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Undesired advection effects are unavoidable in most nano-technological applications involving active matter. However, it is conceivable to govern the transport of active particles at the small scales by suitably tuning the relevant advection and self-propulsion parameters. To this purpose, we numerically investigated the Brownian motion of active Janus particles in a linear array of planar counter-rotating convection rolls at high Péclet numbers. Similarly to passive particles, active microswimmers exhibit advection enhanced diffusion, but only for self-propulsion speeds up to a critical value. The diffusion of faster Janus particles is governed by advection along the array's edges, whereby distinct diffusion regimes are observed and characterized. Contrary to passive particles, the relevant spatial distributions of active Janus particles are inhomogeneous. These peculiar properties of active matter are related to the combined action of noise and self-propulsion in a confined geometry and hold regardless of the actual flow boundary conditions.

A high conduction band degeneracy (Nv = 6) leads to an extraordinary figure of merit (zT) in n-type Mg3Sb2 thermoelectrics, while the p-type ones show a much inferior zT due to its lower Nv of only 1 owing to the large energy offset (ΔE ∼ 0.4 eV) between the two valence bands. The derivatives of Mg3Sb2, ternary AB2C2 (A = Eu, Yb, Ca, Sr, Ba; B = Mg, Zn, Cd; C = Sb, Bi) Zintls, show a similar valence band structure but with a much smaller ΔE of

In mining areas, nano-sized elemental selenium (SeNPs), naturally produced through reduction of SeO32− by abiotic and biotic processes, usually co-exists with Hg in the environment. Little is known about the fate of SeNPs and how they affect the bioavailability and toxicity of Hg towards plants. In this study, the fate of SeNPs and Hg, and the effect of SeNPs on the mobilization of Hg in a hydroponic-cultured plant were investigated. It was found that SeNPs were less phytotoxic and had stronger capacity for Hg sequestration than SeO32−and SeO42−. Synchrotron radiation X-ray fluorescence (SR-XRF) and X-ray absorption near edge structure (XANES) spectroscopy revealed that SeNPs largely captured Hg2+via forming HgSe and HgSeNPs to prevent Hg2+ from entering the root stele, thus inhibiting translocation and accumulation of Hg in the aerial parts. Apart from immobilizing Hg, SeNPs also promoted the conversion of Hg2+ to less toxic RS–Hg–SR and R–Hg–R binding forms in plants. Meanwhile, a portion of SeNPs was transformed into SeMet stored as the nutrient Se source in plant tissues. This study provides insights into the reaction and fate of SeNPs and Hg in water-plant systems, which implies the significance of SeNPs in modulating the fate and toxicity of Hg in mining areas.

Parametric Budyko method has been widely used to assess water availability under changing environment. Its single parameter (w) controlling the shape of the Budyko curve, is of critical importance to water availability assessment (WAA). Here, the water availability is defined as the ratio of evapotranspiration to precipitation in the context of Budyko hypothesis. As an unobserved variable, w is generally estimated through incorporating the long-term water-balance model and Budyko hypothesis, i.e. estimating w as a function of precipitation, runoff, and potential evapotranspiration over a long-term time series of these variables. Inevitably, the estimated value of w is subject to uncertainty resulting from hydro-meteorological records with limited size. Further, this uncertainty affects WAA in context of Budyko hypothesis. The uncertainty and its propagation issue is often overlooked in past research. In this paper, we develop a bootstrap-based algorithm to reveal aforementioned uncertainty. Moreover, a partial derivative-based sensitivity analysis is performed for understanding the propagation of w uncertainty on WAA. Three catchments located in the Yellow River Basin, China, are used as case study sites. Results indicate that there exists remarkable uncertainty in parameter w, which varies with the data length. The impact of such uncertainty on WAA increases quickly under the humid condition, thereafter reaches a peak under the mild condition, and decreases slowly under the arid condition. The reason behind this phenomenon is the largest sensitivity of WAA to parameter w under the mild climate condition. Moreover, a general analytical expression for determining the critical value of climate condition which maximizes the impact of parameter w uncertainty on WAA is derived in this paper. Results of this study can enhance the reliability and robustness of Budyko-based models.

Gasochromic based optical hydrogen sensors have attracted much attention as normal temperature sensors. The behaviors of the hydrogen diffusion largely affect the reaction process and the sensitivity. However, few researches focused on the influence of hydrogen diffusion in gasochromic films. Here, we report a method to pre-split the H2 molecule and separate the hydrogen molecule and hydrogen atom diffusion process by deposition of porous PdCl2/SiO2 catalyst films on WO3. The response time of WO3 at 844 Pa H2 partial pressure reduced from 800 s to 200 s. The stability of WO3 film was largely improved to be more than 160 cycling lifetime. A validation experiment was designed and proved the diffusion of the hydrogen atom and the two-step model of H2 reaction on WO3 films, on the basis of which the diffusion coefficient of the hydrogen atom has been estimated. Moreover, the PdCl2 doping SiO2 catalyst exhibits substrate versatility, which can also coat on the nano-structured WO3.

The influence of lime amendment on the absorption and accumulation of lead (Pb) in the grains of three rice cultivars ((Dong Lian 5 (DL-5, Indica), TeYou 009 (TY-009, Hybrid Indica), and YiYou 673 (YY-673, Hybrid Indica)) was investigated and the associated mechanisms were explored. Pot experiment was conducted in heavily Pb-polluted paddy soil. The transformation of Pb species in soil and roots under different levels of lime application was studied by Pb L3-edge X-ray absorption spectroscopy (Pb L3-XAS) and BCR sequential extraction. The results showed that lime amendment significantly increased soil pH and decreased DTPA-extractable Pb in soil. When the additional ratio of Liming was lower than 32 g kg–1, the Pb accumulation in rice plants, particularly in the grains was remarkably reduced. Moreover the biomass of rice was not significantly affected. Among the three cultivars, the lowest Pb content in rice grains occurred in YY-673. The cultivation of rice cultivar with low Pb accumulation will reduce the Pb content in the grains. Liming significantly inhibited the translocation of Pb from the roots to the aboveground parts, and from the stems and leaves to grains. Pb L3-XAS and BCR s sequential extraction method analysis revealed that lime amendment increased Pb2+ association with Fe oxides (Pb-Ferr), the precipitation of 2PbCO3·Pb(OH)2, the residual fraction of paddy soil, and also promoted the transformation of Pb(NO3)2 and Pb-pectin to 2PbCO3·Pb(OH)2 and Pb-Ferr in rice roots. The suitable lime addition (> 4 g kg–1, under this pot experiment) could effectively reduce Pb accumulation in rice grains.

