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Agradecimentos: This study was supported by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior – Brasil (Capes – Finance Code 001 and grants #A043-2013 and #1777/2014), by grants # 2011/19924-2, 2012/04870-7 and 2012/05903 of the São Paulo Research Foundation (Fapesp) and by grant #OAICE047-2017 of the University of Costa Rica Abstract: The purpose of this study was to describe the synthesis, characterization, and functionalization of b-NaYF4:30%Yb/0.5%Tm upconverting nanocrystals for use as nanofillers in a dental adhesive and microscopically evaluate the interface between the particles and a commercial adhesive. The upconverting nanoparticles were synthesized and purified by thermal decomposition, and their chemical composition determined by energy dispersive X-Ray spectroscopy. The crystalline structure was characterized using X-Ray diffraction and morphology and size were observed with scanning and transmission electron microscopy. Upconverting emission was evaluated by spectrophotometry irradiating the particles with a 975 nm diode laser. Particles were functionalized with polyacrylic acid and the success was confirmed by measurement of Zeta Potential and transmission electron microscopy. The results of X-ray diffraction found a pure hexagonal phase crystalline pattern. Scanning electron microscopy showed uniform dispersion of hexagonal-shaped particles of approximately 150 nm. Upconversion emission was observed in 344 nm, 361 nm, 450 nm, 474nm, 646 nm, 803 nm. Functionalization success was confirmed by formation of a stable aqueous colloid with a Zeta potential of -29.5mV and the absence of voids in the particle-adhesive interface on the transmission electron microscopy images. The reported synthesis and functionalization process produced upconverting nanoparticles emitting photons within the blue spectral region (450 nm and 474 nm) COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP Aberto

Agradecimentos: The authors are grateful to the Instituto Nacional de Ciências e Tecnologias Analíticas Avançadas (INCTAA) processes FAPESP # 2008/57808-1 and CNPq # 573894/2008-6 and to the Agência Nacional de Vigilância Sanitária (ANVISA) through the MCTI/CNPq/ANVISA 23/2012, process # 403403/2012-0, for financial support. This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001 and Fundação de Amparo a Pesquisa do Estado do Rio Grande do Sul (FAPERGS) for scholarship support Abstract: Ceramics manufactured in Brazil and in other countries were analyzed by laser induced breakdown spectroscopy (LIBS). The LIBS spectra were employed to identify the origin of the tableware as produced in Brazil or abroad using soft independent modeling of class analogy (SIMCA) and linear discriminant analysis (LDA). Three sets of spectral variables were evaluated aiming at discrimination of the ceramics: the entire LIBS spectrum, a set of selected spectral ranges, and the maximum of emission intensity of the elements Al, Ca, Mg, Si, Na and Ti. The results for the three sets of variables show good performance, achieving correct classification from 88.6 to 94.3%, and 86.7 to 100% for the external training and test, respectively COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DO RIO GRANDE DO SUL - FAPERGS Fechado

Agradecimentos: We are grateful for the extraordinary contributions of our CTIO colleagues and the DES Camera, Commissioning, and Science Verification teams for achieving excellent instrument and telescope conditions that have made this work possible. The success of this project also relies critically on the expertise and dedication of the DES Data Management organization. Funding for the DES Projects has been provided by the U.S. Department of Energy, the U.S. National Science Foundation, the Ministry of Science and Education of Spain, the Science and Technology Facilities Council of the United Kingdom, the Higher Education Funding Council for England, the National Center for Supercomputing Applications at the University of Illinois at Urbana-Champaign, the Kavli Institute of Cosmological Physics at the University of Chicago, the Center for Cosmology and Astro-Particle Physics at the Ohio State University, the Mitchell Institute for Fundamental Physics and Astronomy at Texas A&MUniversity, Financiadora de Estudos e Projetos, Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro, Conselho Nacional de Desenvolvimento Científico e Tecnológico and the Ministério da Ciência e Tecnologia, the Deutsche Forschungsgemeinschaft, and the Collaborating Institutions in the DES. The DES data management system is supported by the National Science Foundation under Grant Number AST-1138766. The DES participants from Spanish institutions are partially supported by MINECO under grants AYA2012-39559, ESP2013-48274, FPA2013-47986, and Centro de Excelencia Severo Ochoa SEV-2012-0234, some of which include ERDF funds from the European Union. The Collaborating Institutions are Argonne National Laboratory, the University of California at Santa Cruz, the University of Cambridge, Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas-Madrid, the University of Chicago, University College London, the DES-Brazil Consortium, the Eidgenoessische Technische Hochschule (ETH) Zurich, Fermi National Accelerator Laboratory, the University of Edinburgh, the University of Illinois at Urbana-Champaign, the Institut de Ci'encies de l’Espai (IEEC/CSIC), the Institut de F'isica d’Altes Energies, Lawrence Berkeley National Laboratory, the Ludwig-Maximilians Universit¨at and the associated Excellence Cluster Universe, the University of Michigan, the National Optical Astronomy Observatory, the University of Nottingham, the Ohio State University, the University of Pennsylvania, the University of Portsmouth, the SLAC National Accelerator Laboratory, Stanford University, the University of Sussex, and Texas A&M University. This work is based in part on observations obtained at the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under a cooperative agreement with the NSF on behalf of the Gemini partnership: the National Science Foundation (United States), the National Research Council (Canada), CONICYT (Chile), the Australian Research Council (Australia), Ministério da Ciência, Tecnologia e Inovação (Brazil), and Ministerio de Ciencia, Tecnología e Innovación Productiva (Argentina). The data were processed using the Gemini IRAF package v2.16. This research has made use of NASA’s Astrophysics Data System. This manuscript has been authored by Fermi Research Alliance, LLC under Contract No. DE-AC02-07CH11359 with the U.S. Department of Energy, Office of Science, Office of High Energy Physics. TheUnited StatesGovernment retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes Abstract: We describe the observation and confirmation of nine new strong gravitational lenses discovered in Year 1 data from the Dark Energy Survey (DES). We created candidate lists based on (i) galaxy group and cluster samples, and (ii) photometrically selected galaxy samples. We selected 46 candidates through visual inspection and then used the Gemini Multi-Object Spectrograph (GMOS) at the Gemini South telescope to acquire a spectroscopic follow-up of 21 of these candidates. Through an analysis of these spectroscopic follow-up data, we confirmed nine new lensing systems and rejected two candidates, and the analysis was inconclusive on 10 candidates. For each of the confirmed systems, our report measured spectroscopic properties, estimated source image-lens separations, and estimated enclosed masses as well. The sources that we targeted have an i-band surface brightness range of i(SB) similar to 22-24 mag arcsec(-2) and a spectroscopic redshift range of z(spec) similar to 0.8-2.6. The lens galaxies have a photometric redshift range of z(lens) similar to 0.3-0.7. The lensing systems range in source image-lens separation from 2 to 9 arcsec and in enclosed mass from 10(12) to 10(13) M-circle dot FINANCIADORA DE ESTUDOS E PROJETOS - FINEP FUNDAÇÃO CARLOS CHAGAS FILHO DE AMPARO À PESQUISA DO ESTADO DO RIO DE JANEIRO - FAPERJ CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Aberto

