1. Kinetic pathways to visible emission from a moly–oxide–argon discharge bulb.
- Author
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Petrov, G.M., Giuliani, J.L., Dasgupta, A., Bartschat, K., and Pechacek, R.E.
- Subjects
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BULBS (Plants) , *ARGON , *MOLYBDENUM oxides , *EMISSION spectroscopy , *PLASMA gases , *ULTRAVIOLET radiation - Abstract
A low-pressure mercury-free moly-oxide-argon (MOO 3-Ar) electrodeless discharge is investigated with potential application to lighting. The inductive discharge is driven by a 13.56 MHz radio frequency (RF) generator at input powers between 100 and 200 W. Calibrated emission spectra in the near ultraviolet (UV), visible, and near infrared regions are recorded and the corresponding powers emitted as radiation are obtained. An extensive set of transition probabilities and rate coefficients for electron impact excitation between Mo states is assembled and a detailed collisional radiative model of the plasma is developed. The model includes 11 states of neutral Mo, the evaporative and recycling chemistry of MoO 3 into Mo and back, and the relevant species and reactions in argon-oxygen plasma. The possible paths for visible and UV radiation are analyzed in detail. The measured light output at 200 W RF input power is∼ 40 lumens per watt (lpw) with a potential to reach∼ 60-80 lpw. [ABSTRACT FROM AUTHOR]
- Published
- 2004
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