This study aimed to investigate the effects of rice straw biochar and lime (RBL) on the remediation of lead (Pb)-contaminated soil and mitigation of Pb translocation in rice plants by using pot experiments. Lead-contaminated soil collected from a farmland near a Pb-zinc (Zn) mine, biochar, limestone powder, and indica rice (Oryza sativa L.) were used in the present study. The experimental treatments included: (1) control (CK), (2) 2.5% biochar (RB1), (3) 5% biochar (RB2), (4) 0.6% lime (L1), (5) 1.2% lime (L2), (6) 2.5% biochar + 0.6% lime (RBL1), and (7) 2.5% biochar + 1.2% lime (RBL2). The results revealed that the treatment with RBL was more efficient than the treatment with only biochar or lime in decreasing CaCl2-extractable Pb content in the soil by increasing soil pH and soluble sulfate content in the soil. Treatment with RBL reduced in the accumulation of Pb in the shoot of rice plants, this was mainly attributed to the decrease in the concentration of available Pb in the soil. The RBL2 treatment not only decreased the concentration of Pb in brown rice by 84.33% and Pb distribution in rice embryo, but also increased rice yield by 53.38% from that of the control. Further, unlike biochar treatment, RBL and lime treatments decreased the translocation of Pb in rice plants. The RBL treatment increased the proportion of Pb distributed in the cell wall and reduced the mobility of Pb in plant tissues. Thus, application of biochar and lime in combination is more effective than their individual application in reducing the availability of Pb in the soil and Pb accumulation in brown rice.

We numerically investigated the phenomenon of non-Gaussian normal diffusion of a Brownian colloidal particle in a periodic array of planar counter-rotating convection rolls. At high Peclet numbers, normal diffusion is observed to occur at all times with non-Gaussian transient statistics. This effect vanishes with increasing the observation time. The displacement distributions decay either slower or faster than a Gaussian function, depending on the flow parameters. The sign of their excess kurtosis is related to the difference between two dynamical time scales, namely, the mean exit time of the particle out of a convection roll and its circulation period inside it.

We numerically investigated the diffusion of an active Janus particle in periodic arrays of planar counter-rotating convection rolls at high Peclet numbers. We considered convection patterns with distinct longitudinal and transverse advection properties and characterized the dependence of the relevant diffusion constants on the particle's dynamical parameters, namely, self-propulsion speed, correlation time and chirality. Numerical results are interpreted analytically based on qualitative arguments of classical transport theory. The purpose of the present analysis is controlling active matter transport in microfluidic devices.

Tourist food consumption is an important driver of food waste generation within the hotel/restaurant/cafe (HORECA) sector of popular destinations. Little is however known about the exact magnitude of food wastage by tourists alongside the determinants of their wasteful behaviour. This study has striven to contribute to knowledge with an exploratory survey in Lhasa, a popular destination in China, which set to establish the size of food wastage by tourists and explain the role of various socio-demographic and food consumption-related factors in its occurrence by statistical analysis and multiple linear regression analysis, respectively. The study found that tourists generated circa 15% of the total food waste in the HORECA sector, while the taste preferences and portion size were two major causes. The level of tourist education and personal satisfaction with meals exerted a significant negative impact on food waste generation. To reduce food wastage, policy-makers and HORECA professionals should educate tourists about the detrimental effect of wasted food and increase their satisfaction with meals. The research findings provided insights into achieving sustainability objectives in national and international tourism sectors.

It is often desirable to enhance the motility of active nano- or microscale swimmers such as, e.g., self-propelled Janus particles as agents of chemical reactions or weak sperm cells for better chances of successful fertilization. Here we tackle this problem based on the idea that motility can be transferred from a more active guest species to a less active host species. We performed numerical simulations of motility transfer in two typical cases, namely for interacting particles with weak inertia effect, by analyzing their velocity distributions, and for interacting overdamped particles, by studying their effusion rate. In both cases we detected motility transfer with a motility enhancement of the host species of up to a factor of four. This technique of motility enhancement can find applications in chemistry, biology and medicine., Comment: 10 pages

Steel slag is alkaline in aqueous solution, and this is a typical feature for solid wastes that contain large amounts of basic oxides. Therefore, this parameter is used for solid waste hazard assessments. Special attention needs to be paid to the chemical parameters of steel slag to improve its comprehensive utilization, disposal, and storage. The corrosiveness of converter slag samples from different steel plants was evaluated according to the method stipulated by the Chinese national standard GB5085.1–007 to identify whether they would be classified as alkaline hazardous waste. The results showed that steel slag leaching solution had a certain corrosivity, and the pH value of the leaching solution increased with a decrease in the particle size of the steel slag and a decrease in temperature. However, the pH value of the short-term and long-term deposited slag leaching solution was not more than the standard limit value, and hence was not a hazardous waste. It was also found that the pH value (12...

Climate change and its uncertainty may cause hydrological cycle and hydropower plant inflow to be changed, which destroy the consistency of hydrological data time series and change the constraint relationships among operation objects of the hydropower plants. So the conventional operation rules cannot be applied to the current hydrological data time series. Therefore, the main goals of this study are to develop adaptive operation chart for the hydropower plant to mitigate climate change impacts, and to propose an optimal adaptive operation chart for cascade hydropower system to increase power generation under the climate change environment. A methodology that combines simulation and optimization models is presented to formulate the optimal adaptive operation rules that consider the joint operation of cascade reservoirs. And the performance of the optimal adaptive operation rules is verified by comparing it with the conventional rules when both been applied to a case study of Hanjiang River hydropower plant reservoirs system. With the optimal adaptive operation chart, the cascade power generation assurance rate increased to 87%, the average annual power generation increased by 16.1%, and the power generation in typical wet, normal and dry years increased by 4.4%, 9% and 7.3%, respectively, compared with the conventional operation chart.

