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The lack of plant-side energy storage analysis to support nuclear power plants (NPP), has setup this research endeavor to understand the characteristics and role of specific storage technologies and the integration to an NPP. The paper provides a qualitative review of a wide range of configurations for integrating the energy storage system (ESS) to an operating NPP with pressurized water reactor (PWR). The role of ESS technologies most suitable for large-scale storage are evaluated, including thermal energy storage, compressed gas energy storage, and liquid air energy storage. The methods of integration to the NPP steam cycle are introduced and categorized as electrical, mechanical, and thermal, with a review on developments in the integration of ESS with an operating PWR. By adopting simplified off-design modeling for the steam turbines and heat exchangers, the results show the performance of the PWR steam cycle changes with respect to steam bypass rate for thermal and mechanical storage integration options. Analysis of the integrated system characteristics of proposed concepts for three different ESS suggests that certain storage technologies could support steady operation of an NPP. After having reviewed what have been accomplished through the years, the research team presents a list of possible future works.

Organic light-emitting diode (OLED) microdisplays have attracted much attention as displays for small form factor augmented reality (AR) devices. To realize glass-like thin and wide field of view (FoV) AR devices, we designed a display module with a high aspect ratio microdisplay and a thin optical component. For the high aspect ratio microdisplay, we developed the color OLED microdisplay with a 32:9 aspect ratio and a 0.8-inch diagonal ∼2,490-ppi CMOS backplane. To express color and reduce optical crosstalk, we fabricated the color filter (C/F) patterning directly on the white OLED. We also developed a pin mirror lens with 11 pin mirrors to improve the optical efficiency and quality with a thin lens. By combining the microdisplay with LetinAR’s pin mirror lens, we successfully demonstrated an AR device with a wide horizontal FoV of 46° but with a small form factor 4 mm lens.

From the very first time that graphene was used as a transparent electrode for OLED applications, the emergence of active-matrix (AM)-graphene OLED displays has been envisioned. Realizing this expectation, however, turned out to be difficult. Two obstacles are the growth and transfer of a large-area graphene film and the patterning of a graphene film into pixels. To solve these problems, a process of patterning a graphene film without surface contamination was developed. The fabrication of OLED panels by the patterned graphene anode on Gen 2(370 × 470 mm)-sized and flexible substrates was successfully demonstrated. In this work, oxide TFT arrays were combined as a switching backplane, and a pixelated graphene OLED was used as an emissive layer, to realize AM-graphene OLED displays. To explore the technical feasibility of flexible AM-graphene OLED displays, the aforementioned components were formed on a flexible substrate. For commercial-level production, all the processes that were used were chosen to be compatible with the conventional display processes.

Microdisplay is a key technology for realizing augmented reality (AR) and mixed reality (MR) devices, which have attracted much attention of late. Even though the operating voltage in the tandem structure is higher than that in the single structure, 2-stack tandem OLED exhibited 20,000 cd/m2 at 9 V, which is compatible with CMOS circuit driving. Due to its top-emitting geometry with a tandem structure, the OLED device with a well-controlled thickness exhibited a white spectrum with (0.26, 0.26) color coordinates. The pixel density of the fabricated microdisplay panel with a white tandem OLED was about 2350 pixels per inch, and the active area of the panel was 0.7 inch diagonally. The resolution of the panel was 1280 × 1024, corresponding to SXGA, and the maximal luminance was 3,000 cd/m2.

Air pollution sensors based on organic transistors have attracted much interest recently; however, the devices suffer from low responsivity and slow response and recovery rates for gas analytes. These shortcomings are attributed to the low charge-carrier mobility of organic semiconductors and to a structural limitation resulting from the use of a thick and continuous active layer. In the present work, we investigated the material properties of a multiscale porous zeolitic imidazolate framework, [Zn(2-methylimidazole)2]n (ZIF-8), and examined its potential as an analyte channel material inserted at an organic-transistor active layer. A series of carbonized zeolitic imidazolate frameworks (ZIFs) were prepared by thermal conversion of ZIF-8 and also studied for comparison. The microstructures, morphologies, and optical/electrical characteristics of polythiophene/ZIF-8 hybrid films were systematically investigated. Organic-transistor-type nitrogen dioxide sensors based on the polythiophene/ZIF-8 hybrid films showed substantially improved sensing properties, including responsivity, response rate, and recovery rate. The electrical conductivity of the carbonized ZIF-8s enhanced the field-effect mobility of the organic transistors; however, the sensing performance was not improved, because of the closed pore structures resulting from the carbonization. These results provide invaluable information and useful insights into the design of transistor-type gas sensors based on organic semiconductor/metal-organic framework hybrid films.

