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The temperature dependence of the current-voltage characteristics of Ni-InGaAs alloy Schottky contacts to n-In0.53Ga0.47As was measured. Nearly ideal plots with an ideality factor close to unity were obtained. The Arrhenius curve across the wide temperature range of 80-300 K was perfectly linear, yielding a barrier height of 0.239 ± 0.01 eV. This value is substantially larger than previously reported. Conventional metal based Schottky diodes did not exhibit an ideal Schottky behavior. The ideal Schottky diode characteristics are attributed to the lack of oxidation and contamination of the interface between Ni-InGaAs and InGaAs. [ABSTRACT FROM AUTHOR]

Ti-6Al-4V is one of the most widely used titanium alloys. However, it is susceptible to hydrogen embrittlement, e.g. due to hydride formation. Hydrogen permeability through Ti-based alloys is affected by the rapid formation of hydride or oxide surface layers as well as by trapping in the bulk alloy. Here, we analyze and compare the electrochemical hydrogen permeation (EHP) through wrought and electron beam melted (EBM) Ti-6Al-4V alloys. Hydrogen diffusion coefficients are calculated from the permeation current transients. The effective diffusion coefficient of hydrogen in the wrought alloy is found to be an order of magnitude higher than in the AM'ed alloy. The different microstructures of the wrought and EBM alloys are found to play an important role in hydrogen distribution and phase transformation in the alloy. In the EBM alloy, hydrogen is distributed more uniformly and, consequently, more pronounce phase transformations occur, eventually leading to brittle cracking. In the wrought alloy, on the other hand, hydrogen is distributed unevenly in the bulk of the membrane, forming hydride clusters, most probably at α/β interphase boundaries. These findings suggest that the EBM Ti-6Al-4V alloy is more susceptible to HE than its wrought counterpart. • Electrochemical hydrogen permeation (EHP) in wrought and EBM Ti6Al4V is studied. • A different permeation behavior is related to microstructure and hydride distribution. • A careful EHP procedure is established for Ti and its alloys. • Hydrogen diffusivity in the wrought alloy is an order of magnitude higher. • The EBM alloy is more susceptible to hydrogen embrittlement and cracking. [ABSTRACT FROM AUTHOR]