The influence of three Ca-containing amendments (dolomite, slaked lime, and limestone) on soil water soluble Pb (Pb-w) levels, Pb accumulation by two rice plants (TJ-8, japonica and II-3301, indica), and the factors affecting Pb-w were investigated. Pot experiment was performed under waterlogged conditions using Pb-contaminated soil collected from an agricultural field near a mine. It was found that the soil amendments significantly reduced Pb content in the rice plants in the order dolomite > slaked lime > limestone, irrespective of rice cultivar. The Pb content of brown rice with the added soil amendments was lower than that of the recommended limit (0.2 mg kg−1, GB2762-2017) except for cultivar II-3301 with slaked lime. There was a significant positive correlation between the Pb content of the roots, stems, leaves, and grains and the soil Pb-w levels. The amendments reduced soil Eh, Fe, and Mn concentrations in the pore water and increased soil pH. The total organic carbon (TOC) in the pore water significantly decreased for II-3301 but not for TJ-8 at the ripening stage after addition of the amendments. Among soil Eh, pH, TOC, Fe, and Mn in the pore water, Fe and Mn were the most influential in lowering soil Pb-w levels. The amendments inhibited the formation of iron plaques on the root surface and reduced Pb adsorption. The Pb content of the roots was positively correlated with that in iron plaque. These findings are significant as they imply that the application of Ca-containing amendments in Pb-contaminated paddy soils near mines is an effective approach for in situ immobilization of Pb and reduction in Pb levels in the edible parts of crops.

Consumer food waste in developing countries becomes increasingly important as they continue to urbanize and raise the income of their inhabitants. However, there are few empirical studies on the scales, patterns, and impacts of consumer food waste in emerging economies (compared to industrialized countries). Here we report an exploratory study on the amount of Horeca (hotels, restaurants, and cafes) food waste and its ecological footprint in Lhasa, Tibet, in western China, based on a direct-weighing bottom-up approach of 35 representative restaurants in 2011 and 2015. We found that, on a per capita level, Horeca food waste in Lhasa has already reached a high-level (128 ± 3 g/cap/meal in 2011 and 98 ± 2 g/cap/meal in 2015) close to that of western countries despite a lower level of income. The decline of per-capita Horeca food waste generation from 2011 to 2015 most likely reflects the reduction among local residents as a result of recently issued strict regulations (especially those targeting official extravagance and governmental reception meals at public expenses), as similarly observed in Japan and Germany. On the contrary, as a main tourism destination, tourists showed an increasing trend of food waste on a per capita level and contributed over half to the total Horeca food waste in both 2011 and 2015. This also leads to, together with other factors such as growing dining-out frequency of local residents, a sharp increase (39.7%) of total Horeca food waste in Lhasa from 2011 (15 ± 1 kt) to 2015 (21 ± 2 kt). The total ecological footprint of wasted food in the Horeca sector of Lhasa in 2015 is equivalent to 71,516 ± 7,705 ha, almost two times the arable land area of Lhasa.

Rice grains are a methylmercury (MeHg) intake route for humans, especially in certain mercury (Hg)-contaminated areas. For rice plant growth, animal manure is commonly used as an organic fertilizer; however, its role in the formation of MeHg in paddy soils remains poorly understood. The aims of this study were thus to explore 1) the effect of chicken manure (CH) and cow manure (CO) addition on the production of soil MeHg and the accumulation of MeHg in rice plants and 2) the mechanism by which CH and CO addition affect the bioaccumulation of MeHg in grains. A pot experiment with different levels of CH and CO was carried out with newly deposited Hg-contaminated paddy soil. Two microcosm experiments were performed to explore the associated mechanisms. The results of the pot experiment showed that 0.1–1% CH and CO addition promoted the biomass of rice plants by 10–23% and increased the soil MeHg concentration by 34–143%, which exhibited a significant positive correlation with brown rice MeHg content. Organic fertilizer addition significantly increased MeHg bioaccumulation in rice plants and the ratio of MeHg to total Hg (THg) in brown rice. Organic fertilizer also increased the abundance of microbial methylators. The results of the microcosm experiments showed that organic fertilizer addition enhanced dissolved THg concentrations in soil and consequently increased the soil MeHg concentration. These results suggested that applying organic fertilizer to newly deposited Hg-contaminated soil may increase MeHg accumulation in grains due to enhanced Hg release and microbial methylator activity, leading to environmental health concerns.

Thiosulfate addition increases the solubility of mercury (Hg) in soil and Hg uptake by plants under oxic conditions. However, anoxic conditions could dominate the biogeochemical processes of Hg cycling during rice cultivation. The present study aimed to determine whether thiosulfate, a sulfur-containing fertilizer, could be used for Hg immobilization in paddy soil. A pot experiment was conducted using soil newly spiked with Hg and different doses of thiosulfate. Total Hg concentrations in rice tissues, Hg speciation in roots, and geochemical fraction of Hg in soils were investigated. Hydroponic cultivation was conducted to determine the subcellular distribution of Hg in root tissues. Thiosulfate application significantly reduced Hg concentration in rice plants. It increased the percentage of organic-bound Hg, but decreased the percentage of iron/manganese oxide-bound Hg. Thiosulfate enhanced iron plaque formation and Hg adsorption on the iron plaque. Its application increased the percentage of Hg forms similar to HgS and decreased those similar to Hg-glutathione [Hg(GS)2]. Thiosulfate amendments had a remarkable inhibitory effect on Hg accumulation in rice plants in newly Hg-spiked soil. This occurred because thiosulfate reduced Hg mobility in the rhizosphere and root tissues, promoted the formation of iron plaque, and facilitated more Hg adsorption by the iron plaque. Our findings suggest that appropriate thiosulfate treatment could be used as Hg-immobilizing agents in paddy soil.

It is critically important to quantify the impact of land use land cover (LULC) changes on hydrology, and to understand the mechanism by which LULC changes affect the hydrological process in a river basin. To accurately simulate the hydrological process for a watershed like the Wei River Basin, where the surface characteristics are highly modified by human activities, we present an alternative approach of time-varying parameters in a hydrological model to reflect the changes in underlying land surfaces. The spatiotemporal impacts of LULC changes on watershed streamflow are quantified, and the mechanism that connects the changes in runoff generation and streamflow with LULC is explored. Results indicate the following: (1) time-varying parameters’ calibration is effective to ensure model validity when dealing with significant changes in underlying land surfaces; (2) LULC changes have significant impacts on the watershed streamflow, especially on the streamflow during the dry season; (3) the expansion of cropland is the major contributor to the reduction of surface water, causing decline in annual and dry seasonal streamflow. However, the shrinkage of woodland is the main driving force that decreases the soil water, thus contributing to a small increase in streamflow during the dry season.

