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3D printing is a rapidly growing technology that has an enormous potential to impact a wide range of industries such as engineering, art, education, medicine, and aerospace. The flexibility in design provided by this technique offers many opportunities for manufacturing sophisticated 3D devices. The most widely utilized method is an extrusion‐based solid‐freeform fabrication approach, which is an extremely attractive additive manufacturing technology in both academic and industrial research communities. This method is versatile, with the ability to print a range of dimensions, multimaterial, and multifunctional 3D structures. It is also a very affordable technique in prototyping. However, the lack of variety in printable polymers with advanced material properties becomes the main bottleneck in further development of this technology. Herein, a comprehensive review is provided, focusing on material design strategies to achieve or enhance the 3D printability of a range of polymers including thermoplastics, thermosets, hydrogels, and other polymers by extrusion techniques. Moreover, diverse advanced properties exhibited by such printed polymers, such as mechanical strength, conductance, self‐healing, as well as other integrated properties are highlighted. Lastly, the stimuli responsiveness of the 3D printed polymeric materials including shape morphing, degradability, and color changing is also discussed. [ABSTRACT FROM AUTHOR]

• A 3D printed electromembrane extraction device. • The device shows transport of anions, including fluorescein and inorganic anions. • Used for the extraction and concentration of anions in soil. A concentric electromembrane extraction preconcentration device was designed and fabricated using fused deposition modelling 3D printing. The device consisted of a hemispherical electrode sample vial printed from a filament of conductive polylactic acid (PLA), into which sat a smaller hemispherical 3D printed porous membrane acceptor vial. Application of voltage between a point-electrode placed in the center of 20 μL solution inside the acceptor vial and the electrode vial containing 1 mL of sample, enabled anion migration through the 3D printed porous material into the acceptor solution. Electromembrane extraction was proved using fluorescein for imaging of the extraction process, with preconcentration rates of 0.833 μM/sec at 120 V with close to 95% recovery. The performance of the fabricated porous 3D printed device was evaluated for the preconcentration of anions from water prior to capillary electrophoresis detection. Preconcentration factors ranging between 36–44 were obtained for chloride, nitrate, perchlorate and sulfate, while a lower performance was observed for weaker acids as fluoride and phosphate (3–4). The limit of detection (LOD) was determined to be 0.16 μM, 0.18 μM and 0.18 μM for NO 3 −, ClO 4 − and SO 4 2- respectively. The extraction and quantitation of ions from a soil slurry without filtration, namely NO 3 − and SO 4 2- content was determined to be 0.24 and 0.03 mmol/100 g of soil, respectively which are values in the range of those typically reported in soil samples. [ABSTRACT FROM AUTHOR]