22 results on '"Halizah Awang"'
Search Results
2. Reduction of COD and ammoniacal nitrogen from landfill leachate using granular activated carbon and green mussel adsorbent
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Mohd Baharudin Ridzuan, Zawawi Daud, Amir Detho, Mohd Arif Rosli, and Halizah Awang
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Granular activated carbon ,Adsorption ,Chemistry ,Leachate ,Mussel ,Ammoniacal nitrogen ,Pulp and paper industry - Published
- 2021
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3. Comparison study of COD and ammoniacal nitrogen adsorption on activated coconut shell carbon, green mussel (Perna viridis), zeolite and composite material in stabilized landfill leachate treatment
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Husnul Azan Tajarudin, Zawawi Daud, Halizah Awang, Amir Detho, Mohd Arif Rosli, Azhar Abdul Halim, and Mohd Baharudin Ridzuan
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Adsorption ,biology ,Chemistry ,Environmental chemistry ,Shell (structure) ,chemistry.chemical_element ,Mussel ,Leachate ,Ammoniacal nitrogen ,Zeolite ,biology.organism_classification ,Carbon ,Perna viridis - Published
- 2021
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4. COD and ammoniacal nitrogen reduction from stabilized landfill leachate using carbon mineral composite adsorbent
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Mohd Baharudin Ridzuan, Husnul Azan Tajarudin, Amir Detho, Halizah Awang, Zawawi Daud, Azhar Abdul Halim, Mohd Arif Rosli, and Mahamad Anuar Kamaruddin
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Adsorption ,Mineral ,Chemistry ,Composite number ,chemistry.chemical_element ,Leachate ,Ammoniacal nitrogen ,Pulp and paper industry ,Carbon - Published
- 2021
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5. Removal of COD and ammoniacal nitrogen by banana trunk fiber with chitosan adsorbent
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Radin Maya Saphira Radin Mohamed, Noorain Suhani, Adeleke Abdulrahman Oyekanmi, Ab Aziz Abdul Latiff, Halizah Awang, Nazlizan Nasir, Zawawi Daud, and Baharin Ahmad
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021110 strategic, defence & security studies ,General Mathematics ,0211 other engineering and technologies ,General Physics and Astronomy ,02 engineering and technology ,General Chemistry ,010501 environmental sciences ,Pulp and paper industry ,01 natural sciences ,General Biochemistry, Genetics and Molecular Biology ,Chitosan ,chemistry.chemical_compound ,Ammonia ,Adsorption ,chemistry ,Wastewater ,Sewage treatment ,Fiber ,Ammoniacal nitrogen ,General Agricultural and Biological Sciences ,Water pollution ,0105 earth and related environmental sciences - Abstract
Kitchen wastewater that is discharged to the environment is one of the contributing factors to water pollution in developing countries. Adsorption is one of the emerging technology of biological treatments that is an environmentally friendly for the removal of pollutants. Banana trunk fiber with chitosan as an adsorbent was investigated for minimizing COD and ammonia from the kitchen wastewater. The raw kitchen wastewater sample used in the study was collected from the Arked food court located in Universiti Tun Hussein Onn Malaysia in Johor (Malaysia). The optimum of ratio, pH, shaking speed and contact time for COD and ammonia removal were determined. The result indicated the optimum mix ratio of fiber with chitosan, pH, shaking speed and contact time respectively was 50:50, pH 7, 125 rpm and 120 minutes based on the adsorption of COD (87%) and ammonia (90%) by banana trunk fiber with chitosan. Kinetic study of the results gave a pseudo-second order the R2 was closed to unity which was 0.998. It will significantly be considered for efficient removal of organic and nutrient pollutants present in kitchen wastewater treatment.