Screening for tolerant and high biomass producing plants is important for phytoextraction efforts in remediating agricultural soils contaminated by heavy metals. We carried out a greenhouse experiment involving a soil cadmium (Cd) concentration gradient (0.1, 0.5, 1, 2, 4, and 8 mg kg−1) to assess growth and phytoextraction capacity of king grass (Pennisetum sinese Roxb.) in soils contaminated by Cd and to explore changes in diversity and structure of rhizosphere soil bacterial communities in response to long-term Cd pollution. A significant positive relationship was observed between Cd concentrations in P. sinese stems, leaves, and roots and soil Cd concentration. The highest Cd concentrations in shoots and roots were 28.87 and 34.01 mg kg−1, respectively, at 8 mg kg−1of soil Cd supply. Total extraction amounts of Cd in P. sinese were 0.22–1.86 mg plant−1 corresponding to treatment with 0.5–8 mg kg−1 Cd. Most of the Cd was stored in shoots, and the largest accumulation was 1.56 mg plant−1 with 54.02 g dry shoot weight. After phytoextraction, changes in rhizobacterial community composition were found with different levels of Cd application, whereas there were no clear trends in diversity and richness. Results of this study show the feasibility of P. sinese in accumulating Cd and provide support for its application in remediation of soil moderately contaminated by Cd.

Metal halide perovskite nanostructures have recently been the focus of intense research due to their exceptional optoelectronic properties and potential applications in integrated photonics devices. Charge transport in perovskite nanostructure is a crucial process that defines efficiency of optoelectronic devices but still requires a deep understanding. Herein, we report the study of the charge transport, particularly the drift of minority carrier in both all-inorganic CsPbBr3 and organic–inorganic hybrid CH3NH3PbBr3 perovskite nanoplates by electric field modulated photoluminescence (PL) imaging. Bias voltage dependent elongated PL emission patterns were observed due to the carrier drift at external electric fields. By fitting the drift length as a function of electric field, we obtained the carrier mobility of about 28 cm2 V–1 S–1 in the CsPbBr3 perovskite nanoplate. The result is consistent with the spatially resolved PL dynamics measurement, confirming the feasibility of the method. Furthermore, the e...

Hydropower plays a major role in the Chinese electricity generation industry. It is of significant importance to perform efficiency evaluation of the economic operation in a power station, which can help promote better water resources management and create more benefits for power network. Therefore, the main goal of this study is to establish a set of evaluation indexes and investigate the evaluation method to assess the economic operation in a power station. Based on the operation chart, three evaluation indexes including the Relative Water Consumption Rate (RC), the Relative Hydropower Utilization Rate (RU), and the Relative Hydropower Utilization Increasing Rate (RI) were proposed. The Longyangxia power station, as the biggest peak regulation source in the Northwest Power Network in China and the largest reservoir in the Yellow River Basin, was selected to perform an efficiency evaluation of economic operation. The result showed that the economic operation of this power station was not reasonable with RC > 1, RU

Sulfur (S) is an essential element for plant growth and its biogeochemical cycling is strongly linked to the species of heavy metals in soil. In this work, the effects of S (sulfate and elemental sulfur) treatment on the accumulation, distribution and chemical forms of Hg in rice growing in Hg contaminated soil were investigated. It was found that S could promote the formation of iron plaque on the root surface and decrease total mercury (T-Hg) and methylmercury (MeHg) accumulation in rice grains, straw, and roots. Hg in the root was dominated in the form of RS-Hg-SR. Sulfate treatment increased the percentage of RS-Hg-SR to T-Hg in the rice root and changed the Hg species in soil. The dominant Hg species (70%) in soil was organic substance bound fractions. Sulfur treatment decreased Hg motility in the rhizosphere soils by promoting the conversion of RS-Hg-SR to HgS. This study is significant since it suggests that low dose sulfur treatment in Hg-containing water irrigated soil can decrease both T-Hg and MeHg accumulation in rice via inactivating Hg in the soil and promoting the formation of iron plaque in rice root, which may reduce health risk for people consuming those crops.

The high variability of solar energy makes utility-scale photovoltaic power generation confront huge challenges to penetrate into power system. In this paper, the complementary hydro-photovoltaic operation is explored, aiming at improving the power quality of photovoltaic and promoting the integration of photovoltaic into the system. First, solar-rich and hydro-rich regions across the world are revealed, which are suitable for implementing the complementary hydro-photovoltaic operation. Then, three practical scenarios of the novel operation mode are proposed for better satisfying different types of load demand. Moreover, a method for optimal sizing of a photovoltaic plant integrated into a hydropower plant is developed by maximizing the net revenue during lifetime. Longyangxia complementary hydro-photovoltaic project, the current world’s largest hydro-photovoltaic power plant, is selected as a case study and its optimal photovoltaic capacities of different scenarios are calculated. Results indicate that hydropower installed capacity and annual solar curtailment rate play crucial roles in the size optimization of a photovoltaic plant and complementary hydro-photovoltaic operation exerts little adverse effect upon the water resources allocation of Longyangxia reservoir. The novel operation mode not only improves the penetration of utility-scale photovoltaic power generation but also can provide a valuable reference for the large-scale utilization of other kinds of renewable energy worldwide.

We study the 3D dynamics of an elastic dimer consisting of an active swimmer bound to a passive cargo, both suspended in a Couette flow. Using numerical simulations, we determine the diffusivity of such an active dimer in the presence of long-range hydrodynamic interactions for different values of its self-propulsion speed and the Couette flow. We observe that the effect of hydrodynamic interactions is greatly enhanced under the condition that self-propulsion is strong enough to contrast the shear flow. The magnitude of the effect grows with the size of the dimer's constituents relative to their distance, which makes it appreciable under experimental conditions.

In this study, metallurgical-slag-based binder (MSB) with different dosages of calcium hydroxide (CH) was mixed with high-arsenic-containing mine tailings (HAMT) to form green mining fill samples (GMFs) for As solidification/stabilisation (S/S). The As leaching characteristics of the GMFs were evaluated using pH-dependent leaching tests, semi-dynamic leaching tests and toxicity leaching tests. The effective diffusion coefficient (De) decreased from 6.98 × 10−14 to 5.90 × 10−15 cm2/s and the leachability index (LI) increased from 13.53 to 14.73 after 3 wt.% CH was added to the GMFs. The GMFs containing 0 wt.% CH (GMF-0C) and those containing 3 wt.% CH (GMF-3C) reached pH = 2 with acid addition amounts of 9.0 meq/g-dry and 9.3 meq/g-dry at 90 d curing time, and the maximum As leaching concentrations of GMF-0C and GMF-3C reached 10.47 mg/L and 7.47 mg/L, respectively, indicating that GMF-3C exhibited better acid neutralisation and As retention capacities than GMF-0C. Further, a Tescan Integrated Mineral Analyser (TIMA) was used to analyse the dominant hydration products of GMF-3C, which revealed that calcium silicate hydrate, CASH, ettringite and zeolite phases represented approximately 22.5 wt.% of the products. These results provide an understanding regarding the safe large-scale utilisation of GMFs.

