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One NIR luminescent 14-metal Nd(iii) nanoring (1, molecular size: 1.0 × 2.2 × 2.6 nm) was obtained from a rigid tridentate ligand, which can absorb and transfer light energy to the Nd(iii) ions. 1 shows interesting luminescence sensing activity to antibiotics, in particular to NFAs with high sensitivity due to the inner filter effect. The quenching constants and the limits of detection of 1 to NFAs are 1.05 × 104 M-1-2.33 × 104 M-1 and 3.05 μM-6.75 μM, respectively. The high fluorescence sensitivities of 1 to NFAs are not changed by the existence of other antibiotics. It also exhibits high sensitivity in the luminescent detection of NFAs contained in real antibiotic drugs.

Two NIR luminescent Zn(II)/Cd(II)-Yb(III) complexes were obtained by the use of a Schiff base ligand with a binaphthyl backbone. Cd(II)-Yb(III) complex 2 has a triangular structure and exhibits interesting luminescent sensing activity to antibiotics, in particular to ciprofloxacin (CPFX) and norfloxacin (NFX) due to the inner filter effect. The limits of the detection of 2 to CPFX and NFX are 0.18 and 0.36 μM, respectively, and the fluorescence sensitivity is not changed with the existence of other antibiotics tested in this study.

One 18-metal Nd(III) nanoring, [Nd 18 (L 1 ) 8 (HL 2 ) 2 (OAc) 20 (MeOH) 8 (EtOH) 6 (H 2 O) 4 ]·2(MeOH)·6(H 2 O) ( 1 ), was constructed by the use of a hexadentate Schiff base ligand. For 1 , the near-infrared (NIR) luminescence of Nd(III) was detected under the excitation of absorption band at 371 nm. The study of luminescent sensing properties exhibits that, even with the existence of other antibiotics, this Nd(III) nanoring displays high sensitivity and selectivity to nitrofuran antibiotics (NFAs). The luminescence quenching constants and limits of detection of 1 to NFAs are found to be 1.4 × 10 4 to 3.5 × 10 4 M -1 and 0.9-2.2 μM, respectively.

One 12-metal Cd(II)-Yb(III) nanoring, [Cd 8 Yb 4 L 8 (OAc) 8 ]·4OH ( 1 ), with a size of 1.2 × 2.8 × 2.8 nm was obtained from a designed flexible salen-type ligand that has eight coordination sites (O and N atoms). The near-IR emission of Yb(III) at 983 nm was detected upon the excitation of ligand-central absorption at 386 nm. This Cd(II)-Yb(III) nanoring exhibits high sensitivity to nitrofuran antibiotics (NFAs) even in the presence of other antibiotics. The quenching constants and limits of detection of NFAs are 2.5 × 10 4 -4.5 × 10 4 M -1 and 1.5-2.8 μM, respectively.