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- 2020
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6. Equilibrium isotherm and kinetic study of the adsorption of organic pollutants of leachate by using micro peat-activated carbon composite media
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Zawawi Daud, Abdulrahman Oyekanmi Adeleke, Mohd Baharudin Ridzuan, Nur Adila Abd Aziz, Kaizar Hossain, Norli Ismail, Mohd Arif Rosli, and Halizah Awang
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Pollutant ,Adsorption ,Peat ,Chemistry ,Environmental chemistry ,medicine ,Composite media ,Leachate ,Kinetic energy ,Activated carbon ,medicine.drug - Published
- 2019
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7. Review on COD and ammoniacal nitrogen removal from landfill leachate using low-cost adsorbent
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Halizah Awang, Zawawi Daud, Mohd Baharudin Ridzuan, Mohd Arif Rosli, and Amir Detho
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Peat ,Municipal solid waste ,010504 meteorology & atmospheric sciences ,Nitrogen ,Population ,010501 environmental sciences ,Management, Monitoring, Policy and Law ,01 natural sciences ,Water Purification ,Adsorption ,medicine ,Humans ,Leachate ,Ammoniacal nitrogen ,education ,Zeolite ,Waste Management and Disposal ,0105 earth and related environmental sciences ,Biological Oxygen Demand Analysis ,education.field_of_study ,Waste management ,Denitrification ,Environmental science ,Water Pollutants, Chemical ,Activated carbon ,medicine.drug - Abstract
The rapid generation rate of solid waste is due to the increasing population and industrialization. Nowadays, solid waste has been a major concerning problem in handling and disposal thus adsorption treatment process has been introduced which is an effective and low-cost method in removing organic and inorganic compounds from leachates such as chemical oxygen demand (COD) and ammoniacal nitrogen (NH
- Published
- 2021
8. Micro-Peat as a Potential Low-Cost Adsorbent Material for COD and NH3-N Removal
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Azhar Abdul Halim, Zawawi Daud, Ab Aziz Abdul Latiff, Halizah Awang, Mohd Baharufin Ridzuan, and Mohd Arif Rosli
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High concentration ,Radiation ,Peat ,Chemistry ,02 engineering and technology ,010501 environmental sciences ,Condensed Matter Physics ,Pulp and paper industry ,01 natural sciences ,Adsorption ,020401 chemical engineering ,medicine ,General Materials Science ,Leachate ,0204 chemical engineering ,Ammoniacal nitrogen ,0105 earth and related environmental sciences ,Activated carbon ,medicine.drug - Abstract
Micro-peat (M-P) was demonstrated in the present study as a potential low cost natural adsorbent for the removal of COD and ammoniacal nitrogen (NH3-N) from landfill leachate. A series of batch experiments were carried out under fixed conditions and the influence of mixture ratio was investigated. The characteristics of leachate were then determined. Results indicated that leachate is non-biodegradable with high concentration of COD (2739.06 mg/L), NH3-N (1765.34 mg/L) and BOD5/COD ratio (0.09). The optimum ratio for activated carbon (AC) and M-P in the removal of COD and NH3-N obtained were at 2.5:1.5 (87%) and 1.0:3.0 (65%) respectively. The low-cost natural adsorbent used in the present investigation is an attractive alternative to the conventional adsorbent (AC). Thus, M-P can be appropriated for use in leachate treatment that could be cost-effective due its local availability and adsorption property.
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- 2018
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9. Potential of Agro Waste-Derived Adsorbent Material for Colour Removal
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Halizah Awang, Aeslina Abdul Kadir, Nazlizan Nasir, Zawawi Daud, Azhar Abdul Halim, Mohd Baharufin Ridzuan, and Ab Aziz Abdul Latiff
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0106 biological sciences ,Radiation ,Chemistry ,Langmuir adsorption model ,010501 environmental sciences ,Condensed Matter Physics ,Pulp and paper industry ,01 natural sciences ,symbols.namesake ,Adsorption ,Wastewater ,Natural rubber ,010608 biotechnology ,visual_art ,Monolayer ,symbols ,visual_art.visual_art_medium ,General Materials Science ,Sewage treatment ,Freundlich equation ,0105 earth and related environmental sciences ,Agro waste - Abstract
The potential of Empty Fruit Bunch obtained from palm oil tree as a low-cost adsorbent is a sustainable approach in wastewater treatment. The objective this study to investigate the capability of EFB for removal colour from natural rubber wastewater as well as the influence of adsorbent dosage, pH, shaking speed and contact time. The results of the analysis show that all selected factors exhibit significant effect on removal of colour. Maximum removal (87.1%) for colour was achieved at 3.5 g of adsorbent dosage, pH 7, 150 rpm of shaking speed, 120 min of contact time. The Langmuir isotherm (R2= 0.9913) described colour adsorption slightly better than the Freundlich isotherm (R2= 0.9805), suggesting a monolayer adsorption behavior of the adsorption processes