Agradecimentos: This research was supported by Sao Paulo Research Foundation (FAPESP), Young Researchers Award, Grant No. 2015/24351-2; Grant No. (2014/21252-0), and FAEPEX-Unicamp, Grant Nos. 10315 and 3272/17. The authors thank the National Council for Scientific and Technological Development (CNPq), for the scholarship. The researchers confirm that there are no conflict of interest Abstract: Palm oil is widely used in the food industry, and its quality is associated with the free fatty acids (FFA) content. Determination of FFA in oil is time-consuming, requires chemicals and generates residues. There is a trend of applying process analytical technologies (PAT) for fast and nondestructive determination of oil parameters. Portable near-infrared (NIR) spectrometers are cheaper than bench top equipment, and have been used for several tasks in the food processing industry, as it provides fast and reliable data for inline measurements. This study investigated the use of NIR spectra using a portable equipment, combined with both unsupervised and supervised multivariate analyses for identification of palm oil samples with different levels of FFA. Soft independent modeling of class analogy , k-Nearest Neighbors, and linear discriminant analysis models were able to correctly identify 100% of the studied samples with selected wavelengths from NIR spectra. Calibration models were performed for acidity prediction, achieving R2 = 0.97, with root mean square error of prediction = 4.37 for partial least squares model using most relevant wavelengths. These results demonstrate the feasibility of applying a low-cost portable NIR spectrophotometer to predict quality parameters of palm oil FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: We congratulate our colleagues in the CERN accelerator departments for the excellent performance of the LHC and thank the technical and administrative staffs at CERN and at other CMS institutes for their contributions to the success of the CMS effort. In addition, we gratefully acknowledge the computing centers and personnel of the Worldwide LHC Computing Grid for delivering so effectively the computing infrastructure essential to our analyses. Finally, we acknowledge the enduring support for the construction and operation of the LHC and the CMS detector provided by the following funding agencies: BMBWF and FWF (Austria); FNRS and FWO (Belgium); CNPq, CAPES, FAPERJ, FAPERGS, and FAPESP (Brazil); MES (Bulgaria); CERN; CAS, MOST, and NSFC (China); COLCIENCIAS (Colombia); MSES and CSF (Croatia); RPF (Cyprus); SENESCYT (Ecuador); MoER, ERC IUT, and ERDF (Estonia); Academy of Finland, MEC, and HIP (Finland); CEA and CNRS/IN2P3 (France); BMBF, DFG, and HGF (Germany); GSRT (Greece); NKFIA (Hungary); DAE and DST (India); IPM (Iran); SFI (Ireland); INFN (Italy); MSIP and NRF (Republic of Korea); MES (Latvia); LAS (Lithuania); MOE and UM (Malaysia); BUAP, CINVESTAV, CONACYT, LNS, SEP, and UASLP-FAI (Mexico); MOS (Montenegro); MBIE (New Zealand); PAEC (Pakistan); MSHE and NSC (Poland); FCT (Portugal); JINR (Dubna); MON, ROSATOM, RAS, RFBR, and NRC KI (Russia); MESTD (Serbia); SEIDI, CPAN, PCTI, and FEDER (Spain); MoSTR(Sri Lanka); Swiss Funding Agencies (Switzerland); MST (Taipei); ThEPCenter, IPST, STAR, and NSTDA (Thailand); TUBITAK and TAEK (Turkey); NASU and SFFR (Ukraine); STFC (United Kingdom); DOE and NSF (USA). Individuals have received support from the Marie-Curie program and the European Research Council and Horizon 2020 Grant, contract Nos. 675440 and 765710 (European Union); the Leventis Foundation; the A.P. Sloan Foundation; the Alexander von Humboldt Foundation; the Belgian Federal Science Policy Office; the Fonds pour la Formation a la Recherche dans l'Industrie et dans l'Agriculture (FRIA-Belgium); the Agentschap voor Innovatie door Wetenschap en Technologie (IWT-Belgium); the F.R.S.-FNRS and FWO (Belgium) under the "Excellence of Science -EOS" -be.h project n. 30820817; the Beijing Municipal Science & Technology Commission, No. Z181100004218003; the Ministry of Education, Youth and Sports (MEYS) of the Czech Republic; the Lendulet ("Momentum") Program and the Janos Bolyai Research Scholarship of the Hungarian Academy of Sciences, the New National Excellence Program UNKP, the NKFIA research grants 123842, 123959, 124845, 124850, 125105, 128713, 128786, and 129058 (Hungary); the Council of Science and Industrial Research, India; the HOMING PLUS program of the Foundation for Polish Science, cofinanced from European Union, Regional Development Fund, the Mobility Plus program of the Ministry of Science and Higher Education, the National Science Center (Poland), contracts Harmonia 2014/14/M/ST2/00428, Opus 2014/13/B/ST2/02543, 2014/15/B/ST2/03998, and 2015/19/B/ST2/02861, Sonata-bis 2012/07/E/ST2/01406; the National Priorities Research Program by Qatar National Research Fund; the Programa Estatal de Fomento de la Investigacion Cientifica y Tecnica de Excelencia Maria de Maeztu, grant MDM-2015-0509 and the Programa Severo Ochoa del Principado de Asturias; the Thalis and Aristeia programs cofinanced by EU-ESF and the Greek NSRF; the Rachadapisek Sompot Fund for Postdoctoral Fellowship, Chulalongkorn University and the Chulalongkorn Academic into Its 2nd Century Project Advancement Project (Thailand); The Welch Foundation, contract C-1845; and the Weston Havens Foundation (USA) Abstract: Measurements of the pseudorapidity distributions of charged hadrons produced in xenon-xenon collisions at a nucleon-nucleon centre-of-mass energy of root S-NN = 5.44 TeV are presented. The measurements are based on data collected by the CMS experiment at the LHC. The yield of primary charged hadrons produced in xenon-xenon collisions in the pseudorapidity range vertical bar eta vertical bar < 3.2 is determined using the silicon pixel detector in the CMS tracking system. For the 5% most central collisions, the chargedhadron pseudorapidity density in the midrapidity region vertical bar eta vertical bar < 0.5 is found to be 1 187 +/- 36 (syst), with a negligible statistical uncertainty. The rapidity distribution of charged hadrons is also presented in the range vertical bar y vertical bar < 3.2 and is found to be independent of rapidity around y = 0. Existing Monte-Carlo event generators are unable to simultaneously describe both results. Comparisons of charged-hadron multiplicities between xenon-xenon and lead-lead collisions at similar collision energies show that particle production at midrapidity is strongly dependent on the collision geometry in addition to the system size and collision energy COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO CARLOS CHAGAS FILHO DE AMPARO À PESQUISA DO ESTADO DO RIO DE JANEIRO - FAPERJ FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DO RIO GRANDE DO SUL - FAPERGS FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Aberto