A supercritical CO2 (S-CO2)-cooled Brayton cycle is under development for distributed power applications for remote regions. In order to successfully develop it, issues of controlling shaft levitation with bearings have to be solved. From several studies, magnetic bearings have been suggested for reliable levitation performance with reduced cost and complexity. However, several studies on magnetic bearing show that instability issues under high-pressure fluid and high-speed operating conditions may exist. The purpose of this research is to provide background for understanding the instability of magnetic bearings under S-CO2 conditions and propose functional requirements of the magnetic bearing. Thus, the rotating shaft with magnetic bearings operating under high pressure fluid was first analyzed. To test the theory, a magnetic bearing test rig was constructed. By comparing experimental data to the analysis results, the analysis results were verified. Therefore, the analysis results can be used for predicting instability in the future and can contribute to the development of better magnetic bearing controllers.

Supercritical CO2 (S-CO2) has the potential to be used as the working fluid in a power cycle since S-CO2 shows a density value high as its liquid phase while the viscosity value remains closer to its gaseous phase. Thus, it requires much less work to compress due to its low compressibility as well as relatively small flow resistance. However, the S-CO2 leakage flow from turbo-machinery via seal becomes one of the important issues since not only it influences the cycle efficiency due to parasitic loss but also it is important for evaluating the system safety under various operating conditions. In this paper, the gap effect, which is studied by changing the diameter of an orifice, cavity length effect, and the number of tooth effect in a simulated labyrinth seal geometry nozzle are presented. Experimental results under various conditions including not only single phase flow but also two phase flow conditions are presented.

Operation with reduced number of operators is considered as an important operational mode to improve economics of a nuclear power plant (NPP) in the future and it will be more important for the small modular reactors (SMRs). To control NPPs efficiently and safely with a reduced number of operators, an intelligent operation system can be very useful. However, reduced number of operators will result in larger consequence in human error due to simultaneous multi-unit failures are now more probable than the conventional operational mode. Thus, to decrease the probability of human error occurrence for the reduced number of operators, the development of an autonomous operation system with certain level of intelligence is inevitable. The prediction capability of system’s behavior as well as understanding the root cause for the current situation should be an essential function of the designed autonomous operation system. The authors propose to use the current system thermal–hydraulic (STH) analysis code platform to develop such intelligence. As a demonstration of the suggested method, the authors used the STH code to track the accident initiator of both large pressurized water reactor (PWR) and SMR. The discussions on how this method can be useful for future NPP operation and how generic differences in system design actually influence the system behavior are presented.

In this study, condensation heat transfer and multi-phase pressure drop of CO2 near the critical point are investigated occurring in a Printed Circuit Heat Exchanger (PCHE) for a supercritical CO2 power cycle application in mind. Homogeneous Equilibrium Model (HEM) approach is used to evaluate and develop appropriate heat transfer and pressure drop correlations. The experiment was performed with the CO2 test facility called SCO2PE (Supercritical CO2 Pressurizing Experiment) in KAIST. The heat transfer and pressure drop test was conducted with the PCHE in the facility. Existing correlations were compared to the test data and a new set of correlations was necessary to be developed. A new set of correlations is newly suggested in this paper which captures physical characteristics reasonably well.

We investigated the optical reflectance, surface roughness, and sheet resistance of aluminum (Al)/titanium nitride (TiN), titanium (Ti), and tungsten (W) layers on Si substrates, which are available in the CMOS foundry, for organic light-emitting diode (OLED) microdisplays. The devices with different metal anode layers exhibited different hole-injection properties and OLED performances, owing to the different optical and electrical properties of metal anode layers. Based on the OLED characteristics, the Al/TiN layer was selected as an anode layer for OLED microdisplays. A green monochromatic OLED microdisplay panel was designed and implemented using the 0.11-μm CMOS process. The density of pixels was ~2 351 pixels per inch and the panel's active area was 0.7 in in diagonal. The resolution of the panel was 1 280 × 3 × 1 024, corresponding to SXGA. The panel was successfully operated, and the maximal luminance was ~460 cd/m2.