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- 2018
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10. Limestone-Zeolite Biocomposite as Potential Low-Cost Adsorbent for Landfill Leachate Remediation
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Halizah Awang, Mohd Baharudin Ridzuan, Zawawi Daud, and Mohd Arif Rosli
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Adsorption ,Waste management ,Environmental remediation ,Chemistry ,Leachate ,Biocomposite ,Zeolite - Abstract
A novel approach for the low-cost bioadsorbent for the removal of leachate pollutants is presented herein. In this study, limestone is combined with zeolite in order to fabricate biocomposite media with different ratios. Results revealed that limestone-zeolite biocomposite adsorbed ammoniacal nitrogen (NH3-N) and COD, which could possibly be used for the adsorption of NH3-N and COD efficiently from leachate. The optimum mixing ratio by means was carried out using series of batch experiments for limestone and zeolite to measure the remediation of NH3-N and COD in a stabilized leached. The optimum ratio for limestone and zeolite in the remediation of NH3-N and COD obtained were at 25:15 (82%) and 30:10 (75%), respectively. Indeed, the prepared limestone-zeolite biocomposite is a low-cost and effective adsorbent was potential used to derive the NH3-N and COD for a promising adsorption efficiency from stabilized landfill leachate.
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- 2020
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11. Utilization of Zeolite-Feldspar as an Potential Adsorbent for the Adsorption of COD and Ammonical Nitrogen in Stabilized Landfill Leachate
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Mohd Baharudin Ridzuan, Amir Detho, Nair Gomesh, Mohd Arif Rosli, Zawawi Daud, Husnul Azan Tajarudin, Halizah Awang, and Ragunathan Santiagoo
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Adsorption ,chemistry ,visual_art ,Environmental chemistry ,visual_art.visual_art_medium ,chemistry.chemical_element ,Leachate ,Feldspar ,Zeolite ,Nitrogen - Abstract
The robust combination of landfill waste recognized as a potential source of hazards. Landfills is one relatively distinctive issue associated with leachate. Generally, zeolite is considered a known adsorbent however relatively very high in cost. Meanwhile, Feldspar is the world’s most common mineral groups which making up as much as about 60 percent of the crust of the earth. Its quality and availability makes the feldspar become relatively low price material. The mixture of feldspar-zeolite are believe to produces effective and inexpensive composite for the treatment of leachate wastewater. The batch experiment was conducted in an Erlenmeyer flask, 250 mL volume with varying the volume of composite mixture ratio and then shaking for 5 hrs with 200 rpm at pH7. The optimum mixing ratio of feldspar-zeolite is chosen 1:1. The optimum removal of COD and ammonical nitrogen is 55% and 50% respectively. The availability of low-cost materials such as feldspar in the composite has helped to minimize the cost of treatment and has helped to increase the potential capacity for adsorption.
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- 2020
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12. Experimental Approach for Chemical Oxygen Demand and Ammonia Nitrogen Removal from Natural Rubber Wastewater via Adsorption by Kaolin
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Zawawi Daud, Nair Gomesh, Ragunathan Santiagoo, Amir Detho, Husnul Azan Tajarudin, Nazlizan Nasir, Mohd Baharudin Ridzuan, and Halizah Awang
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Adsorption ,Natural rubber ,Wastewater ,Chemistry ,Environmental chemistry ,visual_art ,Chemical oxygen demand ,visual_art.visual_art_medium ,Ammonia nitrogen - Abstract
Natural rubber is an important material because of its high strength compared to synthetic rubber. However, the production process of natural rubber discharges a large amount of wastewater containing high concentrations of organic compounds and nitrogen. Therefore, discharging natural rubber processing wastewater without an appropriate treatment can lead to environmental problems such as deterioration of water quality and eutrophication. In this study, the batch adsorption experiment was carried out for the removal of chemical oxygen demand (COD) and ammonia nitrogen from natural rubber wastewater using kaolin as adsorbent. The efficiency of the kaolin was studied by varying the parameters adsorbent dose, pH, shaking speed and contact time. The experimental equilibrium data for this system has been analyzed using the linearized forms of Langmuir and Freundlich isotherms. COD and ammonia nitrogen removal efficiencies were 71.6% and 75.8%, respectively. While, Langmuir isotherm was found to provide the best theoretical correlation of the experimental data.