Agradecimentos: Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP); Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) Abstract: We describe the experimental observation of nonrectilinear trajectories of a nearly Gaussian light beam propagating in free space, after reflecting from a glass-air interface near critical incidence. The angular-dependent reflection coefficients modulate the incident beam's angular spectrum, shifting the reflected beam from the rectilinear path predicted by geometrical optics. The beam trajectory shows strong dependence on the angle of incidence, changing from rectilinear to oscillatory within 0.07 degrees. Our experimental results are in good agreement with theoretical predictions for the trajectories followed by the intensity peak of the reflected beam FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado

Agradecimentos: We thank J. E. Schiel and T. Mouchahoir for providing the NISTmAb samples and D. Lesko for providing the NH3 lecture bottle sample. We thank N. Newbury, D. Carlson, K. Cossel, M. Weichman, and C. Meuse for providing comments on the manuscript. We thank A. Bartels for advice on the experimental setup. Funding: This work was supported by the Defense Advanced Research Projects Agency (DARPA), National Institute of Standards and Technology (NIST), National Research Council (NRC/National Academies of Sciences, Engineering, and Medicine), and Air Force Office of Scientific Research (AFOSR) (FA9550-16-1- 0016). F.C.C. acknowledges funding from Fapesp (grant # 2018/26673-5). U.E. and J.B. acknowledge funding from "Severo Ochoa" Programme for Centres of Excellence in R&D (SEV-2015-0522), MINECO "FIS2017-89536-P", AGAUR "2017 SGR 1639", EU FET "PETACom" (829153), ERC Advanced Grant "TRANSFORMER" (788218) and PoC miniX (840010) Abstract: Probing matter with light in the mid-infrared provides unique insight into molecular composition, structure, and function with high sensitivity. However, laser spectroscopy in this spectral region lacks the broadband or tunable light sources and efficient detectors available in the visible or near-infrared. We overcome these challenges with an approach that unites a compact source of phase-stable, single-cycle, mid-infrared pulses with room temperature electric field-resolved detection at video rates. The ultrashort pulses correspond to laser frequency combs that span 3 to 27 mm (370 to 3333 cm(-1)), and are measured with dynamic range of gt;10(6) and spectral resolution as high as 0.003 cm(-1). We highlight the brightness and coherence of our apparatus with gas-, liquid-, and solid-phase spectroscopy that extends over spectral bandwidths comparable to thermal or infrared synchrotron sources. This unique combination enables powerful avenues for rapid detection of biological, chemical, and physical properties of matter with molecular specificity FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP Fechado

