To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/j.icarus.2005.08.007 Byline: Athena Coustenis (a), Alberto Negrao (a)(d)(f), Alberto Salama (c), Bernhard Schulz (b), Emmanuel Lellouch (a), Pascal Rannou (d), Pierre Drossart (a), Therese Encrenaz (a), Bernard Schmitt (e), Vincent Boudon (g), Andrei Nikitin (h) Keywords: Titan; Satellites of Saturn; Surfaces; Satellite; Infrared observations; ISO Abstract: The near-infrared spectrum of Titan, Saturn's largest moon and one of the Cassini/Huygens' space mission primary targets, covers the 0.8 to 5 micron region in which it shows several weak CH.sub.4 absorption regions, and in particular one centered near 2.75 micron. Due to the interference of telluric absorption, only part of this window region (2.9-3.1 [mu]m) has previously been observed from the ground [Noll, K.S., Geballe, T.R., Knacke, R., Pendleton, F., Yvonne, J., 1996. Icarus 124, 625-631; Griffith, C.A., Owen, T., Miller, G.A., Geballe, T., 1998. Nature 395, 575-578; Griffith, C.A., Owen, T., Geballe, T.R., Rayner, J., Rannou, P., 2003. Science 300, 628-630; Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42]. We report here on the first spectroscopic observations of Titan covering the whole 2.4-4.9 [mu]m region by two instruments on board the Infrared Space Observatory (ISO) in 1997. These observations show the 2.75-[mu]m window in its complete extent for the first time. In this study we have also used a high-resolution Titan spectrum in the 2.9-3.6 [mu]m region taken with the Keck [Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42; Kim, S.J., Geballe, T.R., Noll, K.S., Courtin, R., 2005. Icarus 173, 522-532] to infer information on the atmospheric parameters (haze extinction, single scattering albedo, methane abundance, etc.) by fitting the methane bands with a detailed microphysical model of Titan's atmosphere (updated from Rannou, P., McKay, C.P., Lorenz, R.D., 2003. Planet. Space Sci. 51, 963-976). We have included in this study an updated version of a database for the CH.sub.4 absorption coefficients [STDS, Wenger, Ch., Champion, J.-P., 1998. J. Quant. Spectrosc. Radiat. Transfer 59, 471-480. See also http://www.u-bourgogne.fr/LPUB/TSM/sTDS.html for latest updates; Boudon, V., Champion, J.-P., Gabard, T., LoA'te, M., Michelot, F., Pierre, G., Rotger, M., Wenger, Ch., Rey, M., 2004. J. Mol. Spectrosc. 228, 620-634]. For the atmosphere we find that (a) the haze extinction profile that best matches the data is one with higher (by 40%) extinction in the atmosphere with respect to Rannou et al. (2003) down to about 30 km where a complete cut-off occurs; (b) the methane mixing ratio at Titan's surface cannot exceed 3% on a disk-average basis, yielding a maximum CH.sub.4 column abundance of 2.27 km-am in Titan's atmosphere. From the derived surface albedo spectrum in the 2.7-3.08 micron region, we bring some constraints on Titan's surface composition. The albedo in the center of the methane window varies from 0.01 to 0.08. These values, compared to others reported in the other methane windows, show a strong compatibility with the water ice spectrum in the near-infrared. Without confirming its existence from this work alone, our data then appear to be compatible with water ice. A variety of other ices, such as CO.sub.2, NH.sub.3, tholin material or hydrocarbon liquid cannot be excluded from our data, but an additional unidentified component with a signature around 2.74 micron is required to satisfy the data. Author Affiliation: (a) LESIA, Observatoire de Paris-Meudon, 5, place Jules Jannsen, F-92195 Meudon Cedex, France (b) California Institute of Technology, Mail Code 100-22, 770 South Wilson Avenue, Pasadena, CA 91125, USA (c) ISO Data Centre, European Space Agency, Villafranca del Castillo, P.O. Box 50727, 28080 Madrid, Spain (d) Service d'Aeronomie/CNRS, Universite de Paris 6-Universite de Versailles, France (e) Laboratoire de Planetologie de Grenoble, 38041 Grenoble Cedex 9, France (f) Observatorio Astronomico and Faculdade de CiA*ncias da Universidade de Lisboa, 1749-016 Lisboa, Portugal (g) Laboratoire de Physique de l'Universite de Bourgogne (LPUB)-CNRS UMR 5027, 9 Av. A. Savary, BP 47870, F-21078 Dijon Cedex, France (h) Laboratory of Theoretical Spectroscopy, Institute of Atmospheric Optics, Russian Academy of Sciences, 634055 Tomsk, Russia Article History: Received 24 March 2005; Revised 31 July 2005