1. Robust Protection of III–V Nanowires in Water Splitting by a Thin Compact TiO2 Layer
- Author
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Kwang-Leong Choy, Sanjayan Sathasivam, Ali Imran Channa, Christopher S. Blackman, Mingqing Wang, Ivan P. Parkin, Yunyan Zhang, Xueming Xia, Fan Cui, H. Aruni Fonseka, Ana M. Sanchez, Ting Li, Huiyun Liu, Hui Yang, Premrudee Promdet, Jiang Wu, and Hezhuang Liu
- Subjects
Photocurrent ,Materials science ,business.industry ,Nanowire ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Photocathode ,0104 chemical sciences ,Atomic layer deposition ,Semiconductor ,Optoelectronics ,Water splitting ,General Materials Science ,0210 nano-technology ,business ,Layer (electronics) ,Faraday efficiency - Abstract
Narrow-band-gap III-V semiconductor nanowires (NWs) with a suitable band structure and strong light-trapping ability are ideal for high-efficiency low-cost solar water-splitting systems. However, due to their nanoscale dimension, they suffer more severe corrosion by the electrolyte solution than the thin-film counterparts. Thus, short-term durability is the major obstacle for using these NWs for practical water-splitting applications. Here, we demonstrated for the first time that a thin layer (∼7 nm thick) of compact TiO2 deposited by atomic layer deposition can provide robust protection to III-V NWs. The protected GaAs NWs maintain 91.4% of its photoluminescence intensity after 14 months of storage in ambient atmosphere, which suggests the TiO2 layer is pinhole-free. Working as a photocathode for water splitting, they exhibited a 45% larger photocurrent density compared with unprotected counterparts and a high Faraday efficiency of 91% and can also maintain a record-long highly stable performance among narrow-band-gap III-V NW photoelectrodes; after 67 h photoelectrochemical stability test reaction in a strong acid electrolyte solution (pH = 1), they show no apparent indication of corrosion, which is in stark contrast to the unprotected NWs that fully failed after 35 h. These findings provide an effective way to enhance both stability and performance of III-V NW-based photoelectrodes, which are highly important for practical applications in solar-energy-based water-splitting systems.
- Published
- 2021