Agradecimentos: The authors would like to dedicate this work to Prof. Dra. Maria Lúcia Belém-Pinheiro from UFAM, Brazil, for her contributions for more than 30 years to the study of the chemistry of natural product from the Amazon region. We are also grateful to Prof. Dr. A. C. Webber of UFAM for botanical identification, M. Sc. Renan Galaverna from UNICAMP, Brazil, for the ECD measurements, and Central Analítica (UFAM) for the NMR and MS analysis. We acknowledge the funding foundations FAPEAM, CAPES, CNPq, FINEP, and FAPESB In addition to seven known alkaloids (2, 6-11) and 1,2,4-trimethoxybenzene (1), three isoquinoline-derived alkaloids (3-5), namely, duguetinine (3), a compound based on an unprecedented oxahomoaporphine scaffold, and two new 8-oxohomoaporphine alkaloids, duguesuramine (4) and 11-methoxyduguesuramine (5), and a new asarone-derived phenylpropanoid (10) were isolated from the bark of Duguetia surinamensis. The isolation workflow was guided by HPLC-HRESIMS/MS and molecular networking-based analyses. Twenty-four known alkaloids were dereplicated from the D. surinamensis alkaloid-rich fraction network and were assigned by manual MS/MS interpretation. Their cytotoxic potential was evaluated FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DA BAHIA - FAPESB COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DO AMAZONAS - FAPEAM Fechado

Agradecimentos: We acknowledge O. Gourdon for many useful discussions. R.T.M. and P.S. acknowledge NSF CAREER Award 1541230 and ACS PRF New Directions Award. C.L. and M.T.G. gratefully acknowledge the CAPES-PDSE program for financial support (88881.131530/2016-01). M.N.H. was supported by National Science Foundation Award No. DMR-1609811. We gratefully acknowledge the computations time awarded by Texas Advanced Computing Center (TACC). Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. A portion of this research used resources at the Spallation Neutron Source, a DOE Office of Science User Facility operated by the Oak Ridge National Laboratory Abstract: This study focuses on a solid solution series, Ca(La1–xCex)2S4 (0 = x = 1), where the f electron density is absent in CaLa2S4 and is progressively increased until it is maximized in CaCe2S4. Correspondingly, these samples, synthesized by a sealed ampule method, showed progressive variations in color ranging from gray for CaLa2S4 to orange-red for CaCe2S4. The crystal structural nuances of both the end members and three solid solutions with x = 0.25, 0.50, and 0.75 were established with the complementary use of synchrotron X-ray diffraction and neutron scattering. Interestingly, these data were consistent with a two-phase composition centered around each nominal solid solution stoichiometry. Optical characterization via diffuse reflectance spectroscopy and Tauc analyses showed a shrinking of the energy band gap (from the UV to vis range) when Ce was progressively introduced into the host CaLa2S4 structure. These data were in concert with electronic band structure calculations, using density functional theory, which showed the progressive formation of an intermediate f band when Ce was introduced intro the structure. Photoelectrochemical measurements in an aqueous redox electrolyte, as well as surface photovoltage and Kelvin probe measurements, revealed all samples to be n-type semiconductors. The valence and conduction band edge positions of the end members and the three solid solutions could be mapped, on both the redox and vacuum reference energy scales, by combining these measurements with the optical data COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado

Agradecimentos: Marciano M. Oliveira acknowledges scholarship funding from FAEPEX/Unicamp, grant n° 103/16. J. P. Cruz-Tirado acknowledges scholarship funding from FAPESP, grant n° 2018/02500-4. The authors acknowledge funding from Sao Paulo Research Foundation (FAPESP), project n° 2015/24351-2, and Brazilian Natl. Council for Scientific and Technological Development (CNPq) project n° 404852/2016-5). This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001 Abstract: Food fraud in herbs and spices is an important topic, which has led to new technologies being studied as potential tools for fraud identification. Nontargeted technologies have proven to be a useful tool for the authentication of herbs and spices. The present review focuses on the use of near-infrared, hyperspectral imaging, Fourier-transform infrared, Raman, nuclear magnetic resonance, and electron spin resonance spectroscopy for the authentication of spices, which includes the determination of origin and irradiated spices and the identification of adulterants. The methods developed based on vibrational spectroscopy combined with chemometric techniques seem to be promising tools for determining the presence of adulterants and contaminants in herbs and spices. On the other hand, nuclear magnetic resonance seems to be the most efficient technology to determine the origin of herbs and spices although, for some cases, studies with near-infrared spectroscopy can be a viable substitute. Electron spin resonance spectroscopy is the technique par excellence used for the authentication of irradiated herbs and spices, so its use should be expanded to many more spices’ varieties. Portable devices are preferred by those involved in the food industry, due to its manageability and low cost. Data fusion and big data are shown as promising tools for spice fraud control. In conclusion, spectroscopic techniques show a great efficiency to authenticate spices, although their evaluation must be expanded to other spice varieties, to new strategies of data analysis (as data fusion and big data), and to the use of portable devices FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP Fechado

Agradecimentos: We thank M. A. Pimenta, E. Nery, F. Plentz, L. Malard, and L. C. Campos for helpful discussions. This work was supported by CAPES, FAPESP, FAPEMIG, CNPq, Nanocarbon INCT, and the Nanofabrication Network, Brazil Abstract: Landau level broadening mechanisms in electrically neutral and quasineutral graphene were investigated through micro-magneto-Raman experiments in three different samples, namely, a natural single-layer graphene flake and a back-gated single-layer device, both deposited over Si/SiO2 substrates, and a multilayer epitaxial graphene employed as a reference sample. Interband Landau level transition widths were estimated through a quantitative analysis of the magnetophonon resonances associated with optically active Landau level transitions crossing the energy of the E-2g Raman-active phonon. Contrary to multilayer graphene, the single-layer graphene samples show a strong damping of the low-field resonances, consistent with an additional broadening contribution of the Landau level energies arising from a random strain field. This extra contribution is properly quantified in terms of a pseudomagnetic field distribution Delta B = 1.0 - 1.7 T in our single-layer samples COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE MINAS GERAIS - FAPEMIG CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Aberto