Immobilization is widely used to decrease the availability of heavy metals, such as Cd and Pb, in contaminated soils. However, the spatial and temporal changes in the immobilization of soil by amendments combined with planting effects have not been studied well. In this study, unplanted and planted (with rice plants) pot experiments were used to assess the spatial and temporal changes in water-soluble Cd, Fe, Mn, and Ca. Soil properties, such as pH, redox potential (Eh), and dissolved organic carbon (DOC), were continuously recorded in both the rhizosphere and bulk soil using non-invasive rhizon samplers and a microelectrode system (Unisense). In unplanted soil, pH and Eh varied with time, but showed little radial variation from the rhizosphere to the bulk soil. The addition of hydrated lime (Ca(OH)2) sharply increased the pH, DOC, and Ca content; decreased the Eh, Fe content, and Mn content; and gradually decreased the water-soluble Cd content in the soil profile. Hydroxyapatite showed no obvious effects in reducing Cd concentrations in different soil zones. The water-soluble Fe, Mn, Ca, and DOC content did not differ significantly between soil zones over time and a non-significant correlation with water-soluble Cd was shown. In planted soil, the pH increased while the Eh value decreased with an increase in the distance from the roots, regardless of the soil amendments used during the rice growth period. Hydroxyapatite gradually increased but hydrated lime decreased the water-soluble Cd in the rhizosphere. The concentration of water-soluble Cd in the rhizosphere was higher than that of the other soil zones during rice growth. These changes lead to more Cd uptake by roots and induced Cd accumulation in rice tissues. In addition, Cd and Fe concentration in iron plaque showed a significant positive correlation with Cd in rice, indicating that iron plaque promotes the uptake and accumulation of Cd in rice with soil amendments. Compared with the control, hydroxyapatite did not significantly affect the Cd content, while Ca(OH)2 significantly reduced the Cd content in iron plaque and rice tissues. In conclusion, the application of hydrated lime can significantly reduce the risk of Cd accumulation by rice in Cd-contaminated soils under flooding conditions.

The leaching characteristics of metallurgical slag-based binders (MSB) solidified/stabilized tailings containing arsenic (As) and antimony (Sb), were investigated via a series of semi-dynamic leaching tests using three kinds of leachant, for the simulation of actual leaching conditions. The effectiveness of solidification/stabilization (S/S) treatment was evaluated by measuring the observed diffusion coefficients (Dobs). It was found that MSB efficiently prevented As and Sb leaching, providing Dobs values in the range of 10−15 to 10−13 cm2/s and 10−11 to 10−9 cm2/s, respectively, with the exception that the leaching mechanism of As was dissolution rather than diffusion under acetic acid leaching conditions. Physical encapsulation was found to be the dominant mechanism for Sb immobilization, while the dominant mechanism of As immobilization was precipitation in the monolithic MSB S/S treated tailings (MST). Results showed that the concentrations of leached As, Sb, Ca and Si, were affected by leachant pH and total acidity as well as the MSB constituent ratio. The effect of these parameters may be attributed to the stability of hydration products and their influence on the buffering capacity and structure of matrices, and the leachant pH and total acidity having the greatest influence on leaching characteristics.

Methylmercury (MeHg) in rice grains grown in Hg-contaminated areas has raised environmental health concerns. Pot experiments found that selenium (Se) could reduce MeHg levels in rice grains. However, relatively high levels of Se (up to 6 mg/kg) were applied in these pot experiments, which may have adverse effects on the soil ecology due to the toxicity of Se. The aims of this work were thus to study 1) the effect of low levels of Se on the accumulation and distribution of Hg, especially MeHg, in rice plants grown in a real Hg-contaminated paddy field and 2) the effect of Se treatment on Se and other nutritional elements (e.g., Cu, Fe, Zn) in grains. A field study amended with different levels of Se was carried out in Hg-contaminated paddy soil in Qingzhen, Guizhou, China. The levels of MeHg and total Hg were studied using cold vapor atomic fluorescence spectrometry (CVAFS) and inductively coupled plasma mass spectrometry (ICP-MS). The distribution and relative quantification of elements in grains were examined by synchrotron radiation X-ray fluorescence analysis (SR-XRF). This field study showed that low levels of Se (0.5 μg/mL, corresponding to 0.15 mg Se/kg soils) could significantly reduce total Hg and MeHg in rice tissues. Se treatment also reduced Hg distribution in the embryo and endosperm and increased the levels of Fe, Cu, Zn and Se in grains and especially embryos. This field study implied that treatment with an appropriate level of Se is an effective approach to not only decrease the level of MeHg but to also increase the levels of nutritional elements such as Fe, Cu, Zn and Se in rice grains, which could bring beneficial effects for rice-dependent residents living in Hg-contaminated areas.

The influence of elemental sulfur (S(0)) amendment on methylmercury (MeHg) accumulation in rice and the chemical form of Hg in the rhizosphere were investigated under waterlogged conditions in Hg-contaminated soil (the majority of the Hg (˜70%) in forms similar to HgS). Different levels of S(0) addition increased the MeHg accumulation in rice. After a sequential extraction analysis of the chemical forms of Hg in the rhizosphere, the results showed that S(0) addition increased the organic bound Hg and decreased the residual Hg in the soils. An Hg LIII XANES further showed that S(0) addition increased the proportion of Hg in the form of RS-Hg-SR and decreased the proportion of Hg in the form of HgS, indicating that S(0) input may reactivate the non-bioavailable Hg in the rhizosphere and improve the net Hg methylation. These findings suggest that the application of S fertilizers to Hg-contaminated paddy soils may increase the MeHg concentration in the edible parts of crops, which may lead to more potential health problems in humans depending on the crop type. However, our study also suggests that S(0) addition could be an effective measure for mobilizing the insoluble Hg and accelerating the phytoremediation process in Hg-contaminated paddy soils.

