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Studies show that the dispersion of silica in the mixing process is an important factor affecting the wear of the mixing chamber. As the most important mixing equipment, the long operational life of the internal mixer will cause wear in the rotor and chamber of the internal mixer. This wear increases the gap between the rotor and chamber of the internal mixer, reduces the mixing performance, weakens the dispersion of packing, and adversely affects the quality of the rubber produced. Therefore, it is important to investigate the metal wear in the mixing process. This article examines the effect of the addition of different amounts of silane coupling agents on metal friction and wear during the mixing process. The silane coupling agent has two functions. The first is to make the surface of the silica hydrophobic, enabling it to combine the inorganic matrix of the silica with the organic matrix of the rubber; the second is to inhibit the aggregation of the silica in the rubber. In the present study, we examine (1) the influence of different formulations on the friction and wear of the metal in the mixing chamber from the perspective of formulation technology, and (2) the correlation between corrosion wear and abrasive wear. It is found that a rubber compound with 6 phr of TESPT has the lowest metal wear and that adding more TESPT does not affect the degree of metal wear. As the amount of TESPT increases, the proportion of abrasive wear decreases, while the proportion of corrosive wear increases, reaching a maximum of 20.7%. In our study we found that abrasive wear is the predominant wear mechanism of a rubber compound on metal. In contrast, the corrosive wear caused by high-temperature water vapor still occupies a large proportion of the total wear. Therefore, improving silica dispersion and reducing abrasive wear are extremely important methods to protect the mixing chamber. However, the corrosion of metals by high-temperature water vapor should also be considered when preparing for the mixing process. [ABSTRACT FROM AUTHOR]

Internal mixer is an important mixing equipment. After working for a long time, the end face of the internal mixer will be worn. The abrasion of the end face can increase the gap between the mixing chamber and the end face, and then material leakage occurs, which reduces the mixing effect and affects the performance of rubber compound. Therefore, it is very necessary to study the wear of the end face in the mixing process. As one‐dimensional nanomaterial, carbon nanotubes (CNTs) have a perfect hexagonal structure and many unusual mechanical, electrical and chemical properties. In recent years, with the deepening of the research of CNTs and nanomaterial's, their broad application prospects have also been continuously revealed. This paper analyzes the influence of rubber compounds with different CNTs content on the friction and wear of the end face from the perspective of formulation, and the correlation between corrosive wear and abrasive wear is studied. In the present study, it is found that as CNTs increase, the proportion of abrasive wear increases, the proportion of corrosive wear decreases, and the amount of the metal wear decreases. With the increase of CNTs, the hindering effect of CNTs on SiO2 molecules is strengthened, the degree of silanization reaction is reduced, the output of high‐temperature water vapor is reduced, and the corrosive wear of the metal is reduced. The spatial structure of CNTs is a cylinder with hexagonal plane, and it has extremely high toughness and softness, so it has slight wear on the metal. On the one hand, CNTs hinder the movement of SiO2 molecules. On the other hand, because CNTs have the wrapping effect on SiO2 molecules, some silica aggregates have no direct contact with the metal, CNTs become the medium for silica aggregates to contact with the metal. Therefore, with the increase of CNTs, the proportion of abrasive wear gradually increases, but the total amount of the metal wear gradually decreases. [ABSTRACT FROM AUTHOR]

Internal mixer is one the most commonly used rubber‐mixing equipment, which has been applied for decades. This device can operate continuously for a long time. Accordingly, it is quite probable to have wear of the end face of the mixer. Studies show that the end face wear increases the gap between the mixing chamber and the end face, resulting in material leakage, reducing the mixing effect and ultimately affecting the properties of the compound. Therefore, it is of significant importance to study the friction and wear of the mixing compound to the metal in the mixing process. Considering the superior characteristics of graphene (GE), it is considered a revolutionary material and has been widely applied in numerous applications. In the present study, the influence of the mixing compound with different amounts of GE on the friction and wear of the metal end face was analyzed and the ratio of the corrosion wear to abrasive wear was calculated for the first time. It was found that as the amount of GE increases, the proportion of abrasive wear on the metal increases, the proportion of corrosive wear on the metal decreases, and the metal wear decreases first and then increases. Moreover, the lowest metal wear can be achieved when the amount of GE is 3 phr. [ABSTRACT FROM AUTHOR]

As an essential rubber mixing equipment in continuous production, an internal mixer should have a long service life while operating at high intensity. Studies show that at these severe operating conditions, end face wear of the internal mixer is inevitable. It is worth noting that the end face is an important part of the closed mixing chamber. The head of the rotor shaft is inserted into the copper ring of the sealing plate, the sealing plate and the mixing chamber are pressed together by bolts. There is a gap between the rotors and the mixing chamber. During the mixing process, the mixed rubber in the mixing chamber is in direct contact with the end face, the end face metal is frictional and abraded. Wear of the end face may result in a gap between the mixing chamber and the end face, leading to material leakage. As the leakage intensifies, the gap between the end face and the mixing chamber further increases, thereby forming negative feedback. This phenomenon not only affects the chemical composition of the rubber but also reduces the mixing efficiency and decreases the performance of the rubber compound. The end surface material is cobalt chromium molybdenum tungsten alloy. The alloy model is Stellite 6B. In the present study, the influence of different amounts of CF on the friction and wear of the end face is analyzed from the chemical composition perspective. Moreover, the ratio of corrosion wear to abrasive wear is calculated. The obtained results show that as the amount of CF in the compound increases, the proportion of the corrosive wear of the compound to the metal increases, while the proportion of abrasive wear decreases. The highest proportion of corrosive wear and the lowest amount of metal wear can be achieved for the CF amount of 9 phr. As the CF content in the composition increases, the ratio of the corrosive wear of the rubber compound to metal decreases, while the proportion of abrasive wear and the total amount of wear to metal increases. • Studies show that at these severe operating conditions, end seal wear of the internal mixer is inevitable. • This study analyzed the effect of different additions of CF on the friction and wear of the end seal. • The highest proportion of corrosive wear and the lowest amount of metal wear can be achieved for the CF amount of 9 phr. [ABSTRACT FROM AUTHOR]