The enhancement of the luminance of organic light-emitting diode (OLED) panels with various areas (2.25–6084 mm2) using a microlens array (MLA) film was investigated. The luminance enhancement was dependent on the viewing angle, and the largest enhancement (64%) was observed in the normal direction while 60 and 18% enhancements were observed at 60 and 30°, which led to lower enhancement (38%) of the total luminous flux compared with the luminance enhancement (64%) in the normal direction. The luminance enhancement with the MLA film also depended on the panel area, and the smaller panels showed lower luminance enhancement than the larger ones. As for the small panels, the straying light beyond the panel areas significantly affected the luminance of the panels, and over 60% luminance enhancement was observed in the normal direction for the large panels (2500 and 6084 mm2) with the MLA film while only 48 and 58% luminance enhancements were observed at the small panels (2.25 and 70 mm2).

Rubrene-based electrochemiluminescence (r-ECL) cells with two different solvent systems is prepared, one in a co-solvent system with a mixture of 1,2-dichlorobenzene and propylene carbonate (DCB : PC, v/v 3 : 1) and another in a single solvent system of tetrahydrofuran (THF), as the medium to form a liquid-electrolyte (L-El). By simply changing the solvent systems, from the co-solvent DCB : PC (v/v 3 : 1) to the single solvent THF, with the same amount of electrochemiluminescent rubrene (5 mM) and Li-based salt, a dramatically enhanced brightness of over 30 cd m−2 is observed for the r-ECL cell in L-ElTHF which is approximately 7-times higher than the brightness of 5 cd m−2 observed for the r-ECL in L-ElDCB:PC(v/v 3:1).

Due to small footprint and high efficiency, a Supercritical CO2 (S-CO2) power cycle is considered to be one of the promising next-generation power cycles. Although S-CO2 is reported as a powerful cleaning agent, the performance of a power system operating with S-CO2 will also inevitably degrade over time. Previous researchers have shown that turbomachinery deterioration could be a major subject regarding the system performance degradation. Nevertheless, no quantitative evaluation has yet been made so far. In this study, the impact of the performance degradation of the S-CO2 turbomachinery on the overall performance of the system is analyzed quantitatively. The concept of Health Parameter is used to simulate turbomachinery degradation. To quantify the impact, an S-CO2 direct-cycle small modular reactor is selected as a target system. A transient analysis platform is built using a nuclear system safety analysis code and the deep neural network (DNN)-based S-CO2 turbomachinery off-design performance model. System dynamics are evaluated for primary frequency control ability and secondary load-following capability. Results show that the control problems during the transient state can occur when the output fluctuations are large and the performance degradation is severe. It has been confirmed that even control failures of the PID controllers can occur. Therefore, the performance degradation of turbomachinery must be monitored and considered, for an operation strategy for S-CO2 systems.

The ability to image pressure distribution over complex three-dimensional surfaces would significantly augment the potential applications of electronic skin. However, existing methods show poor spatial and temporal fidelity due to their limited pixel density, low sensitivity, or low conformability. Here, we report an ultraflexible and transparent electroluminescent skin that autonomously displays super-resolution images of pressure distribution in real time. The device comprises a transparent pressure-sensing film with a solution-processable cellulose/nanowire nanohybrid network featuring ultrahigh sensor sensitivity (>5000 kPa−1) and a fast response time (1000 dpi) pressure imaging without the need for pixel structures. Our approach provides a new framework for visualizing accurate stimulus distribution with potential applications in skin prosthesis, robotics, and advanced human-machine interfaces., Electronic skin that spatially maps pressure distribution through imaging shows limited performance despite improvements to data acquisition. Here, the authors report ultraflexible, transparent electroluminescent skin capable of high-resolution imaging of pressure distribution over 3D surfaces.

