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1. A Method for the Selective Protection of Aromatic Amines in the Presence of Aliphatic Amines

Author

Boulos Zacharie, Valérie Perron, Nancie Moreau, Christopher Penney, Devin Lee, and Shaun D. Abbott

Subjects
Aniline Compounds, Chemistry, Organic Chemistry, Organic chemistry, Regioselectivity, Catalysis
Abstract

A simple and efficient procedure has been developed for the regioselectiveprotection of aromatic amines in the presence of aliphatic amines.The method is general for the preparation of mono- N-Boc,- N-Cbz, - N-Fmocor - N-Alloc aromatic amines in high yieldwithout affecting the aliphatic amines. This approach is applicableto substituted (aminoalkyl)aniline compounds with different functionalitiesand was employed to supply gram quantities of the protected anilineproduct.

Published
2008
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