Agradecimentos: We thank Nestor Armesto, Paukkunen Hannu, Pia Zurita, Petja Paakkinen and Carlos Salgado for the useful discussions and the NLO pQCD calculations with various nPDFs. We congratulate our colleagues in the CERN accelerator departments for the excellent performance of the LHC and thank the technical and administrative staffs at CERN and at other CMS institutes for their contributions to the success of the CMS effort. In addition, we gratefully acknowledge the computing centers and personnel of the Worldwide LHC Computing Grid for delivering so effectively the computing infrastructure essential to our analyses. Finally, we acknowledge the enduring support for the construction and operation of the LHC and the CMS detector provided by the following funding agencies: BMWFW and FWF (Austria); FNRS and FWO (Belgium); CNPq, CAPES, FAPERJ, and FAPESP (Brazil); MES (Bulgaria); CERN; CAS, MoST, and NSFC (China); COLCIENCIAS (Colombia); MSES and CSF (Croatia); RPF (Cyprus); SENESCYT (Ecuador); MoER, ERC IUT, and ERDF (Estonia); Academy of Finland, MEC, and HIP (Finland); CEA and CNRS/IN2P3 (France); BMBF, DFG, and HGF (Germany); GSRT (Greece); NKFIA (Hungary); DAE and DST (India); IPM (Iran); SFI (Ireland); INFN (Italy); MSIP and NRF (Republic of Korea); LAS (Lithuania); MOE and UM (Malaysia); BUAP, CINVESTAV, CONACYT, LNS, SEP, and UASLP-FAI (Mexico); MBIE (New Zealand); PAEC (Pakistan); MSHE and NSC (Poland); FCT (Portugal); JINR (Dubna); MON, RosAtom, RAS and RFBR (Russia); MESTD (Serbia); SEIDI, CPAN, PCTI and FEDER (Spain); Swiss Funding Agencies (Switzerland); MST (Taipei); ThEPCenter, IPST, STAR, and NSTDA (Thailand); TUBITAK and TAEK (Turkey); NASU and SFFR (Ukraine); STFC (United Kingdom); DOE and NSF (USA) Abstract: The pseudorapidity distributions of dijets as functions of their average transverse momentum (p(T)(ave)) are measured in proton-lead (pPb) and proton-proton (pp) collisions. The data samples were collected by the CMS experiment at the CERN LHC, at a nucleon-nucleon center-of-mass energy of 5.02 TeV. A significant modification of the pPb spectra with respect to the pp spectra is observed in all p(T)(ave) intervals investigated. The ratios of the pPb and pp distributions are compared to next-to-leading order perturbative quantum chromodynamics calculations with unbound nucleon and nuclear parton distribution functions (PDFs). These results give the first evidence that the gluon PDF at large Bjorken x in lead ions is strongly suppressed with respect to the PDF in unbound nucleons CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO CARLOS CHAGAS FILHO DE AMPARO À PESQUISA DO ESTADO DO RIO DE JANEIRO - FAPERJ FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP Aberto

Agradecimentos: The authors thank Johnson & Johnson do Brasil Ind. Com. Produtos para Saude ' Ltda. for a scholarship to R.P.O. and Dr. MarcoAurelio De Paoli and Dr. Watson Loh for revision of the manuscript Abstract: It is well known that long term use of shampoo causes damage to human hair. Although the Lowry method has been widely used to quantify hair damage, it is unsuitable to determine this in the presence of some surfactants and there is no other method proposed in literature. In this work, a different method is used to investigate and compare the hair damage induced by four types of surfactants (including three commercial-grade surfactants) and water. Hair samples were immersed in aqueous solution of surfactants under conditions that resemble a shower (38 °C, constant shaking). These solutions become colored with time of contact with hair and its UV–vis spectra were recorded. For comparison, the amount of extracted proteins from hair by sodium dodecyl sulfate (SDS) and by water were estimated by the Lowry method. Additionally, non-pigmented vs. pigmented hair and also sepia melanin were used to understand the washing solution color and their spectra. The results presented herein show that hair degradation is mostly caused by the extraction of proteins, cuticle fragments and melanin granules from hair fiber. It was found that the intensity of solution color varies with the charge density of the surfactants. Furthermore, the intensity of solution color can be correlated to the amount of proteins quantified by the Lowry method as well as to the degree of hair damage. UV–vis spectrum of hair washing solutions is a simple and straightforward method to quantify and compare hair damages induced by different commercial surfactants Fechado

