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1. Rate constants for the reactions of hydroxyl radical with several alkanes, cycloalkanes, and dimethyl ether

Author

DeMore, W.B. and Bayes, K.D.

Subjects
Chemical reaction, Rate of -- Research, Alkanes -- Research, Cyclic compounds -- Research, Methyl ether -- Research, Radicals (Chemistry) -- Research, Hydroxylation -- Research, Chemicals, plastics and rubber industries
Abstract

The rate constants for the reactions of OH with propane, n-butane, n-hexane, cyclopropane, cyclobutane, cyclohexane, cyclopentane and dimethyl ether were investigated. A persistent discrepancy was observed between absolute and relative rate measurements in the low temperature regime. Results also suggested that relative rate constant values can be used in simple Arrhenius expressions.

Published
1999

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