A methodology is developed for thermal-hydraulic analysis and design of a breed-and-burn molten salt reactor (BBMSR). By using separate fuel and coolant molten salts, the BBMSR is proposed to overcome key materials limitations of traditional breed-and-burn and molten salt reactor designs. The BBMSR fuel concept includes an inner wall that divides the ascending and descending flows of naturally convecting fuel salt. A finite-difference model (FDM) is developed to iteratively solve for the temperature and velocity distributions in both sections of the concentric fuel. The FDM is used to perform parametric studies of the effect of fuel geometry and heat generation rate on the heat transfer performance of the fuel. The FDM is then integrated into a design search algorithm that identifies the operational limits for a given BBMSR fuel geometry, within a set of defined constraints. A range of thermal-hydraulic fuel design options are evaluated, and trade-off studies are performed to identify the most promising fuel design space for competitive power production and neutronic efficiency in the BBMSR.

After the Fukushima accident, the importance of an emergency power supply for a nuclear power plant has been emphasized more. In order to maximize the performance of the existing emergency power source in operating nuclear power plants, adding a waste heat recovery system for the emergency power source is suggested for the first time in this study. In order to explore the possibility of the idea, a comparison of six supercritical carbon dioxide (S-CO2) power cycle layouts recovering waste heat from a 7.2 MW alternate alternating current diesel generator (AAC DG) is first presented. The diesel engine can supply two heat sources to the waste heat recovery system: one from exhaust gas and the other from scavenged air. Moreover, a sensitivity study of the cycles for different design parameters is performed, and the thermodynamic performances of the various cycles were evaluated. The main components, including turbomachinery and heat exchangers, are designed with in-house codes which have been validated with experiment data. Based on the designed cycle and components, the bottoming S-CO2 cycle performance under part load operating condition of AAC DG is analyzed by using a quasi-steady state cycle analysis method. It was found that a partial heating cycle has relatively higher net produced work while enjoying the benefit of a simple layout and smaller number of components. This study also revealed that further waste heat can be recovered by adjusting the flow split merging point of the partial heating cycle.

A new structure for a switchable mirror device based on reversible electrodeposition is proposed. This device does not contain Cu ions in the electrolyte and adapts a counter electrode. The feasibility of the device was evaluated with a WO3 film, which is a well-known electrochromic material, as a counter electrode. Even in the absence of Cu ions, the WO3 film facilitates a clean erase feature in the device. Furthermore, using a pre-deposited Ag film as a working electrode, Ag deposition can be driven at a substantially lower voltage than that in conventional devices. Moreover the deposition current decreases with the progress of Ag deposition, and stops after completion of the deposition process. The results clearly indicate that the tri-bromine ion, which makes the self-erasing circulation, is not generated during Ag deposition process. The new switchable mirror shows excellent bistability and size scale-up is possible because it does not consume continuous current in the mirror state. By appling the proposed technology, a switchable mirror device with a 7 cm × 9 cm active area was successfully fabricated.

Nuclear power plants should be capable of contributing safely and flexibly to the electrical grid stability. This research deliberates the feasibility of a new innovative concept of a passive and autonomous frequency control operation (PAFO) in soluble-boron-free (SBF) pressurized water reactors (PWRs). The new concept eliminates any required active control in the reactor core for attaining primary and secondary frequency control operational modes in PWRs. In particular, control rods and soluble-boron are not utilized in a PAFO. Meanwhile, the reactor power maneuvering is achieved entirely by the passive reactor feedback to the coolant temperature change. This approach is motivated by the strongly negative coolant temperature coefficient available in an SBF coolant system. In order to ascertain judiciously the practical viability of the proposed concept, numerical simulations of passive primary and secondary frequency operations are performed using a lumped PWR system model solved by an in-house FORTRAN-95 computer code. The various simulation parameters are obtained from 3D Monte Carlo simulations of an SBF 450 MWt PWR by using Serpent-2 code with ENDF/B-7.1 data library. The numerical simulations are carried out at the beginning, middle and end of the fuel cycle to emphasize the effect of fuel burnup on the proposed PAFO. Moreover, sensitivity analyses on xenon worth and nominal fuel temperature are performed to deliberate their impacts in tailoring the reactor performance. Because the reactor power matches well with the power demand with a small variation in coolant temperature during the frequency control, we conclude that there is promising potential for the proposed PAFO concept.

