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Start Over Author "Michelle Gilhespy" Topic alcohol oxidation
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1. Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

Author

Xavier Baucherel, Michelle Gilhespy, and Martin Lok

Subjects
Primary (chemistry), Chemistry, Metals and Alloys, Nitroxyl, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, Alcohol oxidation, Selective catalyst, Materials Chemistry, Ceramics and Composites, Organic chemistry, Molecular oxygen, Polymer supported
Abstract

PS-TEMPO, a polymer-supported 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)2 and Mn(NO3)2 as co-catalysts.

Published
2005
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