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- 2020
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13. Adsorption Efficiency and Isotherms of COD and Color Using Limestone and Zeolite Adsorbents
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Halizah Awang, Husnul Azan Tajarudin, Mahmoud Hijab Abubakar, Mohd Shalahuddin Adnan, Mohd Arif Rosli, Mohd Baharudin Ridzuan, Zawawi Daud, and Nur Adila Ab Aziz
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chemistry.chemical_classification ,Chemistry ,Mechanical Engineering ,Materials Science (miscellaneous) ,Langmuir adsorption model ,02 engineering and technology ,010501 environmental sciences ,021001 nanoscience & nanotechnology ,01 natural sciences ,Industrial and Manufacturing Engineering ,symbols.namesake ,Adsorption ,Chemical engineering ,Mechanics of Materials ,Percolation ,Monolayer ,symbols ,Organic matter ,Leachate ,Electrical and Electronic Engineering ,0210 nano-technology ,Zeolite ,Water pollution ,0105 earth and related environmental sciences ,Civil and Structural Engineering - Abstract
Leachate is a liquid generated due to rainwater percolation through the wastes in a landfill or dumping site that may contain high levels of organic matter including both biodegradable and non-biodegradable which major source of water pollution. In this research work, landfill leachate has been characterized and found to contain very high COD and color. Adsorption process was performed to find out the performance of different combinations ratio between limestone (LS) and zeolite (ZEO). The removal efficiencies of different ratios were examined for reduction of COD and color. The optimum mixture ratio of adsorbents (LS:ZEO) at 10:30 and 15:25 were found to be more effective in reducing COD and color respectively as compared with the use of individual media. The highest removal percentage were found at approximately 55% of COD and 76% of color with 120 minutes of contact time, 200 rpm in shaking speed at pH7. The Langmuir adsorption isotherm model exhibited a better fit with high correlation R2=0.9991 for COD and R2=0.9827 for (color) respectively, which implies that the adsorption of leachate in this study onto LS-ZEO is homogeneous with monolayer. It was observed that limestone and zeolite mixture provides an alternative medium for removing COD and color at a considerably lower cost.
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- 2018
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14. Chitosan Beads as an Adsorbent for the Removal of Colour from Natural Rubber Wastewater
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Nazlizan Nasir, Mohd Baharudin Ridzuan, Halizah Awang, Baharin Ahmad, Nur Adila Ab Aziz, Zawawi Daud, and Husnul Azan Tajarudin
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Langmuir ,Materials Science (miscellaneous) ,010501 environmental sciences ,01 natural sciences ,Organic compound ,Industrial and Manufacturing Engineering ,Chitosan ,chemistry.chemical_compound ,symbols.namesake ,Adsorption ,Natural rubber ,Freundlich equation ,Electrical and Electronic Engineering ,0105 earth and related environmental sciences ,Civil and Structural Engineering ,chemistry.chemical_classification ,Chemistry ,Mechanical Engineering ,010401 analytical chemistry ,Langmuir adsorption model ,0104 chemical sciences ,Wastewater ,Mechanics of Materials ,visual_art ,visual_art.visual_art_medium ,symbols ,Nuclear chemistry - Abstract
Natural rubber processing wastewater contains high concentration of organic compound, colour, nitrogen, and other contaminants. This study evaluated a chitosan bead as an adsorbent in adsorption process for natural rubber wastewater treatment. The effects of adsorbent dosage, pH, shaking speed and contact time and adsorption isotherm on colour adsorption onto chitosan beads were evaluated using batch experiments. Meanwhile, Langmuir and Freundlich isotherm models were used to validate the experimental data. Maximum removal of 71.5%, for colour was observed for an adsorbent dosage 4.5 g, pH 7, and shaking speed 150 rpm. Equilibrium was achieved in 120 min. The equilibrium data were fitted to Langmuir isotherm model when compared with Freundlich isotherm models.
