Search

Your search keyword '"McDouall, Joseph J. W."' showing total 2 results
Start Over Author "McDouall, Joseph J. W." Topic allene
2 results on '"McDouall, Joseph J. W."'

1. Copper-Catalyzed Borylative Cross-Coupling of Alienes and Imines: Selective Three-Component Assembly of Branched Homoallyl Amines.

Author

Rae, James, Yeung, Kay, McDouall, Joseph J. W., and Procter, David J.

Subjects
COPPER catalysts, COUPLING reactions (Chemistry), MOLECULAR self-assembly, AMINE analysis, IMINES, STEREOSELECTIVE reactions
Abstract

A copper-catalyzed three-component coupling of allenes, bis(pinacolato)diboron, and imines allows regio-, chemo-, and diastereoselective assembly of branched α,βsubstituted- g-boryl homoallylic amines, that is, products bearing versatile amino, alkenyl, and borane functionality. Alternatively, convenient oxidative workup allows access to α-substituted- β-amino ketones. A computational study has been used to probe the stereochemical course of the cross-coupling. [ABSTRACT FROM AUTHOR]

Published
2016
Full Text
View/download PDF

2. ChemInform Abstract: Copper-Catalyzed Borylative Cross-Coupling of Allenes and Imines: Selective Three-Component Assembly of Branched Homoallyl Amines.

Author

Rae, James, Yeung, Kay, McDouall, Joseph J. W., and Procter, David J.

Subjects
*ALLENE, *IMINES, *COPPER catalysts, *BORYLATION, *COUPLING reactions (Chemistry), *ALLYLAMINES
Abstract

A series of branched α,β-substituted-γ-boryl homoallylic amines (IV) is prepared by three-component reaction of imines (I) with allenes (II) and bis(pinacolato)diboron (III) in the presence of a copper catalyst. [ABSTRACT FROM AUTHOR]

Published
2016
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results