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We present the study of the superconducting order parameter in single crystals of alkali metal EuCsFe 4 As 4 pnictide belonging to the novel 1144 family, turning to the superconducting state in the stoichiometric composition at critical temperature T c ≈ 37 K, and showing an antiferromagnetic ordering below T c . In the superconducting state, using incoherent multiple Andreev reflection effect spectroscopy of superconductor-thin normal metal-superconductor (SnS) junctions, we show a multiple-gap superconductivity with possibly anisotropic large SC gap with an extended s-wave symmetry, and isotropic small SC gap. We directly determined the magnitudes, characteristic ratios, and temperature evolution of the superconducting gaps. The latter are found to be typical for a superconductor with rather weak interband interaction between SC condensates in the k-space. [ABSTRACT FROM AUTHOR]

We report crystal growth and characterization of 4 new ternary layered bismuthides with compositions KZn2Bi2 (I), RbZn2Bi2 (II), RbCd2Bi2 (III), and CsCd2Bi2 (IV) that belong to the vast 122 family of compounds. Single crystals were grown by self‐flux technique and characterized by a combination of powder X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, and single crystal X‐ray diffraction. All new compounds crystallize in the layered ThCr2Si2 structure type and exhibit the plate‐like morphology with weak bonding between layers. A significant structural difference between ACd2Bi2 and AZn2Bi2 is found and discussed. [ABSTRACT FROM AUTHOR]