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- 2018
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15. Optimization of Batch Conditions for COD and Ammonia Nitrogen Removal Using cockle shells Through Response Surface Methodology
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Zawawi Daud, Mohd Baharudin Ridzuan, Zainab Belel Ahmed, Mahmoud Hijab Abubakar, Halizah Awang, Mohd Arif Rosli, Husnul Azan Tajarudin, and Ruwaida Aliyu
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010504 meteorology & atmospheric sciences ,Central composite design ,Chemistry ,Mechanical Engineering ,Materials Science (miscellaneous) ,010501 environmental sciences ,Pulp and paper industry ,01 natural sciences ,Industrial and Manufacturing Engineering ,Ammonia nitrogen ,Adsorption ,Mechanics of Materials ,Response surface methodology ,Electrical and Electronic Engineering ,Cockle ,Effluent ,0105 earth and related environmental sciences ,Civil and Structural Engineering - Abstract
The optimal conditions for the reduction of COD and NH3-N using cockle shells (CS) from a stabilised landfill effluent were analyzed. The influence of two variables (adsorbent dosage and pH) were analysed through the application of response surface methodology (RSM) and central composite design (CCD). Quadratic models were developed for the removals of COD and NH3-N parameters. The optimum conditions for removal of 65.6% and 53.6% for COD and NH3-N respectively was achieved at pH 6.34, adsorbent dosage of 20.21 g having 0.888 desirability value. The model F-value obtained for NH3-N removal Prob. > F value of 0.0001 with F-value of 104.21 was obtained. Similarly the Prob. > F value of < 0.0001 for COD with F-value of 82.74 was obtained, these P-values confirmed the significance of the model. The predicted response versus the experimental response depicted that the experimental data were relatively close to the predicted data. Thus, the generated models significantly enclosed the correlation between the process variables and the response. GMT Detect languageAfrikaansAlbanianArabicArmenianAzerbaijaniBasqueBelarusianBengaliBosnianBulgarianCatalanCebuanoChichewaChinese (Simplified)Chinese (Traditional)CroatianCzechDanishDutchEnglishEsperantoEstonianFilipinoFinnishFrenchGalicianGeorgianGermanGreekGujaratiHaitian CreoleHausaHebrewHindiHmongHungarianIcelandicIgboIndonesianIrishItalianJapaneseJavaneseKannadaKazakhKhmerKoreanLaoLatinLatvianLithuanianMacedonianMalagasyMalayMalayalamMalteseMaoriMarathiMongolianMyanmar (Burmese)NepaliNorwegianPersianPolishPortuguesePunjabiRomanianRussianSerbianSesothoSinhalaSlovakSlovenianSomaliSpanishSundaneseSwahiliSwedishTajikTamilTeluguThaiTurkishUkrainianUrduUzbekVietnameseWelshYiddishYorubaZulu AfrikaansAlbanianArabicArmenianAzerbaijaniBasqueBelarusianBengaliBosnianBulgarianCatalanCebuanoChichewaChinese (Simplified)Chinese (Traditional)CroatianCzechDanishDutchEnglishEsperantoEstonianFilipinoFinnishFrenchGalicianGeorgianGermanGreekGujaratiHaitian CreoleHausaHebrewHindiHmongHungarianIcelandicIgboIndonesianIrishItalianJapaneseJavaneseKannadaKazakhKhmerKoreanLaoLatinLatvianLithuanianMacedonianMalagasyMalayMalayalamMalteseMaoriMarathiMongolianMyanmar (Burmese)NepaliNorwegianPersianPolishPortuguesePunjabiRomanianRussianSerbianSesothoSinhalaSlovakSlovenianSomaliSpanishSundaneseSwahiliSwedishTajikTamilTeluguThaiTurkishUkrainianUrduUzbekVietnameseWelshYiddishYorubaZulu Text-to-speech function is limited to 200 characters Options : History : Feedback : DonateClose
- Published
- 2018
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16. Chitosan ultilization in biocomposite adsorbent in Iron (Fe) removal from landfill leachate
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Farah Nur Diyana Ibrahim, Mahmoud Hijab Abubakar, Zulkifli Ahmad, Halizah Awang, Mohd Baharudin Ridzuan, Zawawi Daud, Nur Adila Ab Aziz, and Husnul Azan Tajarudin
