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An ethnoarchaeometric approach has been followed to identify the textural and compositional characteristics of the ceramic pastes produced in ancient Iaitas/Ietas, an indigenous site located in western Sicily on Monte Iato, a few tens of kilometres from Palermo. This approach was primarily motivated by the lack of discovered Archaic kilns or production sites/workshops and the inability to identify reference groups. Raw clays were sampled in the territory of San Cipirello and San Giuseppe Iato (today’s municipalities both sited on the northern slopes of Monte Iato), together with representative historic tiles and bricks locally produced until fairly recently. Grain-size analysis and experimental firings were performed on the clay samples. A significant number of archaeological ceramic samples (incised and painted indigenous pottery dating back to the seventh–fifth centuries BCE) from stratigraphic excavations on Monte Iato, and hypothesized as local productions on a stylistic-morphological basis, was carefully selected for archaeometric analysis. This set of samples (90 in total, comprising raw clays, historic tiles/bricks and archaeological ceramics) underwent a combined chemical and mineralogical-petrographic analysis to identify any possible compositional matching. This approach enabled the identification of minero-petrographic and chemical markers pertinent to the indigenous Archaic pottery produced at Monte Iato, although no evidence of coeval ceramic kilns has been found so far. Local raw clay sources have been documented and some significant points of the chaîne opératoire adopted in antiquity have been noted (clay mixing and tempering practices). Attesting Monte Iato as a centre of ceramic production and defining both the microscopic fabric and the average composition of local pastes open up new perspectives in the complex issue concerning the production and regional circulation of incised and painted indigenous ceramics in Archaic Sicily.

This study presents the results of the examination and characterisation of the wall paintings that decorate the rupestrian church named Grotta del Crocifisso, which is located in the territory of Lentini (eastern Sicily, few tens of kilometres from Catania and Syracuse). The earliest mural paintings in the church date back to the twelfth century AD. A multi-analytical approach was adopted for the characterisation of stone materials, secondary degradation products, and pigments. For this purpose, the following techniques were used: reflected light microscopy (RLM), polarised light microscopy on thin sections (PLM), X-ray powder diffraction (XRPD), mercury intrusion porosimetry (MIP), portable X-ray fluorescence (p-XRF), scanning electron microscopy (SEM-EDS), Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy (RS). The lithic substrate and the plaster’s coating layers were thoroughly characterised from compositional and textural points of view, and the use of locally available raw materials was established. Similarly, the newly formed crystalline phases produced by alteration processes of the original materials were recognised. The red, yellow, brown, and green pigments were easily identified by p-XRF and SEM-EDS. The use of “earth pigments” widely available in the surrounding area (various types of ochre) was thus highlighted. The recognition of the dark blue pigment created some additional issues in its identification, making further diagnostic methods necessary. In fact, the use of the most common mineral pigments was categorically excluded by both p-XRF and SEM-EDS, since no chromophore metallic elements were highlighted with the exception of trace amounts of iron. A combination of detailed microscopic observations together with the application of FTIR and RS supported the use of an organic pigment obtained from the maceration of woad (Isatis tinctoria). The green pigment is the result of a mixture between woad and yellow ochre. Woad is even today easily available in Sicily, and some additional experimental tests were carried out on Isatis tinctoria that had been freshly collected in the area (treated with traditional procedures). Over the past centuries, woad was widely used for dyeing fabrics, but its practice for wall paintings has only been sporadically proven. The identification reported in this case study could be considered a novelty at least in the Sicilian panorama.

