1. Saturated Zone Denitrification: Potential for Natural Attenuation of Nitrate Contamination in Shallow Groundwater Under Dairy Operations.
- Author
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Singleton, M. J., Esser, B. K., Moran, J. E., Hudson, G. B., McNab, W. W., and Harter, T.
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GROUNDWATER , *DENITRIFICATION , *CHEMICAL reduction , *NITRATES , *NITROGEN compounds , *OXYGEN , *ANIMAL feeding , *MASS spectrometry - Abstract
We present results from field studies at two central California dairies that demonstrate the prevalence of saturated-zone denitrification in shallow groundwater with ³H/³He apparent ages of <35 years. Concentrated animal feeding operations are suspected to be major contributors of nitrate to groundwater, but saturated zone denitrification could mitigate their impact to groundwater quality. Denitrification is identified and quantified using N and 0 stable isotope compositions of nitrate coupled with measurements of excess N2 and residual NO3- concentrations. Nitrate in dairy groundwater from this study has δ15N values (4.3–61‰), and δ18O values (-4.5–24.5‰) that plot with δ18O/δ15N slopes of 0.47–0.66, consistent with denitrification. Noble gas mass spectrometry is used to quantify recharge temperature and excess air content. Dissolved N2 is found at concentrations well above those expected for equilibrium with air or incorporation of excess air, consistent with reduction of nitrate to N2. Fractionation factors for nitrogen and oxygen isotopes in nitrate appear to be highly variable at a dairy site where denitrification is found in a laterally extensive anoxic zone 5 m below the water table, and at a second dairy site where denitrification occurs near the water table and is strongly influenced by localized lagoon seepage. [ABSTRACT FROM AUTHOR]
- Published
- 2007
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