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Pollutant ,010405 organic chemistry ,Chemistry ,Mechanical Engineering ,Materials Science (miscellaneous) ,010402 general chemistry ,01 natural sciences ,Industrial and Manufacturing Engineering ,0104 chemical sciences ,Catalysis ,Chitosan ,chemistry.chemical_compound ,Adsorption ,Wastewater ,Mechanics of Materials ,Leachate ,Electrical and Electronic Engineering ,Biocomposite ,Zeolite ,Civil and Structural Engineering ,Nuclear chemistry - Abstract
Leachate are very high strength wastewaters that contain a variety of pollutants that pose a serious threat to the environment if appropriate control measure is ignored. Composite adsorbent is an emerging, interesting and attractive alternative to conventional adsorbents and having the ability to act as catalysts due to their high reactivity and excellent selectivity towards specific pollutant compounds. This study investigated the potential of biocomposite adsorbent made from a combination of chitosan, feldspar and zeolite (CFZ) for the treatment of Iron (Fe) from leachate wastewater. Leachate characterization and batch adsorption experiments was conducted to determine the optimum conditions for pH, dosage and contact time parameter in the removal of Fe. The result shows that the concentration of Fe was 15.82 which exceeded the recommended limit. The optimum conditions also occurred at pH 5 with 6 gram of biocomposite dosage and at 180 minutes contact time. The corresponding removal efficiency for Fe is 90% with 0.0127 mg/g uptake capacity
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- 2018
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17. Removal of COD Using Delonix Regia Pods Activated Carbon Adsorbent for Natural Rubber Wastewater Treatment
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Mahmoud Hijab Abubakar, Baharin Ahmad, Mohd Baharudin Ridzuan, Husnul Azan Tajarudin, Halizah Awang, and Zawawi Daud
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Pollutant ,biology ,Chemistry ,Mechanical Engineering ,Materials Science (miscellaneous) ,Pulp and paper industry ,biology.organism_classification ,Industrial and Manufacturing Engineering ,Adsorption ,Natural rubber ,Wastewater ,Mechanics of Materials ,visual_art ,visual_art.visual_art_medium ,medicine ,Sewage treatment ,Response surface methodology ,Electrical and Electronic Engineering ,Delonix regia ,Civil and Structural Engineering ,Activated carbon ,medicine.drug - Abstract
Plant waste such as Delonix Regia Pods have the potential to be used as absorbents. A study of activated carbon derived from delonix regia pods was carried out for the removal COD in natural rubber wastewater. Sample wastewater was obtained from the rubber processing industry and characterized to determine the level of pollutant content. Results of the analysis of wastewater characterization shows that the COD value was 5196 mg/L which is above discharge standards. Laboratory experiments was conducted to determine the optimum dosage, pH, shaking speed and contact time using response surface methodology. The results showed that the optimal dosage, pH, shaking speed and contact time were 4 g, pH 8, 150 rpm and 100 minutes with COD removal value of 70.65 %. The model F-value obtained for COD was 68.27 with the Prob. > F value of < 0.0001 indicating the significance of the model. The predicted versus the empirical data were relatively close to each other, therefore the developed models sufficiently described the response and variables interaction in the adsorption process. The results also indicate the suitability of the adsorbent for application in a sustainable wastewater treatment. It is recommended that further study be carried out to assess its application for other pollutants derived from non-rubber industries.
