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Two asymmetrical amphiphilic phthalocyanines simultaneously containing hydrophobic alkoxy and hydrophilic 15-crown-5-ether substituents at the phthalocyanine periphery H2{Pc(15C5)3[(OC8H[Formula: see text]]}(Pc-1) and H2{Pc(15C5)[(OC8H[Formula: see text]]}(Pc-2) and their symmetrical analogue H2[Pc(OC8H[Formula: see text]] (Pc-3) have been synthesized and characterized. The Pc-n/CdS ([Formula: see text] 1, 2 and 3, respectively) hybrid films are obtained successfully via a simple quasi-Langmuir–Shäfer (QLS) method using H2S-vapor annealing over the Pc-n/Cd[Formula: see text] self-assembled film formed at the interface of the air/CdCl2 aqueous solution. The film-structure and properties of both the hybrid Pc-n/CdS and pure Pc-n films are comparatively studied by a wide range of methods including UV-vis, polarized UV-vis, XRD, SEM and I–V measurements. Experimental results exhibit a slipped co-facial stacking mode in an “edge-on” conformation ([Formula: see text]-type aggregate) formed for the phthalocyanine molecules in both pure Pc-n films and the corresponding Pc-n/CdS hybrid films, with increasing intermolecular [Formula: see text]–[Formula: see text] interactions in the order of Pc-n 2 in the 0.05–2.5 ppm range within a fast dynamic exposure period of 30 s. Strikingly, Pc-1/CdS hybrid film presents an unprecedented high sensitivity of 157.3%.ppm[Formula: see text] vs. very low NO2 concentration range of 0.05˜0.25 ppm, achieving one of the best room temperature sensing performances in terms of high sensitivity, rapid responsibility and low detection limit among self-assembled film-based NO2 sensors.