Supercritical CO2 (S-CO2) power cycles have received much attention due to their desired advantages in various applications. Due to the substantial difference in specific heat of S-CO2 at different pressure, unique characteristics inside heat exchangers, especially in the recuperator, are observed and affect the cycle design. In this research, the problem of inner pinch occurring inside the S-CO2 recuperator is identified and resolved by suggesting a new framework for the definition of heat exchanger effectiveness using the point of zero inner pinch. The design methodology of S-CO2 cycles is improved using this definition by developing a module to calculate the zero inner pinch using artificial neural network (ANN) to undergo a learning process. As a result, the computation time required for cycle analysis is reduced by an order of 10 3 in the case of simple recuperated Brayton cycle, under the accuracy of 10 - 7 error bound. As the readers gain the access to the developed module for calculating the zero inner pinch, the procedure for S-CO2 cycle optimization will become far more manageable for researchers, and as a result, this result can allow the conceptualization of even further complex layouts in S-CO2 cycle research.

Adjoint sensitivity based optimization methodology for a supercritical CO2 (S-CO2) cycle is developed in this paper. The adjoint sensitivity analysis method (adjoint method) is a way to analyze sensitivity very quickly. By using the developed methodology, the optimal state variation due to the change of cycle parameters is analyzed. The S-CO2 recompression Brayton cycle is used for an example case for the demonstration of the proposed method. The independence of time consumption for the developed adjoint sensitivity analysis method to the number of optimized variables is demonstrated. For the test case, the developed algorithm shows the ability to make the design parameters converge with a precision of 10−6 by more than ten times faster for calculating the sensitivity than conventional optimization methods. Validation of the obtained optimal point is also included in the paper. For the validation, a response surface analysis is performed to visualize the pathway during the iteration for optimization. It is very challenging to carry out the optimization having the same precision using a brute force algorithm or a probability-based optimization algorithm since the number of variables to be optimized is substantial for this type of a problem. The smoothness of an optimal cycle efficiency variation is observed in every case.

With increasing demand for transparent conducting electrodes, graphene has attracted considerable attention, owing to its high electrical conductivity, high transmittance, low reflectance, flexibility, and tunable work function. Two faces of single-layer graphene are indistinguishable in its nature, and this idea has not been doubted even in multilayered graphene (MLG) because it is difficult to separately characterize the front (first-born) and the rear face (last-born) of MLG by using conventional analysis tools, such as Raman and ultraviolet spectroscopy, scanning probe microscopy, and sheet resistance. In this paper, we report the striking difference of the emission pattern and performance of transparent organic light-emitting diodes (OLEDs) depending on the adopted face of MLG and show the resolved chemical and physical states of both faces by using depth-selected absorption spectroscopy. Our results strongly support that the interface property between two different materials rules over the bulk property in the driving performance of OLEDs.

To meet the energy requirement for a remote and isolated region, a concept of supercritical CO 2 (S-CO 2 ) cooled micro modular reactor (MMR) has been developed, which is easy to transport by fully modularizing the nuclear power system. From the previous work, only the on-design performances of MMR were presented. However, since the nuclear system needs to meet high safety standard, the design can be finalized only after the evaluation of the nuclear system response under multiple transient conditions. Such transient conditions may include part load operation and postulated accidents. The system response can be evaluated only with a high fidelity computer simulation, since it is almost impossible to construct a nuclear facility to test at such conditions. The simulation is performed to guarantee its autonomous operability and safety. Unfortunately, a system analysis computer code available for the S-CO 2 cycle analysis is yet to be developed for the MMR safety evaluation. Description of a S-CO 2 system analysis code platform is first presented in this paper. After that, the developed code is validated with experimental data. The steady state of MMR is first modeled with the code, which is followed by simulations of part load operation and postulated accidents of MMR. All simulation results show that the current design of MMR has the ability to maintain its safety and structural integrity even under extreme conditions to protect the public from radiation hazard at all times.

