1. Synthesis of Lanthanum Orotate and its Application as PVC Thermal Stabilizer
- Author
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Mansurjon Juraev, Xiao Tao Ma, Feng Ye, Cheng Fang, Xiao Ya Zhou, Qiu Feng Ye, and Ye Qian Ge
- Subjects
Materials science ,Mechanical Engineering ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Poly vinyl chloride ,chemistry ,Chemical engineering ,Mechanics of Materials ,Thermal ,Lanthanum ,General Materials Science ,0210 nano-technology ,Stabilizer (chemistry) - Abstract
The structure of basic lanthanum orotate (LaOr) were characterized by elemental analysis and infrared spectroscopy. The thermal stability of polyvinyl chloride (PVC) was further studied by Congo red method, oven discoloration method and thermogravimetric analysis. The results showed that LaOr could prolong the oven discoloration time of PVC, and the color was not completely blackened until 120 min. It has a good synergetic effect with dibenzoyl methane (DBM), and the best effect is achieved when LaOr/DBM ratio is 1.8/1.2. The thermal decomposition kinetics experiment showed that adding DBM can effectively improve the activation energy of PVC/LaOr. The stabilization mechanism of PVC was studied by absorbing HCl method and infrared spectroscopy. The results showed that LaOr could not only replace the unstable chlorine atoms on PVC, but also promote the long-term thermal stability of PVC by absorbing HCl.
- Published
- 2021