Household has been widely considered as the top contributor to food waste generation in industrialized countries. However, the characteristics and driving factors of household food waste generation in developing countries, particularly in rural areas, remain less understood. In the present work, we reported a case study for rural households in China, where food consumption structure has been undergoing rapid transformation, to explore the scales and drivers of rural household food waste generation. A direct-weighing method was used in a field survey for 207 rural households in 21 villages of 3 prefecture-level cities in Shandong province, northern China. We determined the average rural household food waste generation as 8.74 g/cap/meal (more than 90% was plant-based food waste in which nearly half was vegetable waste), a number much lower than that in high-income countries and the Chinese urban restaurants. We also found that such a number varies considerably by household (0–126.21 g/cap/meal), and almost half of surveyed households generated almost no food waste. Among the surveyed prefectural areas, food waste in Jinan was significantly higher than that in Dezhou and Weifang (P

Reservoirs are well known as a far-reaching human modification on the functions of natural river networks. However, changes in the chemistry and reactivity of dissolved organic matter (DOM) responding to hydrological management for water retention structures, and its influence on the river carbon cycle, remain poorly understood. Here we show that hydrological management does shape the molecular composition of DOM in the world's largest Three Gorges Reservoir, as revealed by optical spectroscopy and ultrahigh-resolution mass spectrometry. Relatively higher terrestrial input, molecular complexity, isomeric complexity, and environmental stability of DOM were observed during the storage period, whereas the inverse occurred during the drainage period. The results demonstrate that the hydrodynamic processes, which are mainly controlled by water intrusion from mainstream to tributaries, are likely the underlying mechanism controlling DOM chemistry. Integrated with observations from worldwide river reservoirs, the DOM degradation experiments suggest that reservoir hydrological management would enhance DOM mineralization, thereby increase CO2 emission and change the river carbon cycle.

It is critical to assess drought risk based on a reliably integrated drought index incorporating comprehensive information of meteorology, hydrology and agriculture drought indices, which is of great value for further understanding the future drought tendency, prevention and mitigation. Thus, the primary objective of this study was to focus on constructing a multivariate integrated drought index (MIDI) by coupling four drought indices (i.e., Precipitation Anomaly Percentage (PAP), Runoff Anomaly Percentage (RAP), Standardized Precipitation Index with 6-month aggregation time step (SPI6) and Modified Palmer Drought Severity Index (MPDSI)) to objectively and comprehensively investigate drought risk. The variable fuzzy set theory and entropy weight method are used during the MIDI construction process. Based on the MIDI, a drought event including drought duration and severity is redefined using run theory. Then copula-based drought risk is fully assessed through the joint probability distribution of drought duration and severity. Results indicate the following: (1) the constructed MIDI is consistent with the Standardized Precipitation Index (SPI) and Runoff Anomaly Percentage (RAP) series, and it is more sensitive and effective to capture historical drought events; (2) the drought characteristics present noticeable spatial variability among five subzones, and the entire basin has 49 droughts with the longest drought duration spanning 8.55 months; and (3) the mainstream, especially the middle and lower reaches, has higher occurrences of severe droughts for approximately every 10 years.

We investigate two-photon luminescence (TPL) of single CdSe nanowires (NWs) excited by tightly focused cylindrical vector beams of 150 fs pulses, achieving an optical resolution better than λ/4. Comparing the TPL images recorded by scanning the nanowires through the focal fields created either by a radially or an azimuthally polarized vector beam we observe a distinct anisotropic excitation efficiency which depends on the orientation of the electric field component with respect to the nanowire. The excitation anisotropy of the linear photoluminescence (PL) and TPL can directly be derived from the respective image patterns. Our results show that the highest TPL signal from a single NW is detected when the electric excitation field is parallel to the long axis of the NW, i.e. about one order of magnitude stronger than that excited along the short axis. We attribute the TPL to an emission mechanism based on the recombination of free carriers, which exhibits a fourth order excitation power dependence in low power regime and a second order power dependence in high power regime.

Fully elucidating the precipitation–runoff relationship (PRR) is of great significance for better water resources planning and management and understanding hydrological cycle processes. For investigating the multi-scale PRR variability in the Weihe River basin in 1960–2010, a new hybrid method is proposed in which ensemble empirical mode decomposition (EEMD) and cross wavelet transform and wavelet transform coherence are used in combination. With the application of mutual information entropy, monthly precipitation and runoff are decomposed into two parts: high- (HFC) and low-frequency components (LFC). The results show that HFCs are characterized by inter- and intra-annual variations in precipitation and runoff, whereas LFCs display approximately two-year periodicity and contain abundant abnormal information of the raw data. Therefore, the PRR between HFCs exhibited significant correlations at the 95% confidence level over the whole time period. However, the correlations of the PRR between LFCs are not significant for many of the time-frequency domains. Additionally, the phase relations are disordered in these time-frequency domains, and no certain trend in phase angle variations can be identified. Through comparative analysis of the anthropogenic activities and climatic events with PRR variations, it can be concluded that the hybrid method can efficiently capture the PRR in various time-frequency domains.

A type of nanolaser array based on individual waved CdS nanoribbons is proposed. The ridges with the triangular cross section are formed and act as the position‐defined optical cavities periodically aligned along the length direction of the ribbons. These subcavities integrated in single ribbons can all realize lasing under pulsed laser excitation.

Sweet potato starch (SPS) granules were firstly subjected to heat-moisture treatment (HMT) and then esterified with citric acid (CA). The physicochemical properties of CA-starch and heat moisture treatment citric acid starch (HMT-CA-starch) were investigated. Results showed that the high dosage of CA significantly increased the degree of substitution (DS) and the resistant starch (RS) content of the CA-starch (P

The main goal of this study is to introduce the Archimedean copulas, which overcome the low accuracy and subjective nature of the traditional double mass curve method, to investigate the precipitation–runoff relationship (PRR) and detect change points in the Weihe River Basin (WRB). With the construction of a joint distribution between precipitation and runoff by the Archimedean copulas, a statistical variable considering the distribution parameter was estimated to judge the change point of the PRR. The results show that: (1) annual precipitation and runoff present decreasing trends that are significant and insignificant, respectively, at the 95% significance level, while annual potential evapotranspiration (PET) increases slightly; (2) change points of the PRR occurred in 1971 and 1994; (3) the annual runoff changed more dramatically than precipitation during the periods from 1972 to 1994 and 1995 to 2010 compared with 1960–1971, which indicates that in addition to precipitation, there are some other non-precipitation factors that are responsible for the change in the PRR; and (4) the contributions to runoff from human activities declined from 1972 to 1994 (84.15%) and 1995 to 2010 (57.16%). These results suggest that human activities (e.g., irrigation, reservoirs, water-and-soil conservation) were the primary driving forces leading to changes in the PRR in the WRB.