From 2017, an unknown rural settlement in Contrada Castro at Corleone (Palermo Province, western Sicily) was investigated as part of the `Harvesting Memories Project¿. The stratigraphic sequence, supported by radiocarbon dating, has demonstrated a reoccupation of a pre-Roman site during the transition between the Byzantine and Islamic periods. In particular, the main occupation occurred in the late 8th¿9th century when pottery kilns and a probable warehouse were constructed. During the 10th¿11th century, a new structure with different orientations replaced the previous buildings that had already collapsed. Specifically focusing on a perspective of the household production and its relationship to the surrounding landscapes of this site, this paper presents the results of a geological survey and petrographic analysis of ceramic finds and lithic samples to identify the source area of the geomaterials used in the studied settlement. The ceramic finds were divided into different Paste Groups based on the characteristics of a polarizing microscope study. The use of some locally available raw materials was recorded both for ceramic and lithic samples. Such an approach enables us to better understand ceramic craft technology, clay and lithic procurement strategies and, more broadly, the consumption of household pottery in the Early Medieval site in Contrada Castro. Furthermore, this study verifies the close relationship that this rural settlement had with the surrounding resources in the area and reveals a connection with the city of Palermo during the Early Middle Ages., Bona Furtuna LLC; Università degli Studi di Palermo, Funding information: Bona Furtuna LLC; Università degli Studi di Palermo

This paper aims at an interdisciplinary, archaeological and archaeometric characterisation of the western Greek amphorae series produced in late Archaic and Classical-period Agrigento (southern Sicily). The research is based on a macroscopic examination, according to the standardised methods of Fabrics of the Central Mediterranean (FACEM), combined with petrographic analyses of 21 amphorae samples of presumed local fabric found in Agrigento itself. These were found in the artisanal area outside Porta V, in the excavations South of the temple of Zeus, and in several Sicilian consumption sites. Furthermore, a selection of 12 coarse ware samples and three tiles, all of supposed local manufacture and unearthed in Agrigento, has been investigated. For comparison, 12 raw clays sampled in the gullies between the Tempio di Giunone and the Tempio della Concordia have been included in this study and are complimented by chemical analyses (ICP-MS and ICP/OES) undertaken on a group of 19 ceramic samples and seven raw materials. As a result, our study confirms the local manufacture of the entire selection of 36 ceramic samples and the more than acceptable petrographic and chemical homogeneity of the ceramic pastes produced with locally sourced clays. The identification of a production of western Greek wine (?) amphorae in Agrigento dating from the late 6th-4th century BCE breaks ground for a better understanding of the colony's economic development during the late Archaic and Classical periods. The city has to be regarded, in fact, as one of the major global players within the wider frame of Sicilian commercial interaction, especially during the 5th century BCE.

This paper concerns the archaeometric analysis of ceramic finds dating to the Roman Imperial period, brought to light during the excavation campaigns conducted at Vagnari (Puglia) in south-east Italy. On the site of the central village (vicus) of this imperial estate, established by the Roman Emperor in the early 1st century CE, large dolia (wine vats) sunk into the floor of a winery of the 2nd century CE recently were brought to light. Other discoveries include kilns for the production of ceramic roof tiles and also kiln wasters such as misfired tiles. The purpose of the analytical approach was therefore twofold: 1) to establish the composition of local ceramic products and of raw clay resources available nearby; 2) to prove that the dolia were imported and not produced locally (as macroscopic observations of the ceramic vessels would suggest) and to offer a hypothesis concerning their provenance through petrographic observations and chemical analysis. The results show that roof tiles for the settlement were manufactured locally from readily available clay deposits, but the dolia were imported, by sea and/or land, from distant workshops in volcanic zones on the west coast of Italy around Rome or south of Rome near Minturno on the Campanian border.

