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Main observation and conclusion: One near‐infrared (NIR) luminescent octanuclear Zn(II)‐Yb(III) complex [Zn6Yb2L4(OAc)2(DMF)EtOH] (1) was obtained from a new multidentate Schiff base ligand. It exhibits interesting luminescent sensing activity to antibiotics, in particular to nitrofuran antibiotics (NFAs) with high sensitivity due to the inner filter effect. The NIR luminescence quenching constants and limits of the detection of the complex towards NFAs are 2.9 × 104—5.5 × 104 L/mol and 1.27—2.38 μmol/L, respectively. Its high luminescence sensitivity to NFAs is not changed with the existence of other antibiotics. [ABSTRACT FROM AUTHOR]

One NIR luminescent 14-metal Nd(III) nanoring (1, molecular size: 1.0 × 2.2 × 2.6 nm) was obtained from a rigid tridentate ligand, which can absorb and transfer light energy to the Nd(III) ions. 1 shows interesting luminescence sensing activity to antibiotics, in particular to NFAs with high sensitivity due to the inner filter effect. The quenching constants and the limits of detection of 1 to NFAs are 1.05 × 104 M−1–2.33 × 104 M−1 and 3.05 μM–6.75 μM, respectively. The high fluorescence sensitivities of 1 to NFAs are not changed by the existence of other antibiotics. It also exhibits high sensitivity in the luminescent detection of NFAs contained in real antibiotic drugs. [ABSTRACT FROM AUTHOR]

A 18-metal Yb(III) nanoring was constructed by the using of a Schiff base ligand. It exhibits interesting NIR luminescent sensing behavior to antibiotics and explosives, in particular to NFAs and TNP with high sensitivity. The K SV values and LODs of this lanthanide nanoring to NFAs and TNP are 1.5 × 104–4.6 × 104 (mol/L)−1 and 1.7–5.1 μmol/L, respectively. Its high luminescence sensitivities to NFAs and TNP are not affected by the existence of other antibiotics and explosives. [Display omitted] • The complex shows a ring-like structure. • The complex displays typical NIR lanthanide luminescence. • The complex exhibits NIR luminescence response to antibiotics and explosives. [ABSTRACT FROM AUTHOR]