It is critical important to accurately evaluate hydrological drought evolutions based on a composite index for the sustainable development of water resources. In this study, a Nonlinear Joint Hydrological Drought Index (NJHDI) is constructed by combining surface water and groundwater to better reflect the multivariate phenomenon in characterizing hydrological drought. The bi-dimensional copula function is applied to describe the complicated and nonlinear relationship between surface water and groundwater due to its dependence structure and flexibility. To reflect the changes in underlying surface, the time-varying parameters are applied in the Soil and Water Assessment Tool (SWAT) model to simulate the surface water and groundwater more accurately. Based on the NJHDI, the spatio-temporal hydrological drought evolutions as well as their potential influencing factors are analyzed in a case study of the Yellow River Basin (YRB). Results indicate that: 1) compared to the single hydrological index, the NJHDI is more sensitive and effective to capture historically droughts; 2) hydrological droughts became increasingly serious during the last few decades, especially in parts of the basin located in the Loess Plateau areas where the ecosystem is extremely fragile; 3) climate and LULC changes have both contributed to the changes in hydrological droughts but their contributions vary significantly spatially. In general, the NJHDI-based hydrological drought evolution can provide more reliable information in hydrological drought decision-making owing to considering changes in underlying land surface, and combining the surface water and groundwater with nonlinear combination method.

Micro/nanostructures with high aspect ratios in silicon wafers obtained by plasma etching are of great significance in device fabrication. In most cases, the scallop nanostructure in deep silicon etching should be suppressed. However, the scallop nanostructure could be applied in electronic device fabrication as characteristic information, which indicates the balance between deposition and etching. In this work, the applications of scallop nanostructures in etching process optimization and environmental protection are demonstrated. In addition, the minimum effect of the cycle time on the scallop size is reported for the first time. These results could bring new thoughts to the electronic devices related fields, such as micro-electro-mechanical systems (MEMS), silicon capacitors and advanced packaging.

Copula-based statistical model has been extensively used to characterize the joint probability behaviors of extreme hydro-climatic design events, such as bivariate design floods. However, parameter uncertainty, not desirably but inevitably, accompanies the copula-based design flood estimation (CDFE) model which makes the inference results of design flood ambiguous. In this paper, we develop a Bayesian information-theoretic (BIT) approach to disclose design flood uncertainty arising from parameter uncertainty in CDFE model and furthermore examine how the parameter uncertainty is propagated to design flood estimation. Two catchments located in the Yellow River Basin, China, are selected as study regions. The research we have done indicates that design flood uncertainty is considerably large under parameter uncertainty. Worse still, the uncertainty in design flood increases along with the return period, thus making the design flood inference more ambiguous. Specifically, shape and scale parameters of marginal distributions have the largest contribution to the design flood uncertainty, followed by copula parameter, finally the location parameter of marginal distribution. Furthermore, the interaction between some parameters has dominant effect on design flood uncertainty compared with the individual effect of these parameters. These findings will enable better understanding the design flood uncertainty under parameter uncertainty. Moreover, the proposed BIT approach also offers a promising technical reference for design estimation of other types of extreme hydrological events, not limited to the design flood.

A fluorescent nanoprobe based on yellow-emissive carbon dots (Y-CDs) has been constructed for selective and sensitive sensing of 2,4,6-trinitrophenol (TNP). Y-CDs with a large Stokes shift (115 nm) were obtained through a simple one-pot solvothermal method. Significantly, the addition of TNP induced remarkable quenching of fluorescence intensity of Y-CDs via an inner filter effect. There was a good linear relationship between the fluorescence of Y-CDs and TNP concentration (0.2–130 μM), displaying a limit of detection of 56 nM. The nanoprobe can selectively detect TNP without interference from other nitroaromatic explosives, and has been successfully used for determining TNP in environmental water samples, representing a convenient tool for TNP sensing in environmental samples.

Determining the resource intensity and environmental impacts of tourist food consumption is important for the design of sustainable development strategies for tourist destinations. Yet, studies aiming to accurately quantify the environmental repercussions of tourist food consumption for specific destinations are rare and take limited account of temporal changes in food consumption patterns among tourists. This study contributes to knowledge by calculating the impact of temporal changes in tourist food consumption on arable land requirements (ALR) in a popular tourist destination of Lhasa, Tibet. It finds that tourist food consumption per meal has increased by 8% within the period of 2013–15 which translates into over 50% increase in ALR. The study further pinpoints that 84% of the ALR increase is attributed to the animal-based food consumption of tourist. Lastly, the study shows that, in 2015, nearly 62% of the arable land area of the Lhasa region was required to meet the growing tourist demand for food.

Mercury (Hg) pollution seriously threatens food safety and has attracted global attention. Phytoextraction, due to its low cost, applicability, and environmental friendliness, is considered a new technology for clean-up of heavy metal contamination in the environment. However, the low bioavailability of Hg in polluted areas greatly limits the applicability of phytoextraction. Here, we compared the effects of six common chelating ligands on the absorption and transport of Hg in maize (Zea mays L.), which has a high biomass and short growth cycle. The results showed that the root length and biomass of maize seedlings of the groups treated with the six chelating ligands (EDTA, iodide, ammonium, thiosulfate, thiocyanate, and thiocarbamide) did not change compared with those of the non-treated groups. Co-exposure to Hg and each chelating ligand markedly alleviated the inhibitory effect induced by Hg. Iodide treatment resulted in the lowest root Hg content and highest translocation factor (TF) value, while ammonium treatment gave rise to the highest shoot Hg concentration and lowest TF. Compared with other chelating ligands, thiosulfate exhibited the maximum alleviation of Hg toxicity and achieved the highest concentration of Hg in the roots and aerial parts. Moreover, the TF and Hg accumulation in the thiosulfate and Hg co-exposed group were much higher than those in the group exposed to Hg alone. This finding suggests that, among these common chelating ligands, thiosulfate compounds have great potential for Hg phytoextraction, while the others can immobilize Hg in polluted areas.

The mixture of finely ground blast furnace slag (BFS), basic oxygen furnace (BOF) steel slag (SS), and flue gas desulfurisation (FGD) gypsum could be used as cement to solidify heavy metals. In this study, these cementitious materials were combined with high-arsenic-containing tailings to form cemented backfill material (CBM). The results indicated that the optimal design of CBM was that of specimen CBM2 which showed good early strength (10.09 MPa) at a curing age of 3 days containing 60% BF slag, 30% SS, and 10% gypsum. And the arsenic leaching concentration of CBM2 at a curing age of 7 days and 28 days were both less than the limits specified in standards for drinking water quality (Chinese Standard GB 5749-2006). The predominant hydration products of CBM2 contained rod-like ettringite and amorphous C–S–H gel both of which promote arsenic solidification.