This tutorial paper is focused on the mineralogical-petrographic characterization of clayey raw materials with the purpose of sourcing supply basins and answering questions about the provenance of the corresponding archaeological ceramic artefacts. The first part gives general indications of how to profitably study archaeological ceramic thin sections through the polarizing microscope. Brief notes are provided on the theoretical basis of optical microscopy. A scheme is then provided for the petrographic description of ceramic samples, concerning the textural and compositional characteristics of aplastic inclusions and groundmass. Suggestions are also given for identifying any minero-petrographic marker and establishing minero-petrographic groups (MGP) aimed at archaeological ceramic provenance studies. After broadly describing the geological origin of the clay deposits, there is discussion of how to plan a field survey aimed at the location of clay sources and sampling. The importance of the ethnoarchaeometric approach in provenance studies is also underlined. The third part of the paper describes the preliminary treatments to which the clayey raw materials are subjected before reporting on a grain size analysis and how to proceed when performing experimental firing tests. Finally some suggestions are made about how to compare clay firing tests (experimental briquettes) and archaeological ceramic finds when assessing a production centre.

A set of 37 overfired ceramic samples was collected from the dump of two kilns sited in the productive area FF1 in the acropolis of Selinunte (south western Sicily), being specifically active in the period 409–250 BCE. The ceramic samples were analysed by thin-section petrography and chemical analysis, with the aim to establish a valuable ‘reference group’ representative of the ceramic produced at Selinunte during the Punic phase. The petrographic and chemical analyses allowed to state that the ceramic manufactures from the kilns operating in the FF1 insula are characterized by rather homogeneous textural/compositional features. The daily-use common ware here produced is characterized by aplastic inclusions mainly falling in the size classes of coarse silt and medium sand, with relative abundance ranging between 15 and 25% area. The inclusions are composed of monocrystalline quartz and, subordinately, of calcareous bioclasts, polycrystalline quartz, K-feldspar, plagioclase, chert, sandstones and acid rock fragments. The relatively low total chemical variability of the ceramic sample set reflects the specific incidence of the above-mentioned mineralogical and textural features. The variable amount of quartz-rich sand used for tempering the local raw clays produces slight variations in the SiO2/CaO concentration ratio. Nonetheless, the chemical ‘reference group’ defined through this study seems to be consistent and characterized by satisfactory low standard deviations and it is fully congruent with the geo-lithological background of the area. This new chemical ‘reference group’ might be applied to studies that are aimed to define the trade networks in that time in south western Sicily. It could also represent a useful starting point for future systematic studies concerning various ceramics classes (i.e. tableware, cooking ware, transport amphorae, etc.), taking into account the consumption and insular/extra insular trade dynamics of the ceramic products of Punic Selinunte.

The study of ceramic-making communities which employ traditional practices can provide insights into the raw materials and techniques used over the centuries in a particular territory. The archaeometric study of ceramic products and of the raw materials used in their production is an effective complement to the existing ethnographic information. This paper focuses on the brick and tile making tradition of Oristano, a town in Central-Western Sardinia (Italy). Applying a combination of techniques, it includes an extensive analysis of traditional handmade and early industrial bricks and tiles, and a study of the local clays that may have been used as raw materials. Although we were unable to study workshops in operation, we had access to the oral testimonies of local workers regarding traditional production processes. In this sense, this is an ethnographic case study that can be considered as a semiarchaeological situation. Studies of this kind, in conjunction with ethnoarchaeometric analyses, are also useful to test some of the theoretical and methodological approaches used in archaeometric research. In this regard, the present study also explores the compositional variability of the ceramic production within the same territory.

This paper deals with the archaeometric study of lime-based plasters found in the archaeological settlement of Scauri, located in the homonymous bay in the south-western part of Pantelleria Island. Since 1999, archaeological surveys have led to the recovery of the huge remains of a Late Roman settlement dating back to the fourth-fifth century AD. It is well known that the island of Pantelleria is entirely composed of volcanic rocks. Accordingly, the production of quicklime required calcareous rocks to be imported. Also, the selection criteria of the sandy aggregate are relevant and of interest to this study, to evaluate the achieved technological level. Within this context, a mineralogical and petrographic characterisation of the plasters was carried out using thin-section petrography, for the classification of the sand aggregate. Moreover, X-ray diffraction and scanning electron microscopy were performed to investigate the composition of the binder. The analytical results allowed the identification of different recipes for the manufacture of the studied plasters, obtained by the use of different types of aggregate (volcanic rock fragments, pumice, basaltic scoriae, and ceramic fragments) and highlighted the degree of pozzolanic reaction of the binder. Finally, the provenance of the calcareous raw material was inferred using a petrographic approach.

