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Start Over Author "Goerls, Helmar" Topic anaerobes
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1. Formation of a Dinuclear Copper(I) Complex from the Clostridium-Derived Antibiotic Closthioamide.

Author

Kloss, Florian, Pidot, Sacha, Goerls, Helmar, Friedrich, Thorsten, and Hertweck, Christian

Subjects
METAL complexes, COPPER, CLOSTRIDIUM cellulolyticum, METABOLITES, MICROORGANISMS
Abstract

A metal chelator from the oxygen‐free world: Multiple lines of experimental evidence show that closthioamide, the first antibiotic from a strictly anaerobic bacterium (Clostridium), is a selective copper(I) chelator. The geometry of the polythioamide complex, in which two copper ions in a trigonal‐planar coordination stabilize the pitch of a helix‐like arrangement, is unprecedented for natural products. [ABSTRACT FROM AUTHOR]

Published
2013
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