Normalized difference vegetation index (NDVI) is an important indicator for measuring vegetation coverage, which is of great significance for evaluating vegetation dynamics and vegetation restoration. It can clearly analyze the suitable growth condition of vegetation by studying the relationship between meteorological factors, soil moisture and NDVI. Based on MODIS/NDVI data, the spatio-temporal characteristics of vegetation coverage in the Weihe River Basin (WRB) were analyzed by the trend analysis method. The relationship of NDVI with meteorological factors and NDVI with soil moisture simulated by the soil and water assessment tool (SWAT) model was analyzed in this paper. The results show that NDVI values gradually change with an increase from north to south in the WRB. The maximum of the average monthly NDVI is 0.702 (August) and the minimum is 0.288 in February from 2000 to 2015. The results of the seven grades of NDVI trend line slope indicate that the improvement area of vegetation coverage accounts for 30.93% of the total basin, and the degradation area and basically unchanged area account for 23% and 42.9%, respectively. The annual mean soil moisture is 19.37% in the WRB. There was a strong correlation between NDVI and precipitation, temperature, evaporation and soil moisture, and the correlation coefficients were 0.78, 0.89, 0.71 and 0.65, respectively. The ranges of the most suitable growth conditions for vegetation are 80–145 mm (precipitation), 13–23 °C (temperature), 94–144 mm (evaporation) and 25–33% (soil moisture), respectively.

In the absence of advection, confined diffusion characterizes transport in many natural and artificial devices, such as ionic channels, zeolites, and nanopores. While extensive theoretical and numerical studies on this subject have produced many important predictions, experimental verifications of the predictions are rare. Here, we experimentally measure colloidal diffusion times in microchannels with periodically varying width and contrast results with predictions from the Fick-Jacobs theory and Brownian dynamics simulation. While the theory and simulation correctly predict the entropic effect of the varying channel width, they fail to account for hydrodynamic effects, which include both an overall decrease and a spatial variation of diffusivity in channels. Neglecting such hydrodynamic effects, the theory and simulation underestimate the mean and standard deviation of first passage times by 40\% in channels with a neck width twice the particle diameter. We further show that the validity of the Fick-Jakobs theory can be restored by reformulating it in terms of the experimentally measured diffusivity. Our work thus demonstrates that hydrodynamic effects play a key role in diffusive transport through narrow channels and should be included in theoretical and numerical models., Comment: 7 pages, 4 figures

The dynamics of a pair of identical artificial microswimmers bound inside two harmonic traps, in a thin sheared fluid film, is numerically investigated. In a two-dimensional Oseen approximation, the hydrodynamic pair coupling is long-ranged and proportional to the particle radius to film thickness ratio. On increasing such ratio above a certain threshold, a transition occurs between a free regime, where each swimmer orbits in its own trap with random phase, and a strong synchronization regime, where the two swimmers strongly repel each other to an average distance larger than both the trap distance and their free orbit diameter. Moreover, the swimmers tend to synchronize their positions opposite the center of the system.

The mechanism of thermal conductivity in amorphous polymers, especially polymer fibers, is unclear in comparison with that in inorganic materials. Here, we report the observation of across over of heat conduction behavior from three dimensions (3D) to quasi-one dimension (1D) in Polyimide(PI) nanofibers at a given temperature. A theoretical model based on the random walk theory has been proposed to quantitatively describe the interplay between the inter-chain hopping and the intra-chain hopping in nanofibers. This model explains well the diameter dependence of thermal conductivity and also speculates the upper limit of thermal conductivity of amorphous polymers in the quasi-1D limit., Comment: this article is published in National Science Review(NSR) Link: https://doi.org/10.1093/nsr/nwy004

The Ning-Meng reach of the Yellow River in China is located in a high-latitude area, and river freezes up and breaks up every year, leading to ice flood and disaster. Since the 1990s, due to the rising winter temperatures, river channel shrinkage and impacts of reservoir operation, the river ice regime of the Ning-Meng reach has changed. This paper investigated reservoir operation effect on river ice regime by eliminating the impact of climatic conditions, and the test method could be applied to other rivers, where similar anthropogenic impacts can be suspected to affect the river ice regime. The results show that compared to the statistics when there were no reservoirs, the duration of ice freezing days reduced 8–33 days, and the ice cover thickness was 16–25 cm thinner than that without reservoirs. The average number of ice flood incidents per year decreased from 11.61 to 3.25, and the number of disasters reduced from 1.69 to 1.41. Moreover, the changes induced by reservoirs joint operation may vastly exceed that by single reservoir operation. The smaller is the distance to the upstream reservoir, the more obvious is the impact from the reservoir.

Background and aims: Iron plaque can affect the absorption and accumulation of metal(loid)s in plants. However, it is still unclear whether iron plaque plays different roles in the accumulation of different mercury species in rice plants. The aims of this study are 1) to explore the adsorption of IHg and MeHg onto iron plaque, 2) to investigate the influence of iron plaque on the absorption, translocation of IHg and MeHg in rice plants, 3) to explore whether the process of methylation and demethylation of Hg in vivo occurs in rice plants, and 4) to investigate the effects of iron plaque on the IHg and MeHg transformation in rice. Methods: The seedlings were cultivated in an Fe2+ soln. for 24 h to induce the iron plaque and then transferred into a nutrient soln. contg. 500 渭g/L HgCl2 or MeHgCl for 72 h. The Hg content in the iron plaque and rice seedlings was measured by ICP-MS. The chem. forms of Hg in the rice seedlings were detd. with HPLC-ICP-MS and XANES. Results: Both IHg and MeHg, particularly MeHg, could be adsorbed by iron plaque. The IHg content of the root and the MeHg content in both the roots and shoots decreased markedly with the increase in iron plaque. The Hg in the root was mainly in the form of RS-Hg-SR with the exposure to HgCl2 and in the form of CH3-Hg-SR and RS-Hg-SR (4:1) with the exposure to MeHgCl. The iron plaque did not change the chem. forms of Hg in the rice plants. Conclusions: Iron plaque greatly decreased the absorption and translocation of both IHg and MeHg in rice seedlings. The demethylation of MeHg occurred in rice plants (in vivo) regardless the formation of iron plaque. This work sheds some light on the understanding of different pathways between IHg and MeHg in rice plants. [on SciFinder(R)]