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- 2018
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18. Ammoniacal Nitrogen Removal Using flamboyant pods (Delonix Regia) Adsorbent for Natural Rubber Wastewater Treatment
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Baharin Ahmad, Halizah Awang, Zawawi Daud, Mahmoud Hijab Abubakar, Nazlizan Nasir, and Husnul Azan Tajarudin
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Materials Science (miscellaneous) ,Environmental pollution ,010501 environmental sciences ,01 natural sciences ,Industrial and Manufacturing Engineering ,Adsorption ,Natural rubber ,0502 economics and business ,Electrical and Electronic Engineering ,Ammoniacal nitrogen ,0105 earth and related environmental sciences ,Civil and Structural Engineering ,biology ,Chemistry ,Mechanical Engineering ,05 social sciences ,biology.organism_classification ,Pulp and paper industry ,Environmentally friendly ,Wastewater ,Mechanics of Materials ,visual_art ,visual_art.visual_art_medium ,Sewage treatment ,Delonix regia ,050203 business & management - Abstract
Plant waste such as Delonix Regia Pods (DRP) have the potential to be used as adsorbents. A study of lignocellulose delonix regia pods was carried to assess ammoniacal nitrogen removal from natural rubber wastewater. Sample wastewater was taken from the rubber processing industry and characterization was carried out. Outcomes from the analysis shows that the ammoniacal nitrogen concentration was 66 mg/L and higher than the recommended wastewater discharge standards. Batch experiments were conducted on the effect of dose, pH, shaking speed and contact time parameters for optimum condition. The results revealed that the optimal dosage, pH, shaking speed and contact time is 4.5 g, pH 8, 150 rpm and 120 minutes with ammoniacal nitrogen removal efficiency of 74.3 % and the adsorption capacity of 1.22 mg/g. Pseudo second order kinetic model was found to fit the data better and the R2 obtained was 0.9992. From the study, it can be concluded that the media can be used for the removal of ammoniacal nitrogen in natural rubber wastewater and subsequently reduce environmental pollution. Hence, it can be sustainable and environmentally friendly.
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- 2018
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19. Utilization of Empty Fruit Bunch Fibre as Potential Adsorbent for Ammonia Nitrogen Removal in Natural Rubber Wastewater
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Mahmoud Hijab Abubakar, Mohd Baharudin Ridzuan, Zawawi Daud, Nazlizan Nasir, Baharin Ahmad, Husnul Azan Tajarudin, Halizah Awang, and Nur Adila Ab Aziz
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Chemistry ,Mechanical Engineering ,Materials Science (miscellaneous) ,Langmuir adsorption model ,Industrial and Manufacturing Engineering ,Ammonia nitrogen ,symbols.namesake ,Adsorption ,Natural rubber ,Wastewater ,Chemical engineering ,Mechanics of Materials ,visual_art ,Monolayer ,visual_art.visual_art_medium ,symbols ,Freundlich equation ,Fiber ,Electrical and Electronic Engineering ,Civil and Structural Engineering - Abstract
The objective of this study was to identify the performance of empty fruit bunch (EFB) to assess its use as potential adsorbent in treat ammonia nitrogen in natural rubber wastewater. The adsorption method was employed to investigate the effect of a number of factors, namely, adsorbent dosage, pH, shaking speed and contact time. The results revealed that the removal of ammonia nitrogen up to 79.5% from natural rubber wastewater. The adsorption efficiency of EFB fibre was maximum at 3.5 g dosage, pH 7, 150 rpm shaking speed and 120 min contact time. The results proved that EFB fiber are good alternative low cost adsorbent for the removal of ammonia nitrogen from natural rubber wastewater. The Langmuir isotherm (R2=0.9923) described ammonia nitrogen adsorption slightly better than the Freundlich isotherm (R2 = 0.9450), suggesting a monolayer adsorption behaviour of the adsorption processes.
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- 2018
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20. COD AND AMMONIA REMOVAL FROM LANDFILL LEACHATE USING MIXED GRANULAR ADSORBENT MEDIA
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Mohd Baharudin Ridzuan, Mahmoud Hijab Abubakar, Halizah Awang, Zawawi Daud, Zulkifli Ahmad, and Ab Aziz Abdul Latiff
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Chemistry ,Environmental remediation ,General Engineering ,Langmuir adsorption model ,Contamination ,Pulp and paper industry ,Ammonia ,chemistry.chemical_compound ,symbols.namesake ,Adsorption ,symbols ,Freundlich equation ,Particle size ,Leachate - Abstract
Landfills generate leachate that contains elevated concentration of contaminants and is hazardous to human health and the ecosystem. In this study, the mixture of granular feldspar and cockle shells was investigated for remediation of COD and ammonia from landfill leachate. All adsorbent media were sieved to a particle size between 2.00 and 3.35 mm. The results revealed that the optimum mixing ratio of feldspar and cockle shells was 20:20, shaking speed was 150 rpm, pH level was 6, shaking time was 120 min, and dosage was 30 g. The adsorption isotherm analysis reveals that the Langmuir isotherm yielded the best fit to experimental data as compared to the Freundlich isotherm. The media produce encouraging results and can potentially be used as a good and sustainable adsorbent.