This paper presents the neutronics and transient studies of a supercritical CO2-cooled micro modular reactor (MMR). The suggested MMR is an extremely compact, integrated, and truck-transportable reactor with 36.2 MWth power and a 20-year lifetime without refueling. A salient feature of the MMR is that all the components including the generator are contained in a small reactor vessel. For a minimum volume and maximum lifetime of the MMR core, a fast neutron spectrum is utilized. To improve the fuel-coolant compatibility and to maximize the fuel volume fraction, UC fuel is considered. A unique replaceable fixed absorber (RFA) is also introduced in order to maintain the excess reactivity at less than 1 dollar during the whole operational period. A drum-type reactivity control system is adopted in the MMR as the primary control system to prevent a control rod ejection accident and a single absorber rod located at the core center is used as the secondary ultimate shutdown system. The neutronics analysis is performed by using the continuous energy Monte Carlo code Serpent with the ENDF/B-VII.1 library. In addition, an unprotected loss of flow (ULOF) accident is simulated by the system analysis code GAMMA+ to show the passive safety of the MMR system.

In this paper, a thermodynamic study of newly suggested supercritical carbon dioxide (s-CO2) cycle layouts using an isothermal compressor is presented. The isothermal compressor is conceptually defined using the ‘infinitesimal approach’ in attempt to resolve the ambiguity in its performance framework. As part of preliminary investigation, the isothermal compressor is demonstrated thermodynamically, and the calculations highlight that it reduces the compression work significantly under s-CO2 power cycle operating conditions over other representative working fluids. The in-house code is modified to allow the analysis of three s-CO2 cycle layouts, simple recuperated Brayton cycle, recompression Brayton cycle, and partial heating Brayton cycle, adopting the isothermal compressor. The cycle performance is evaluated through a sensitivity analysis of cycle design parameters, pressure ratio and flow split ratio. When the machinery is applied, the cycle net efficiency of the simple recuperated cycle and the recompression cycle is improved by 0.5% point and 1–3% points, respectively. Moreover, the partial heating cycle layout, known for its outstanding performance in waste heat recovery applications as a bottoming cycle, produces 15–18% more net work when using an isothermal compressor, compared to the reference cycle. Overall, the use of the isothermal compressor not only improves the general cycle performance, but also provides another degree of freedom for cycle design optimization of s-CO2 cycles.

Although the number of meshes and their distribution are important parameters that affect both computation resources and the accuracy of the numerical results, meshing of most of all computational problems still depends highly on the users’ experiences. In this paper, a deterministic adjoint-based method of optimizing mesh distribution is proposed. The developed method is applied to a nuclear power plant safety analysis. The mesh optimization was performed with 1D steady state cylindrical nuclear fuel problem first. Radial and axial mesh distributions are optimized respectively. With no surprise, the optimized mesh system performs superior than the same number of uniformly meshed system. However, it was unexpected that the optimized mesh retains generality and therefore, the optimized mesh system can be still the best mesh system for given number of meshes under different condition or even during transient analysis. The authors applied the optimized mesh distribution to nuclear system safety analysis. A large pressurized water reactor cold leg guillotine break (LBLOCA) scenario was analyzed and the consequence of different mesh systems is investigated and discussed. From this preliminary study the usefulness and implication of the adjoint based mesh optimization method for the nuclear safety analysis is uncovered.

As the share of renewable energy will be increasing, there is a growing interest in flexible power sources and energy storage systems due to the intermittent nature of renewable energy. We propose the Energy Storage System (ESS) integrated Nuclear Power Plant (NPP) as a solution. The system operates on load-following by branching the mass flow from the steam cycle to the ESS without changing the reactor thermal output. However, the merging point can be different for heat storing ESS and work storing ESS because the outlet conditions of the ESS vary depending on the type of ESS. In this study, the merging points are categorized into two types, feedwater heater and condenser. At each merging point, cycle optimization is performed while increasing the branch flow into ESS. The optimization goal is to maintain the feedwater temperature at the inlet of a steam generator. The power output and energy delivered to the ESS according to the merging point are estimated. From this study, it was found that when 25% of the inlet mass flow rate to the low-pressure turbine is diverted to ESS, the overall output of the steam cycle is decreased by 44.17% for the heat conversion ESS and 49.95% for the work conversion ESS.

