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1. Reversible photochemically gated transformation of a hemicarcerand to a carcerand.

Author

Wang H, Liu F, Helgeson RC, and Houk KN

Subjects
Molecular Conformation, Photochemical Processes, Anthracenes chemistry, Bridged-Ring Compounds chemistry
Abstract

Guests in a gated community: introduction of two anthracene groups into a linker in a hemicarcerand creates a new type of photochemically controlled gated hemicarcerand. The reversible opening and closing of the "gate" of the host is controlled photochemically. The encapsulation and release of the guest molecules such as 1,4-dimethoxybenzene is controlled by irradiation with light of different wavelengths., (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Published
2013
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