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Start Over Author "Efthymiou CG" Topic 2,2'-dipyridyl

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1. Nickel/lanthanide single-molecule magnets: {Ni(3)Ln} "stars" with a ligand derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions.

Author

Efthymiou CG, Stamatatos TC, Papatriantafyllopoulou C, Tasiopoulos AJ, Wernsdorfer W, Perlepes SP, and Christou G

Subjects
2,2'-Dipyridyl chemistry, Ligands, Models, Molecular, Molecular Structure, Oxidation-Reduction, 2,2'-Dipyridyl analogs & derivatives, Lanthanoid Series Elements chemistry, Magnetics, Nickel chemistry, Temperature
Abstract

Unusual {Ni(II)(3)Ln(III)(μ-OR)(6)}(3+) complexes with a "star" topology have been prepared with ligands derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions; the Dy(III) member shows weak single-molecule-magnet behavior.

Published
2010
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