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1. Visible-light-mediated metal-free decarboxylative acylations of isocyanides with α-oxocarboxylic acids and water leading to α-ketoamides.

Author

Lv, Yufen, Bao, Pengli, Yue, Huilan, Li, Jiang-Sheng, and Wei, Wei

Subjects
*LEAD in water, *ACIDS, *HYDRATION, *DECARBOXYLATION, *ACYLATION
Abstract

An efficient visible-light-promoted approach for preparing α-ketoamides from α-oxocarboxylic acids, isocyanides and water is disclosed. The present transformation could be achieved under mild and metal-free conditions through a sequence of decarboxylation, radical addition and hydration processes, which provides a novel and facile route to construct α-ketoamides from simple and readily available chemical feedstocks. [ABSTRACT FROM AUTHOR]

Published
2019
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