This contribution is focused on a specific class of indigenous Archaic pottery (sixth and fifth century BC) with matt-painted geometric decoration that was recovered in large quantities in the excavations at Entella, an indigenous site located in western Sicily. The site of Entella was strategically considerable in this part of Sicily, controlling the north-south routes running along the river Belice. Kiln structures were attested at Entella that, until today, it is the only Archaic site in the area with an unmistakable evidence of production of fine pottery. The present research is aimed at yielding a complete petrographic and chemical characterization of the table ware produced at Entella during the sixth and fifth century BC. Analytical results were afterward compared with data concerning local clays that were subjected to experimental firing tests as well. This study is expected to provide additional interpretations concerning the trade between the native centers located in the interior of western Sicily and the Greek or Punic colonies sited along the coasts of the same territory.

Given that amphorae were used for storage or for long and/or short distance transport, they must have been able to retain their content and, at the same time, be able to resist important load during transport. This paper concerns aspects of the techno-functionality of pre-Roman Iberian amphorae. The basic performance requirement concerned here is the mechanical strength (transverse rupture strength: TRS). Strength is related to the adequacy for storage or short and/or long distance transport that, up to now, is only assessed by typological identification or archaeological evidence. Experimental implementation on actual archaeological material has confirmed that strength increased with higher firing temperatures, less porosity, finer texture, less calcareous composition and a more siliciclastic component. The general conclusion is that only specific types of Iberian amphorae were appropriate for short distance and occasional transport.

The westernmost of the Greek-Sicilian towns, Selinunte, founded in western Sicily during the second half of the seventh century BCE, gives amazing evidences of a historic activity of ceramic production (seventh to third century BCE). The present study aims to identify the raw materials available in the vicinity of the archaeological site of Selinunte, which were possibly used by the ancient potters, and to characterise them by means of petrographic and chemical techniques. A sampling campaign of clays and sands for tempering was undertaken in the archaeological site and the adjacent area. Moreover, locally produced archaeological bricks and tiles were considered helpful for comparison regarding the definition of local ceramic macro- and micro-fabrics and were analysed as well. The comparison between textural, mineralogical and chemical data allowed us to highlight a good similarity between the clayey materials available in the area and the local ancient bricks and tiles. Their compositional resemblance suggests the hypothesis of a systematic use of the studied clays for ceramic productions from the Archaic to the Hellenistic period. The preliminary archaeometric results obtained so far could enhance the distinction between local manufactures and imports and may well lead to the identification of ceramic artefacts produced by the Archaic-Hellenistic workshops of Selinunte at various consumption sites.

A selected assortment of Archaic-Hellenistic tableware samples from Solunto, a Phoenician-Punic site located 20 km east of Palermo (Sicily), has been subjected to thin-section petrography and chemical analysis (XRF). In this settlement several ceramic kilns remained operative over a long time period (7th to 3rd century B.C.). The main goal of this analytical study is to distinguish the ceramics manufactured locally from regional and off-island imports. Analytical results were matched to similar data concerning local natural clay sources and to coeval tableware productions from other sites in the same area. The ceramic pastes used by the ancient craftsmen of Solunto in the case of this class of pottery could be differentiated clearly by their petrochemical characteristics. We conclude that ceramics were locally produced far beyond satisfying just internal consumption needs, indicating interaction of Solunto with neighboring Greek colonies, indigenous people, and Phoenician-Punic colonies of Sicily. © 2009 Wiley Periodicals, Inc.

