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Clay content and the ability to reversibly retain cations affect many essential chemical and physical properties of soil, such as pH buffering and carbon sequestration. Cation exchange capacity (CEC) and base saturation are also commonly used as criteria in soil classification. However, determination of CEC and particle-size distribution is laborious and not included in routine soil testing. In this study, pedotransfer functions including soil test cations (STCat; Ca2+ + Mg2+ + K+), pH and soil organic carbon (SOC, %) as explanatory variables were developed for estimating CEC, titratable acidity (TA; H+ + Al3+) and clay content (clay, %). In addition, reference values for potential CEC and its components were determined for Finnish mineral and organic soils. The mean of potential CEC extracted by 1 M ammonium acetate at pH 7.0 ranged from 14 (range 6.4−25) in coarse soils to 33 (21−45) cmol(+) kg-1 in heavy clay soils, and from 42 (24−82) in mull soils to 77 (25−138) cmol(+) kg-1 in peat soils. The average CEC of clay and SOC were 27 and 160 cmol(+) kg-1, respectively. Titratable acidity occupied 53% and around 40% of the CEC sites in organic and mineral soils, respectively, evidencing that it is a prominent component of the potential CEC in these predominantly acidic soils. STCat, pH and SOC explained 96% of the variation in potential CEC. STCat and pH can be used in estimating the clay content especially for soils containing over 30% clay. In coarse textured soils, in contrast, SOC hampers the STCat based estimation of clay content.

To achieve appropriate yield levels, inherent nitrogen (N) supply and biological N fixation are often complemented by fertilization. To avoid economic losses and negative environmental impacts due to over-application of N fertilizer, estimation of the inherent N supply is critical. We aimed to identify the roles of soil texture and organic matter in N mineralization and yield levels attained in cereal cultivation with or without N fertilization in boreal mineral soils. First, the net N mineralization and soil respiration were measured by laboratory incubation with soil samples varying in clay and organic carbon (C) contents. Secondly, to estimate the inherent soil N supply under field conditions, both unfertilized and fertilized cereal yields were measured in fields on clay soils (clay 30-78%) and coarse-textured soils (clay 0-28%). In clay soils (C 2.5-9.0%), both the net N mineralization and the cereal yields (without and with fertilization) decreased with increasing clay/C ratio. Moreover, in soils with high clay/C ratio, the agronomic N use efficiency (additional yield per kg of fertilizer N) varied considerably, indicating the presence of growth limitations other than N. In coarse-textured soils, the yield increase attained by fertilization increased with increasing organic C. Our results indicate that for clay soils in a cool and humid climate, the higher the clay content, the more organic C is needed to produce reasonable yields and to ensure efficient use of added nutrients without high N losses to the environment. For coarse soils having a rather high mean organic C of 2.3%, the organic C appeared to improve agronomic N use efficiency. For farmers, simple indicators such as the clay/C ratio or the use of non-N-fertilized control plots may be useful for site-specific adjustment of the rates of N fertilization. Highlights We aimed to identify simple indicators of inherent soil N supply applicable at the farm level. In clay soils, the net N mineralization was found to correlate negatively with the clay/C ratio. In coarse-textured soils, agronomic N use efficiency improved with increasing soil organic C. Clay soils with high clay/C ratio are at risk of low yield levels.

There is a great need for sustainable fertilisers and soil amendments, as current fertilisation practices negativelyaffect the environment. Pulp mill sludges (PMS) could provide a means to replace fertilisers made using non-renewable resources while adding slowly decomposing organic material to the soil and utilising nutrients from the forest industry. This study tested the effects of composted and lime-stabilised mixed PMS (CPMS and LPMS) on wheat (Triticum aestivum) yields and residual effect on oat (Avena sativa) yields in the boreal region. A two-year field experiment included two CPMS and two LPMS treatments all with additional mineral fertilisation, a mineral fertiliser treatment, and a zero-control treatment. All the fertilisers increased yields. There were no differences in crop yields between CPMS, LPMS and mineral fertiliser treatments. However, some quality characteristics and nitrogen (N) uptake were lower with all or some PMS compared with mineral fertilisation. This result suggests that part of the mineral fertilisation for cereals could be replaced by using PMS, but more information on N mineralisation from sludges is needed.

Production of organic fertilizers from poultry manure may compromise availability of phosphorus (P) to plants. This study examined the effects of granulation, feather meal addition, and pyrolysis on bioavailability of P in broiler manure in a pot experiment with ryegrass and assessed whether P availability is enhanced by inoculating arbuscular mycorrhizal fungi (AMF) into soil. Granulated broiler manure gave similar plant yield and P uptake to superphosphate. Feather meal addition had a minor negative effect on P availability, whereas pyrolysis lowered the fertilization effect of broiler manure. The yield-based mineral-P equivalences were 120%, 85% and 75% during the first harvest, and 100%, 75% and 45% during one growing season for granulated unamended, granulated amended with feather meal and pyrolyzed broiler manure. Soil inoculation with AMF did not enhance P availability. Granulated poultry manure is suitable as a P fertilizer for annual crops with comparable bioavailability to mineral fertilizer P, whereas pyrolyzed poultry manure is suitable as a slow-release or storage P fertilizer in slightly acidic soils. Knowledge on P bioavailability in organic fertilizers produced with different technologies can be used for optimizing fertilization, minimizing build-up of soil P and its adverse environmental effects. (C) 2021 The Author(s). Published by Elsevier B.V.

