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Start Over Author "Ye, Yinmei" Topic alcohols (chemical class)
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1. Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride.

Author

Chen, Long, Zhou, Teng, Chen, Lifang, Ye, Yinmei, Qi, Zhiwen, Freund, Hannsjörg, and Sundmacher, Kai

Subjects
OXIDATION, IONIC liquids, ALCOHOLS (Chemical class), CYCLOHEXANONES, IMIDAZOLES, CHLORIDES, HYDROGEN peroxide
Abstract

Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100% conversion of cyclohexanol with 100% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO3as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory. [ABSTRACT FROM AUTHOR]

Published
2011
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