose conditions that must be met by models of the continuum. Several simple models for 2-8.5 micron radiation are examined. The new continuum data impose a constraint on the size of the grains in the cooler, optically thin part of the object. Earlier photometry has been combined with the present data to yield an improved value of the average period: 644 + or - 17 days. It appears that the variability is irregular and that the minima have been deeper in recent years than they were in 1965-1969.

The paper deals with spectrophotometric observations covering the essentially complete wavelength interval between 1.2 and 30.0 microns. The observations confirm the identification of the C3 band at 5.2 microns. They show that if SiC2 is present, the SiC1 absorption band at 5.7 microns would be obscured by C3 at a 1% spectral resolution. Silicon carbide emission at 11.5 microns exists simultaneously with C3 absorption at 5.2 microns, requiring a contribution of both species to the violet opacity of Y CVn.

With a 1.7% spectral-resolution filter-wheel spectrometer, 1.2-5.2-micron spectra have been obtained for a sample of carbon stars. The previously unidentified 3.9-micron band is attributed to a combination of CS and C2H2. The first observation of SiO in a carbon star is also reported.