Erosion and colloidal particle loss from cultivated clay soils in cool humid climate pose a risk to soil productivity and surface water quality. To enhance soil management practices that effectively reduce clay soil erosion, we need to understand the interrelations between the key variables on which clay soil aggregate structure depend. The objective of our study was to quantify the relative importance of OC content, land use and soil wetness, for the aggregate stability of post-glacial clay soils. We estimated the potential effect of five different land uses (cereal cropping with variable tillage and crop rotation, permanent grassland and forest as a control) on clay soil aggregate stability as measured by the percentage of water-stable aggregates (WSA% of 2–5 mm fraction) and colloid detachment (turbidity, NTU%), after controlling for the differences in organic carbon content (OC%) and Clay%/OC% ratio between the land uses through covariance analysis. Further, we assessed how aggregate structure in differently managed soils with different OC% tolerates the varying moisture conditions. The higher OC% was reflected in all cultivated soils by increased aggregate stability, implying that OC inputs may positively affect soil structure even in low additions. When compared at equal OC%, the mean WSA% was lower in cereal cropping than in soils under forest or permanent grass, clearly showing the negative effect of tillage frequency on the aggregate stability. The detachment of colloidal particles from aggregates was higher in soils with a high Clay%/OC% ratio, and thus the Clay%/OC% ratio may offer an easily measurable indicator for the risk of clay dispersion, and thereby soil erosion and the export of particle-bound nutrients from cultivated fields. When compared at an equal Clay%/OC% ratio, colloid detachment from aggregates representing cereal fields was two- to threefold as compared to permanent grassland. Cultivated soils with less than 4–6% OC were very sensitive to waterlogging, highlighting the role of proper drainage in erosion control. The results demonstrate that an increase in OC content and proper drainage would help to improve the aggregate stability of cultivated clay soils in cool humid climate, but the effective improvement of the present situation would require drastically reduced soil disturbances for areas with the highest erosion risk.

Dissolved organic carbon (DOC) load in discharges from cultivated soils may have negative impacts on surface waters. The magnitude of the load may vary according to soil properties or agricultural management practices. This study quantifies the DOC load of cultivated mineral soils and investigates whether the load is affected by agricultural practices. Discharge volumes and concentrations of DOC and dissolved organic nitrogen (DON) were continually measured at three sites from surface runoff and artificial subsurface drainage or from combined total discharge over a two-year period (2012-2014). Two experimental sites in South-West Finland had clayey soils (with soil carbon contents of 2.7-5.9% in the topmost soil layer), and the third site in West-Central Finland had sandy soil (soil carbon contents of 4.3-6.2%). Permanent grassland, organic manure application, mineral fertilization, and conventional ploughing or no-till activities were studied. Furthermore, the biodegradable DOC pool of surface runoff and subsurface drainage water from no-till and ploughed fields was estimated in a 2-month incubation experiment with natural bacterial communities collected from the Baltic Sea seawater. The annual DOC and DON loads were affected by discharge volume and seasonal weather conditions. The loads varied between 25-52 kg ha(-1) and 0.8-3.2 kg ha(-1), respectively, and were comparable to those from boreal forests with similar soil types. The DOC load increased with increasing topsoil carbon content at all sites. There were slightly higher DOC concentrations and DOC load from permanent grassland, but otherwise we could not distinguish any clear management-induced differences in the total DOC loads. While only 6-17% of the DOC in discharge water was biologically degraded during the 2-month incubation, the proportion of biodegradable (labile) DOC in surface runoff appeared to increase when soil was ploughed compared to no-till. (c) 2017 Elsevier B.V. All rights reserved.

Soil structure is one of the key properties affecting the productivity of soils and the environmental side effects of agricultural soils. Poor surface soil structure increases the risk of soil erosion by water and eroded clay-sized particles can carry adsorbed phosphorus (P) to the surface waters, thus inducing eutrophication of receiving waterways. Management practices, e.g. reduced tillage, used to reduce erosion can lead to enrichment of P in the uppermost soil layers, which leads to elevated risk for dissolved P loss in the runoff water. In this study, we aimed to identify whether biochar (BC) could be used to reduce clay soil erosion by improving aggregate stability. Moreover, we tested whether the BC addition would change the P sorption affinity of the soil and help to reduce the loss of dissolved P. One sandy and two clayey soils were amended with BC (0, 15 and 30 t ha − 1 ) and after a 3-week incubation, a wet-sieving method was used to measure the release of colloidal particles and the stability of aggregates. The sorption of P onto soil surfaces was estimated with a Q/I (quantity/intensity) plot technique. The BC used here had a very low P sorption affinity and the BC addition did not increase the sorption of P in incubated soils. However, for the two clayey soils, the BC additions increased aggregate stability and reduced detachment of colloidal material. The BC thus induced changes in soil properties that could be beneficial for erosion control and thereby aid in reducing particulate P losses from agricultural fields.