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- 2018
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21. ADSORPTION STUDIES OF LEACHATE ON COCKLE SHELLS
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Aeslina Abdul Kadir, Mahmoud Hijab Abubakar, Halizah Awang, Abdul Aziz Abdul Latiff, Azhar Abdul Halim, Zawawi Daud, and Aminaton Marto
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Biochemical oxygen demand ,021110 strategic, defence & security studies ,Environmental Engineering ,Municipal solid waste ,Chemistry ,Chemical oxygen demand ,0211 other engineering and technologies ,Environmental engineering ,Soil Science ,Langmuir adsorption model ,02 engineering and technology ,Building and Construction ,010501 environmental sciences ,Geotechnical Engineering and Engineering Geology ,Pulp and paper industry ,01 natural sciences ,symbols.namesake ,Adsorption ,symbols ,Freundlich equation ,Leachate ,Cockle ,0105 earth and related environmental sciences - Abstract
Sanitary landfills are important means of disposing municipal solid waste in developing countries. However, these landfills are associated with the generation of leachate, which if untreated may pose severe public health risk and may damage the ecosystem in the long term. In this study, cockle shells were explored as an adsorbent media for the treatment of a stabilized landfill leachate. The optimum shaking speed, pH, and dosage for chemical oxygen demand (COD) parameter removal were investigated using the adsorbent media of particle sizes ranging from 2.00 mm to 3.35 mm. Leachate characteristics were then determined. Results indicated that leachate is non-biodegradable with high concentrations of COD (1763 mg/L), ammonia nitrogen (573 mg/L), and biochemical oxygen demand/COD (0.09). The optimum conditions for shaking were determined at 150 rpm according to the adsorption of COD by the media. Optimum pH and dosage was 5.5 and 35 g/L, respectively. The adsorption isotherms indicated that Langmuir isotherm is better fitted than Freundlich isotherm.
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- 2017
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22. Optimization of Leachate Treatment with Granular Biomedia: Feldspar and Zeolite
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Aeslina Abdul Kadir, Halizah Awang, Mahmoud Hijab Abubakar, Zawawi Daud, Ab Aziz Abdul Latiff, Aminaton Marto, and Azhar Abdul Halim
- Subjects
Multidisciplinary ,020209 energy ,02 engineering and technology ,Contamination ,Feldspar ,Pulp and paper industry ,Ammonia ,chemistry.chemical_compound ,Adsorption ,chemistry ,Hazardous waste ,visual_art ,0202 electrical engineering, electronic engineering, information engineering ,visual_art.visual_art_medium ,Environmental science ,Particle size ,Leachate ,Zeolite - Abstract
Background/Objectives: Landfills generate leachate having an elevated concentration of contaminants and hazardous to health and the ecosystem. Feldspar and zeolite mixture was investigated for minimizing COD and ammonia from the leachate. Methods/Statistical Analysis: All adsorbent media were sieved to a particle size between 2.00 and 3.35 mm. The optimum shaking speed, mixing ratio, and pH were determined. Raw leachate Sample used in the study was collected from the influent of the detention pond at the SimpangRenggam Municipal landfill in Johor (Malaysia). Findings: Results of the leachate characteristics indicated a non-biodegradable leachate with a high concentration of COD (1763 mg/L), ammonia nitrogen (573 mg/L) and BOD5/COD ratio (0.09). The optimum condition for shaking speed was 150 rpm, the optimum mix ratio of zeolite and feldspar was 20:20, and the optimum pH was 6–6.5. Applications/Improvements: The mixed media produced encouraging results for leachate treatment. It will significantly be applicable in reducing zeolite usage conventionally and consequently decreasing the operational cost in leachate treatments.
- Published
- 2016
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