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Your search keyword '"Crosthwaite, Jacob M."' showing total 1 results
Start Over Author "Crosthwaite, Jacob M." Topic acetonitrile
1 results on '"Crosthwaite, Jacob M."'

1. Epoxidation of alkenes by Oxone™ using 2-alkyl-3,4-dihydroisoquinolinium salts as catalysts in ionic liquids

Author

Crosthwaite, Jacob M., Farmer, Victoria A., Hallett, Jason P., and Welton, Tom

Subjects
*IONIC liquids, *ALKENES, *SOLVENTS, *ACETONITRILE
Abstract

Abstract: A number of ionic liquids have been used as co-solvents for the N-alkyl-3,4-dihyroisoquinoliunium catalyzed epoxidation of alkenes. Water miscible ionic liquids gave systems with similar reactivities to the conventional acetonitrile based systems. Attempts to produce an aqueous/ionic liquid biphasic system that could be used to recycle the catalyst failed due to a lack of phase transfer between the aqueous and ionic liquid phases. [Copyright &y& Elsevier]

Published
2008
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