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Abstract: “Stickies” are tacky species, present in recycled paper and coated broke, derived from coating formulations, adhesives etc. They impact negatively on paper quality and cause web runnability problems by deposit build-up. To sustain recycling, stickies are controlled by adsorbing them onto minerals added to the recycled stock. We report isotherms for a fatty acid ester defoamer and an acrylic acid ester copolymer adsorbing from colloidal suspension onto various talcs and modified calcium carbonates. We used commercial preparations of the fatty acid ester defoamer and acrylic acid ester copolymer to provide a simple analogue to the industrial process. The modified calcium carbonates are hydrophilic with anionic and cationic sites present. Adsorption isotherms for low surface area modified calcium carbonate conform to the Langmuir model, while those for high surface area modified calcium carbonate reflect a two stage process involving the formation of a monolayer over the mineral surface and subsequent partial aggregation. Talc platelets display hydrophilic edges and hydrophobic surfaces. Adsorption onto them appears to involve three stages; specifically, a hydrophilic interaction between hydrophilic groups on the molecules and the talc edges, followed by hydrophobic interactions between the molecules and the talc surfaces, and finally by formation of multilayers. [ABSTRACT FROM AUTHOR]

Abstract: Mineral particles are used in many industrial applications as fillers, in coatings, as ad- and absorbers or in catalysis. In these manifold fields the particle size and shape control the final performance and properties of the minerals. Much has been published using different techniques to describe the aspect ratio of platy particles. This study describes a simple method to calculate aspect ratios for platy particles based on particle size data and specific surface area determined by nitrogen adsorption, exemplified with three different talc grades which vary in their amount of specific surface area and geological origin, as well as with one nano-sized synthetic Laponite (Laponite® RD) to illustrate the sensitivity to input parameters and their physical interpretation. The contrast between mass/volume and number probability distribution of particle size is discussed and illustrated. [Copyright &y& Elsevier]