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The crust of accreting neutron stars plays a central role in many different observational phenomena. In these stars, heavy elements produced by H-He burning in the rapid proton capture (rp-) process continually freeze to form new crust. In this paper, we explore the expected composition of the solid phase. We first demonstrate using molecular dynamics that two distinct types of chemical separation occur, depending on the composition of the rp-process ashes. We then calculate phase diagrams for three-component mixtures and use them to determine the allowed crust compositions. We show that, for the large range of atomic numbers produced in the rp-process ($Z\sim 10$--$50$), the solid that forms has only a small number of available compositions. We conclude that accreting neutron star crusts should be polycrystalline, with domains of distinct composition. Our results motivate further work on the size of the compositional domains, and have implications for crust physics and accreting neutron star phenomenology., 8 pages, 4 figures, Submitted to ApJ, this article supersedes arXiv:1709.09260

We present a series of high-resolution, three-dimensional hydrodynamics simulations of a gravitationally unstable solar nebula model. The influences of both azimuthal grid resolution and the treatment of thermal processes on the origin and evolution of gravitational instabilities are investigated. In the first set of simulations, we vary the azimuthal resolution for a locally isothermal simulation, doubling and quadrupling the resolution used in a previous study; the largest number of grid points is (256, 256, 64) in cylindrical coordinates (r, , z). At this resolution, the disk breaks apart into a dozen short-lived condensations. Although our previous calculations underresolved the number and growth rate of clumps in the disk, the overall qualitative, but fundamental, conclusion remains: fragmentation under the locally isothermal condition in numerical simulations does not in itself lead to the survival of clumps to become gaseous giant protoplanets. Since local isothermality represents an extreme assumption about thermal processes in the disk, we also present several extended simulations in which heating from an artificial viscosity scheme and cooling from a simple volumetric cooling function are applied to two different models of the solar nebula. The models are differentiated primarily by disk temperature: a high-Q model generated directly by our self-consistent field equilibrium code and a low-Q model generated by cooling the high-Q model in a two-dimensional version of our hydrodynamics code. Here, high-Q and low-Q refer to the minimum values of the Toomre stability parameter Q in each disk, Qmin = 1.8 and 0.9, respectively. Previous simulations, by ourselves as well as others, have focused on initial states that are already gravitationally unstable, i.e., models similar to the low-Q model. This paper presents for the first time the numerical evolution of an essentially stable initial equilibrium state (the high-Q model) to a severely unstable one by cooling. The additional heating and cooling are applied to each model over the outer half of the disk or the entire disk. The models are subject to the rapid growth of a four-armed spiral instability; the subsequent evolution of the models depends on the thermal behavior of the disk. The cooling function tends to overwhelm the heating included in our artificial viscosity prescription, and as a result the spiral structure strengthens. The spiral disturbances transport mass at prodigious rates during the early nonlinear stages of development and significantly alter the disk's vertical surface. Although dense condensations of material can appear, their character depends on the extent of the volumetric cooling in the disk. In the simulation of the high-Q model with heating and cooling applied throughout the disk, thin, dense rings form at radii ranging from 1 to 3 AU and steadily increase in mass; later companion formation may occur in these rings as cooling drives them toward instability. When heating and cooling are applied only over the outer radial half of the disk, however, a succession of single condensations appears near 5 AU. Each clump has roughly the mass of Saturn, and some survive a complete orbit. Since the clumps form near the artificial boundary in the treatment of the disk gas physics, the production of a clump in this case is a numerical artifact. Nevertheless, radially abrupt transitions in disk gas characteristics, for example, in opacity, might mimic the artificial boundary effects in our simulations and favor the production of stable companions in actual protostellar and protoplanetary disks. The ultimate survival of condensations as eventual stellar or substellar companions to the central star is still largely an open question.

We determine the phase diagram for dense carbon/ oxygen mixtures in White Dwarf (WD) star interiors using molecular dynamics simulations involving liquid and solid phases. Our phase diagram agrees well with predictions from Ogata et al. and Medin and Cumming and gives lower melting temperatures than Segretain et al. Observations of WD crystallization in the globular cluster NGC 6397 by Winget et al. suggest that the melting temperature of WD cores is close to that for pure carbon. If this is true, our phase diagram implies that the central oxygen abundance in these stars is less than about 60%. This constraint, along with assumptions about convection in stellar evolution models, limits the effective S factor for the $^{12}$C($\alpha,\gamma$)$^{16}$O reaction to S_{300}, Comment: 4 pages, 2 figures, Phys. Rev. Lett. in press

Fusion reactions in the crust of an accreting neutron star are an important source of heat, and the depth at which these reactions occur is important for determining the temperature profile of the star. Fusion reactions depend strongly on the nuclear charge $Z$. Nuclei with $Z\le 6$ can fuse at low densities in a liquid ocean. However, nuclei with Z=8 or 10 may not burn until higher densities where the crust is solid and electron capture has made the nuclei neutron rich. We calculate the $S$ factor for fusion reactions of neutron rich nuclei including $^{24}$O + $^{24}$O and $^{28}$Ne + $^{28}$Ne. We use a simple barrier penetration model. The $S$ factor could be further enhanced by dynamical effects involving the neutron rich skin. This possible enhancement in $S$ should be studied in the laboratory with neutron rich radioactive beams. We model the structure of the crust with molecular dynamics simulations. We find that the crust of accreting neutron stars may contain micro-crystals or regions of phase separation. Nevertheless, the screening factors that we determine for the enhancement of the rate of thermonuclear reactions are insensitive to these features. Finally, we calculate the rate of thermonuclear $^{24}$O + $^{24}$O fusion and find that $^{24}$O should burn at densities near $10^{11}$ g/cm$^3$. The energy released from this and similar reactions may be important for the temperature profile of the star., Comment: 7 pages, 4 figs, minor changes, to be published in Phys. Rev. C