Agradecimentos: We congratulate our colleagues in the CERN accelerator departments for the excellent performance of the LHC and thank the technical and administrative staffs at CERN and at other CMS institutes for their contributions to the success of the CMS effort. In addition, we gratefully acknowledge the computing centers and personnel of the Worldwide LHC Computing Grid for delivering so effectively the computing infrastructure essential to our analyses. Finally, we acknowledge the enduring support for the construction and operation of the LHC and the CMS detector provided by the following funding agencies: BMWFW and FWF (Austria); FNRS and FWO (Belgium); CNPq, CAPES, FAPERJ, and FAPESP (Brazil); MES (Bulgaria); CERN; CAS, MoST, and NSFC (China); COLCIENCIAS (Colombia); MSES and CSF (Croatia); RPF (Cyprus); MoER, ERC IUT and ERDF (Estonia); Academy of Finland, MEC, and HIP (Finland); CEA and CNRS/IN2P3 (France); BMBF, DFG, and HGF (Germany); GSRT (Greece); OTKA and NIH (Hungary); DAE and DST (India); IPM (Iran); SFI (Ireland); INFN (Italy); MSIP and NRF (Republic of Korea); LAS (Lithuania); MOE and UM (Malaysia); BUAP, CINVESTAV, CONACYT, LNS, SEP, and UASLP-FAI (Mexico); MBIE (New Zealand); PAEC (Pakistan); MSHE and NSC (Poland); FCT (Portugal); JINR (Dubna); MON, RosAtom, RAS and RFBR (Russia); MESTD (Serbia); SEIDI and CPAN (Spain); Swiss Funding Agencies (Switzerland); MST (Taipei); ThEPCenter, IPST, STAR and NSTDA (Thailand); TUBITAK and TAEK (Turkey); NASU and SFFR (Ukraine); STFC (United Kingdom); DOE and NSF (USA). Individuals have received support from the Marie-Curie program and the European Research Council and EPLANET (European Union); the Leventis Foundation; the A.P. Sloan Foundation; the Alexander von Humboldt Foundation; the Belgian Federal Science Policy Office; the Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture (FRIA-Belgium); the Agentschap voor Innovatie door Wetenschap en Technologie (IWT-Belgium); the Ministry of Education, Youth and Sports (MEYS) of the Czech Republic; the Council of Science and Industrial Research, India; the HOMING PLUS program of the Foundation for Polish Science, cofinanced from European Union, Regional Development Fund; the Mobility Plus program of the Ministry of Science and Higher Education (Poland); the OPUS program of the National Science Center (Poland); the Thalis and Aristeia programs cofinanced by EU-ESF and the Greek NSRF; the National Priorities Research Program by Qatar National Research Fund; the Programa Clarín-COFUND del Principado de Asturias; the Rachadapisek Sompot Fund for Postdoctoral Fellowship, Chulalongkorn University (Thailand); the Chulalongkorn Academic into Its 2nd Century Project Advancement Project (Thailand); and the Welch Foundation, contract C-1845 Abstract: Measurements of strange hadron (K-S(0), Lambda +(Lambda) over bar, and Xi(-)+(Xi) over bar (+)) transverse momentum spectra in pp, pPb, and PbPb collisions are presented over a wide range of rapidity and event charged-particle multiplicity. The data were collected with the CMS detector at the CERN LHC in pp collisions at root s= 7 TeV, pPb collisions at root(NN)-N-s= 5.02 TeV, and PbPb collisions at root(NN)-N-s = 2.76 TeV. The average transverse kinetic energy is found to increase with multiplicity, at a faster rate for heavier strange particle species in all systems. At similar multiplicities, the difference in average transverse kinetic energy between different particle species is observed to be larger for pp and pPb events than for PbPb events. In pPb collisions, the average transverse kinetic energy is found to be slightly larger in the Pb-going direction than in the p-going direction for events with large multiplicity. The spectra are compared to models motivated by hydrodynamics CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO CARLOS CHAGAS FILHO DE AMPARO À PESQUISA DO ESTADO DO RIO DE JANEIRO - FAPERJ FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP Aberto

Agradecimentos: The authors thanks FAPESP (Proc. 2013/09022-7), CNPq, and CAPES foundations (Brazil) for financial support Abstract: The characterization, thermal stability and thermal decomposition of some lighter trivalent lanthanide p-aminobenzoates, Ln(C7H6NO2)3·H2O (Ln = La, Ce, Pr, Nd, Sm), as well as the thermal behavior and spectroscopic study of p-aminobenzoic acid C7H7NO2 and its sodium salt were investigated. The following methods were utilized: simultaneous thermogravimetry and differential thermal analysis (TG–DTA) in dynamic dry air and nitrogen atmospheres; differential scanning calorimetry (DSC); middle (MIR) and near (NIR) infrared region spectroscopy; evolved gas analysis (EGA); elemental analysis; complexometry; X-ray diffraction (XRD); and diffuse reflectance spectroscopy (DR) in the ultraviolet and visible regions. All the compounds were obtained monohydrated and the thermal decomposition occurred in two, three or four steps in an air atmosphere, and three or four steps in N2 atmosphere. In both atmospheres (air and N2) the final residues were CeO2, Pr6O11, Ln2O3 (Ln = La, Nd, Sm). The results also provided information concerning the coordination mode and thermal behavior, as well as the identification of the gaseous products which evolved during the thermal decomposition of these compounds. The DR and NIR spectra provided information about the ligand absorption bands and the f–f transitions of the Nd3+, Pr3+ and Sm3+ ions FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado

Agradecimentos: This material is based upon work supported by the National Science Foundation (Award Nos. 0078812 and 0406556), the Washington Space Grant Consortium (Award No. NNX10AK64H), and the Central Washington University Faculty Sabbatical Program. We are also grateful to B. Freeman, C. Gerke, P. Mehl, M. Smith, and E. Westbay for their assistance in measuring several CD3OH laser frequencies Abstract: Twenty two laser frequencies, whose values range from 1.6 to 8.6 THz, have been measured for the first time using heterodyne techniques. These laser emissions were generated by an optically pumped molecular laser that used either CD3OH or CD3OD as its lasing medium. At least three of the observed laser emissions generated by CD3OH were discovered during this investigation and the first laser frequencies measured for CD3OH above 8 THz are reported. The laser frequencies were measured with fractional uncertainties up to +/- 2 x 10(-7), of sufficient accuracy to confirm two proposed far-infrared laser assignments. The offset frequency of the CO2 pump laser with respect to its center frequency was also measured for nearly all laser emissions generated by CD3OH Fechado

