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The market for urban distributed photovoltaics (DPV) is expected to take off in the next decade. However, these systems are often subject to complex urban contexts and sub-optimal conditions, requiring scalable and comprehensive solutions to detect their underperformances. In recent years, deep generative models (DGMs) have exhibited outstanding performance in the anomaly detection domain, dealing with generic high-dimensional time series data. Nevertheless, the existing applications of DGMs in the photovoltaic (PV) sector are still unable to account for environmental information, limiting their performance under various environmental conditions. This study proposes the Sequential Conditional Variational Autoencoder (SCVAE), which can cope with the sequential impacts of the environment on PV power generation. Using real-world data collected from 30 rooftop PV sites located across China, a data processing pipeline is developed to construct the training datasets which contain mostly normal samples for unsupervised SCVAE model training. This work also constructs a synthetic dataset with a wide variety of artificial anomalies in reference to the domain insights and engineering practice of DPV systems. After checking and refining by experts, the synthetic dataset can finally be used to validate the anomaly detection models. The results demonstrate that the SCVAE model outperforms existing state-of-the-art unsupervised anomaly detection models and can be effectively generalized to unseen PV sites. Moreover, the latent variables of SCVAE could be used to identify the type of DPV failure, thereby enabling more targeted diagnostics of anomaly mechanisms. • An anomaly detection method is proposed for DPV in various environmental scenarios. • A novel unsupervised model is proposed for time series anomaly detection. • A real-world data processing pipeline and a labeled synthetic dataset are proposed. [ABSTRACT FROM AUTHOR]