Recently, crust cooling times have been measured for neutron stars after extended outbursts. These observations are very sensitive to the thermal conductivity $\kappa$ of the crust and strongly suggest that $\kappa$ is large. We perform molecular dynamics simulations of the structure of the crust of an accreting neutron star using a complex composition that includes many impurities. The composition comes from simulations of rapid proton capture nucleosynthesys followed by electron captures. We find that the thermal conductivity is reduced by impurity scattering. In addition, we find phase separation. Some impurities with low atomic number $Z$ are concentrated in a subregion of the simulation volume. For our composition, the solid crust must separate into regions of different compositions. This could lead to an asymmetric star with a quadrupole deformation that radiates gravitational waves. Observations of crust cooling can constrain impurity concentrations., Comment: 8 pages, 8 figures, minor changes, PRE in press

We calculate the shear viscosity $\eta$ and thermal conductivity $\kappa$ of a nuclear pasta phase in neutron star crusts. This involves complex non-spherical shapes. We use semiclassical molecular dynamics simulations involving 40,000 to 100,000 nucleons. The viscosity $\eta$ can be simply expressed in terms of the height $Z^*$ and width $\Delta q$ of the peak in the static structure factor $S_p(q)$. We find that $\eta$ increases somewhat, compared to a lower density phase involving spherical nuclei, because $Z^*$ decreases from form factor and ion screening effects. However, we do not find a dramatic increase in $\eta$ from non-spherical shapes, as may occur in conventional complex fluids., Comment: 8 pages, 7 figures, minor changes, Phys. Rev. C in press

Nucleosynthesis, on the surface of accreting neutron stars, produces a range of chemical elements. We perform molecular dynamics simulations of crystallization to see how this complex composition forms new neutron star crust. We find chemical separation, with the liquid ocean phase greatly enriched in low atomic number elements compared to the solid crust. This phase separation should change many crust properties such as the thermal conductivity and shear modulus. The concentration of carbon, if present, is enriched in the ocean. This may allow unstable thermonuclear burning of the carbon and help explain the ignition of the very energetic explosions known as superbursts., Comment: 8 pages, 6 figures, minor changes, Physical Review E in press

Neutrinos in core collapse supernovae are likely trapped by neutrino-nucleus elastic scattering. Using molecular dynamics simulations, we calculate neutrino mean free paths and ion-ion correlation functions for heterogeneous plasmas. Mean free paths are systematically shorter in plasmas containing a mixture of ions compared to a plasma composed of a single ion species. This is because neutrinos can scatter from concentration fluctuations. The dynamical response function of a heterogeneous plasma is found to have an extra peak at low energies describing the diffusion of concentration fluctuations. Our exact molecular dynamics results for the static structure factor reduce to the Debye Huckel approximation, but only in the limit of very low momentum transfers., 11 pages, 13 figures

The nuclear pasta -- a novel state of matter having nucleons arranged in a variety of complex shapes -- is expected to be found in the crust of neutron stars and in core-collapse supernovae at subnuclear densities of about $10^{14}$ g/cm$^3$. Due to frustration, a phenomenon that emerges from the competition between short-range nuclear attraction and long-range Coulomb repulsion, the nuclear pasta displays a preponderance of unique low-energy excitations. These excitations could have a strong impact on many transport properties, such as neutrino propagation through stellar environments. The excitation spectrum of the nuclear pasta is computed via a molecular-dynamics simulation involving up to 100,000 nucleons. The dynamic response of the pasta displays a classical plasma oscillation in the 1-2 MeV region. In addition, substantial strength is found at low energies. Yet this low-energy strength is missing from a simple ion model containing a single-representative heavy nucleus. The low-energy strength observed in the dynamic response of the pasta is likely to be a density wave involving the internal degrees of freedom of the clusters., Comment: 4 pages, 3 figures, Phys Rev C in press

Nonuniform neutron-rich matter present in both core-collapse supernovae and neutron-star crusts is described in terms of a semiclassical model that reproduces nuclear-matter properties and includes long-range Coulomb interactions. The neutron-neutron correlation function and the corresponding static structure factor are calculated from molecular dynamics simulations involving 40,000 to 100,000 nucleons. The static structure factor describes coherent neutrino scattering which is expected to dominate the neutrino opacity. At low momentum transfers the static structure factor is found to be small because of ion screening. In contrast, at intermediate momentum transfers the static structure factor displays a large peak due to coherent scattering from all the neutrons in a cluster. This peak moves to higher momentum transfers and decreases in amplitude as the density increases. A large static structure factor at zero momentum transfer, indicative of large density fluctuations during a first-order phase transition, may increase the neutrino opacity. However, no evidence of such an increase has been found. Therefore, it is unlikely that the system undergoes a simple first-order phase transition. It is found that corrections to the commonly used single heavy nucleus approximation first appear at a density of the order of $10^{13}$ g/cm$^3$ and increase rapidly with increasing density. Thus, neutrino opacities are overestimated in the single heavy nucleus approximation relative to the complete molecular dynamics simulations., 17 pages, 23 included ps figures

The liquid-solid phase-diagram of dense carbon-oxygen plasma mixtures found in white dwarf stars interiors is determined from molecular dynamics (MD) simulations. Our MD simulations consist of boxes with 55296 ions with different carbon to oxygen ratios. Finite size effects are estimated comparing the new MD simulations results to previous smaller simulations. We use bond angle metric to identify whether an ion is in the solid, liquid or interface and study non-equilibrium effects by obtaining the diffusion coefficients in the different phases. Our phase diagram agrees with predictions from Medin and Cumming obtained by an independent method.