Agradecimentos: The authors thank the São Paulo Research Foundation (FAPESP) through grants #2010/06816-4 and #2010/16437-0, CNPq (National Council for Scientific and Technological Development) and National Institute of Science and Technology - Radiation Metrology in Medicine (INCT) Abstract: In this work we evaluate the intensity and the spectral shape of the leakage radiation from the built-in beta and alpha sources of a Risø TL/OSL reader. LiF (TLD-100), fluorite-based pellets and Al2O3:C detectors were used in order to determine the dose rate delivered to the dosimeters when the sources are closed. The leakage spectra under both alpha and beta sources were registered with a CdTe semiconductor detector. The spectrum measured under the beta source shows the X-ray beam generated by the interaction of the beta particles with the lead used to shield the source. Besides, the 59.4 keV gamma ray from 241Am was registered under the alpha source. Dose rates from 50 to 100 µGy/h were obtained for the dosimeter positions in the turntable under the beta and the alpha sources with the luminescent dosimeters FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: This study was supported by Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - CAPES - Brasil Abstract: To evaluate the influence of light-activation of second, third and fourth increments on degree of conversion (DC) and microhardness (KHN) of the top (T) and bottom (B) surface of the first increment. Forty samples (n = 5) were prepared. In groups 1-4, after each increment light-activation (multiple irradiation), T and B of the first increment were measured in DC and KHN. In groups 5-8, only the first increment was made (single irradiation) and measurements of DC and KHN were taken at 15 min intervals. The light-activation modes were (XL) 500 mW/cm(2) x 38 s (G1/G5); (S) 1000 mW/cm(2) x 19 s (G2/G6), (HP) 1400 mW/cm(2) x 14 s (G3/G7); (PE) 3200 mW/cm(2) x 6 s (G4/G8). Data for DC and KHN were analyzed separately by using PROC MIXED for repeated measures and Tukey-Kramer test (alpha = 0.05). Results. For KHN, B showed lower values than T. PE resulted in lower values of KHN in B surface. For single and multiple irradiations, T and B of first measurement showed the lowest KHN and the fourth measurement showed the highest, with significant difference between them. For single irradiation, first and second increments presented similar KHN, different from the third and fourth increment, which did not differ between them. For multiple irradiations, the second light-activation resulted in KHN similar to first, third and fourth increments. For DC, except QTH, T presented higher DC than B. Conclusion. The light-activation of successive increments was not able to influence the KHN and DC of the first increment COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado

Agradecimentos: G. T. Nogueira acknowledges a scholarship from CAPES. F. C. Cruz (flavio@ifi.unicamp.br) acknowledges financial support from FAPESP, CEPOF, and CNPq. The MSU team acknowledges partial funding for the project from the National Science Foundation Abstract: We report a self-starting prismless femtosecond Ti:sapphire ring laser whose repetition rate has been gradually increased from 1 to 2.12 GHz. A broadband spectrum extending from 650 to 1040 nm, in which 17% of the intracavity power is generated in a single-pass through the crystal, is preserved in spite of the reduction in peak power. An average power of 0.95 W was obtained for 7.5 W of pump power, with very stable operation verified over 22 hours. Pulses from this laser have been fully characterized in spectral phase, and then compressed to 5.9 femtoseconds using multiphoton intrapulse interference phase scan (MIIPS) COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Aberto

Agradecimentos: We thank S. Diddams for valuable contributions, including discussions and equipment loan; T. Fortier, M. Kirchner, and M. Thorpe for help on the setup, measurements, and analysis software for the whitelight interferometer; F. Wunderlich (Layertec) for providing data on mirrors; and S. Foreman and H. Kapteyn for comments on the manuscript. F. C. Cruz (flavio@ifi.unicamp.br) is a 2005 JILA Visiting Fellow and acknowledges the support of FAPESP, CAPES, and CNPq-Brazil. G. T. Nogueira acknowledges a scholarship from CAPES and the support of the National Institute of Standards and Technology during a four-month stay in Boulder Abstract: We demonstrate a 1 GHz prisinless femtosecond Ti:sapphire ring laser that emits 890 MW for 7.6 W of pump power over a continuum extending from 585 to 1200 nm at -20 dB below the maximum. A broadband continuum is obtained with the net cavity group delay dispersion having -50 to 100 fs(2) oscillations from 700 to 900 nm. Further broadening is obtained by use of a slightly convex cavity mirror that increases self-phase modulation. Approximately 17% (75%) of the intracavity (output) power is generated in single pass through the crystal, outside the cavity bandwidth, and concentrated in the low-gain IR from 960 to 1200 nm FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: Part of this work is based upon research conducted at the Synchrotron Radiation Center, University of Wisconsin-Madison, which is supported by the NSF under Award No. DMR-0084402 Abstract: We give a unified discussion of two different approaches to the design of grazing incidence monochromators with a variable line spacing (VLS) grating for soft X-ray undulator sources. Neither one uses an entrance slit and both work with a fixed position exit slit. In one approach, being constructed at LNLS and designed for the energy range 100 < E < 1000 eV, the choice of the VLS parameters allows for the operation at a variable c-value with a single plane grating and little sacrifice in the maximum resolving power. In this case source size limited resolving power of circa 40 000 is expected at 100 eV. In the second approach, for the storage ring in Wisconsin, two gratings covering the energy range 40 < E < 1500 eV are used, one capable of delivering a resolving power larger than 20 000 at 860 eV and the other lower resolving power but much higher flux Fechado