In questo studio sono state integrate osservazioni tipologiche, condotte su forme a vernice nera rinvenute a Palermo, Termini Imerese, Monte Iato e Marineo, con i dati ricavati dalla caratterizzazione mineralogica, petrografica e chimica degli impasti. I 55 campioni selezionati appartengono a due forme : un piatto («Lamboglia 36 » , serie 1310-1320 di J.-P. Morel), tra i più comuni nella Campana A di I e II secolo a. C. ; ed una coppa di produzione locale o regionale, attestata (fine IV-III secolo a. C.) in insediamenti della Sicilia nord-occidentale, che è stata utilizzata anche come «gruppo di riferimento » chimicopetrografico. Sono stati distinti due gruppi composizionali, da ascrivere uno all’area del Golfo di Napoli, l’altro ad ambito produttivo locale, che per le caratteristiche mineralogico-petrografiche e chimiche è riferibile alle Argille di Ficarazzi (periferia orientale di Palermo). Ad entrambi i gruppi appartengono reperti del piatto Lamboglia 36, ma solo al secondo i campioni della coppa., Belvedere Oscar, Burgio Aurelio, Iliopoulos Ioannis, Montana Giuseppe, Spatafora Francesca. Ceramica a vernice nera di età ellenistica da siti della Sicilia nord-occidentale : considerazioni tipologiche ed analisi archeometriche. In: Mélanges de l'École française de Rome. Antiquité, tome 118, n°2. 2006. Antiquité. pp. 549-571.

Ceramic ethnoarchaeology has been used to explore fully the chaîne opératoire and to understand all of the stages and factors involved in pottery production, such as raw material selection or paste recipes used by the potters. This work presents the results of the application of compositional analysis undertaken in the village of Pabillonis (western Sardinia, Italy), the main cooking ware production centre of the island. Pottery and local clays have been characterized using a combination of analytical techniques. By integrating the ethnographic information and the archaeometric approach, it was possible to reconstruct the operational sequence, exploring the relationship between the processing of raw materials and the functionality of the final products, and the intra-production compositional variability. © 2014 University of Oxford.

This paper deals with the comparative evaluation of different procedures of salt extraction designed for archaeological ceramics from submarine burial environments. The experimental work was carried out on a particular type of late-Roman cooking ware finds (Pantellerian ware) found in a shipwreck near the shoreline of the Island of Pantelleria (Sicily). The studied ceramic test-pieces were first recognised in terms of bulk characteristics (mineralogy, petrography and chemistry). SEM-EDS observation allowed verification of the presence of various secondary minerals at the surface and in the pore spaces formed after the prolonged permanence in seawater under oxidising or reducing conditions. Pore-size distribution was also determined in the same fragments that had been subjected to the salt extraction routines. Three salt extraction methods were tested: two methods based on diffusion processes (water immersion under stationary conditions and under mechanical stirring conditions) and one method based on both diffusive and advective processes (multiple packages of sepiolite). The obtained experimental data allowed us to identify strengths and weaknesses of the tested procedures with practical spin-off for archaeologists and restorers (efficiency, kinetics, compatibility with the ceramic substrate, costs and simplicity of use). Salt extraction under mechanical stirring was the most effective method and, for this reason, is suitable for laboratory fieldwork during or immediately after submarine archaeological excavations. Similar advantages are also intended for the preliminary treatments of the most precious findings prior to museum storage.

Deep blue glasses coloured by octahedral Fe 2+ cations are often reported as textbook examples of blue pigmentation. However, despite the possibility of laboratory synthesis under reducing conditions, to date there are no well-reported occurrences of their production and use in the past. A thorough historical, ethnographic, mineralogical, and chemico-physical investigation of the 'smaltini di calcara' from several baroque churches in Palermo, Sicily, has revealed that the blue enamels widely used for altar decorations in the 17th and 18th centuries are actually a unique case of ancient blue glasses pigmented by divalent iron cations in distorted octahedral coordination. This mixed-alkali glass was accidentally produced under severely reducing conditions in the local kilns during production of lime.