In this work, we report new optically pumped far-infrared (FIR) laser lines from CHD2OH. A waveguide CO2 laser of wide tunability (290 MHz) was used as pump source, and a Fabry-Perot open cavity was used as a FIR laser resonator. Optoacoustic absorption spectra were used as a guide to search for new FIR laser lines. We could observe 15 new laser lines in the range from 116.4 to 401.4 mu m. The lines were characterized according to wavelength, relative polarization, relative intensity, and optimum working pressure. The transferred Lamb-dip technique was used to measure the frequency absorption transition both for the new and previously reported laser lines FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: This work was supported by FAPESP, CAPES, CNPq, and FAEP-UNICAMP, Brazilian government agencies. Support for RLCF was through CAPES graduate research scholarship and for DAM and DRO through FAPESP graduate and undergraduate scholarships respectively Abstract: We report on a simple scheme to efficiently load an on-axis magneto-optical trap (MOT) from a decelerated atomic beam, which avoids perturbation by radiation pressure from the decelerating laser. This has been tightly focused near the MOT center, with a waist size much smaller than the atomic cloud. For comparison, and in order to test the efficiency of this non-optimum deceleration geometry we have employed a second, independent decelerating laser, with a profile mode matched to the atomic beam. Using a Calcium MOT, good performance has been achieved and for an oven temperature of 580 degreesC we loaded 1.2 (2) x10(7) atoms in 16 (1) ms. The technique described here has been essential for the sensitive detection of cold collisions, which represent minor losses in MOTs of alkaline-earth metal elements (R.L. Cavasso-Filho, A. Scalabrin, D. Pereira, F.C. Cruz: Phys. Rev. A, 67, 021402(R) (2003)) FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: This research was supported by the Brazilian government agencies Fundação de Amparo à Pesquisa do Estado de São Paulo (including its Optics and Photonics Center), Coordenção de Aperfeiçoamento de Pessoal de Nível Superior, Conselho Nacional de Desenvolvimento Científico e Tecnológico, and Fundo de Apoio à Pesquisa da Universidade Estadual de Campinas. F. C. Cruz benefited from fruitful discussions with C. W. Oates, J. C. Bergquist, W. M. Itano, N. Beverini, and A. Hemmerich Abstract: We report on a system for atomic beam deceleration and magneto-optical trapping of calcium atoms that uses the S-1(0)-P-1(1) transition, in which a single laser is used to trap and slow the atoms. The slower laser beam is focused near the magneto-optical trap's center, which has a waist size much smaller than the atomic cloud such that its influence on the trapped atoms is greatly reduced. We also investigate the theoretical possibility of cooling by use of a two-photon (4s(2))S-1(0)-(4s5s)S-1(0) transition. Excitation near resonance with the P-1(1) level results in an equilibrium temperature seven times smaller than the Doppler limit of the S-1(0)-P-1(1) transition FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

Agradecimentos: We would like to acknowledge the glass shop of the UNICAMP Physics Institute for the very well done work in the construction of the atomic beam and MOT glass chamber. We also would like to thank the machine shop and J.B.Rodrigues for the mechanical parts. This work was supported by FAPESP, CAPES and CNPq and FAEPUNICAMP, Brazilian government agencies. Support for RLCF was through CAPES graduate research scholarship and for DAM and DRO through FAPESP graduate and undergraduate scholarships respectively Abstract: We describe a new system for laser cooling and trapping of neutral Calcium atoms employing the ¹S0 -¹ P1 resonant transition at 423 nm. An on-axis magneto-optical trap (MOT) is loaded from a Zeeman decelerated atomic beam. When a single laser is used, in order to avoid perturbation of the trap by the deceleration laser beam, this one has been tightly focused near the MOT center, with a waist size much smaller than the atomic cloud. In order to test the efficiency of this novel technique, we have then employed a second, independent decelerating laser, with a profile mode matched to the atomic beam. For an oven temperature of 580±C this system can load 1.2 (2) x 10(7) atoms in 16 (1) ms. By the spatial extension of the atomic cloud the one dimension rms velocity was estimated to be 136 (12) cm/s, corresponding to a temperature of 9 (2) mK. The variation of the number of trapped atoms as a function of laser detuning and intensity, trap magnetic field gradient and oven temperature is analyzed. Spatial structures of the trapped atoms, like stable rings created by vortex forces, have been observed. This is the first time that these structures, already observed in alkali-metal elements, are reported in MOTs of alkaline-earth elements FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Aberto

Agradecimentos: This work was supported by FAPESP, CNPq, and CAPES, Brazilian government agencies. We would like to thank Jim Bergquist for many of the design concepts used by us and for the continuing assistance and support; V.S. Bagnato, L.G. Marcassa, and S.C. Zilio for supplying Ti:Al2O3, a TGG crystal, and the mirrors from the University of São Carlos Optics Workshop (Brazil); Nelson B. Sales, Jorge L. Pires, Antônio J. Polaquini, and João B. Rodrigues for the mechanical parts Autor: We describe in detail the design, construction, and characterization of an efficient frequency doubled and stabilized all-solid-state Ti:sapphire laser. The laser frequency has been locked to the resonance of a Fabry-Perot cavity, and doubled in a Brewster-cut potassium niobate crystal placed inside a power enhancement cavity. Up to 200 mW of single frequency blue light with fast frequency instabilities of 40-kHz rms and a drift of 10 MHz/hour has been generated. The spectral distributions of amplitude and frequency noise for the free-running laser have been measured and compared with the case of pumping from an argon ion laser. Our laser is well suited in atomic physics for high resolution spectroscopy and for laser cooling and trapping using transitions in the blue-violet region, as we demonstrate with the calcium resonant transition, at 423 nm FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado

We report on an alternative extended cavity scheme used with a 180 mW quantum well GaAlAs diode laser, operating near 850 nm. A dispersing prism and a thin glass plate are employed to enforce stable single-mode operation in the strong feedback regime, with no need for laser AR coatings. Compared to other configurations where a grating is used, the lower loss in the extended cavity allows higher fundamental power available for second harmonic generation. For example, by frequency doubling using potassium niobate in a power enhancement cavity, enough power can be generated from a single diode laser to decelerate and trap calcium atoms with radiation at 423 nm FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ Fechado

We carried out an exact density matrix analysis for the nonlinear Hanle effect in an open V-type level system. Steady-state analytical solutions of the Liouville equation have been obtained and the dependence of the populations of the upper and lower states on the applied magnetic field is discussed. These curves, corresponding to experimental ones when fluorescence or absorption is detected, are dependent on the excitation and decay rates and can be used as a tool for analysing population inversion in laser transitions FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES Fechado