Recently, oxy-combustion cycles with CO2 dilution have been of interest to eliminate NOx emission and to facilitate CO2 capture. Theoretically, they are operated in an overall stoichiometric condition. In addition, high pressure is preferred not only for better thermal efficiency but also for easier CO2 capture and storage. In this study, a triple-coaxial-tube was selected as the simplest conceptual design for an oxy-combustion burner at elevated pressure. Flame stabilization, soot emissions, and combustion efficiencies were investigated in relation to variation of the tube size, CO2 dilution ratio, and pressure. As a result, a jet Reynolds number and CO2 diffusion could explain the flame stabilization limits. Soot emission could be reduced at atmospheric pressure when the fuel-tube tip was moved into the middle oxidant tube, which also improved the combustion efficiency. Nevertheless, serious soot emissions recurred at excessive fuel flow rates and at elevated pressures. In such conditions, a lifted flame detached from the fuel-tube tip could be employed by increasing the flow rate or enhancing the CO2 dilution, and the soot emission was reduced again without losing combustion efficiency. Finally, the flame-stabilization mechanisms of the attached flame and of the lifted flame were discussed and optimized designs and operating conditions were proposed for less soot emission and better combustion efficiency at higher pressures.

The four different geometries of a reactor vessel auxiliary cooling system (RVACS) are designed to investigate how the heat removal capability changes by the geometries. Each geometry has different heat transfer characteristics regarding airflow and the presence of an air separator and an insulation material. The heat removal performance is evaluated with the reactor vessel (RV) temperature, the RV wall emissivity, and the airflow gap. For the same RVACS volume, 600 °C RV temperature, and 6-cm gap, the heat removal capability varies from 240.8 kW to 308.5 kW, depending on the geometry. The wall emissivity is less effective for Geometry 2, which has a large cavity volume and a small heat transfer area compared to the other geometries. The highest heat removal performance was obtained using Geometry 3 because cold air flows in from the bottom of the RVACS, improving both radiative and convective heat transfer. Reducing the gap size by 3 cm results in only 80.0 kW of heat removal capability for Geometry 1, and the heat removal dramatically decreases to 0.2 kW at an RV temperature of 800 °C. A sufficient RVACS gap size of at least 6 cm with a 0.6-m diameter intake pipe is required to provide adequate natural circulation and eventually enhance the heat removal capability.

A Supercritical CO2 (S-CO2) power cycle is one of the next generation power conversion cycles, which has many advantages originate from unique fluid’s characteristics near the critical point. Recently, a concept of small modular nuclear reactor (SMR) coupled with an S-CO2 power cycle is proposed to target aggressively expanding SMR market. However, many components of S-CO2 power cycle were designed with the experiences from the conventional fluids such as air and water. In this paper, in order to harness the full potential of the S-CO2 power cycle by utilizing the fluid properties further, an S-CO2 compressor with different characteristics from air compressor is evaluated in the viewpoint of system level. The analyzed compressor has a larger backswept angle in the impeller than the conventional compressor and this can be done due to the unique properties of S-CO2. A 10 MW scale SMR is selected to demonstrate the compressor’s effect on the system performance and control. As a result, S-CO2 cycle with larger backswept angle compressor can be regulated by inventory control in a wider load variation because the system has low surging mass flow rate. Thus, the system with larger backswept angle compressor has 5.6% wider part-load performance range with inventory control alone than the system with conventional compressor.

In the event of a core meltdown in a high-power reactor, the integrity of the reactor pressure vessel is presumably protected by severe accident mitigation systems such as in-vessel retention external reactor vessel cooling (IVR-ERVC). However, in the late phase of the accident, two possible locations on the RPV are prone to failure: the location of the focusing effect and location of in-core instrument penetration. These two potential points of damage in the RPV are investigated in this study. A numerical model for the prediction of the natural convection, melting, and solidification processes for IVR-ERVC is presented. The model is based on the enthalpy-porosity approach with an extension for continuous liquid fraction function. The model is implemented in open-source field operation and manipulation (OpenFOAM) computational fluid dynamic code to produce a new solver which is based on the combination of conjugate heat transfer solver and buoyant-driven natural convection solver and the new solver is validated against the melting Gallium experimental test, in-core instrumentation failure experimental test, and BALI experimental test. This numerical model is applied for the investigation of the RPV rupture at the location of the focusing effect and in-core instrumentation penetrations. Severe ablations of the cladding and the weld materials are observed at a heat load of about ~1800 K which is expected to lead to the ejection of the penetration tubes if the force holding the penetration tube in place is lower than the force exerted by the system pressure. Subsequently, a two-layer IVR configuration is assessed and the integrity of the RPV is found not to be compromised under external reactor vessel cooling. However, in the case of a boiling crisis, the temperature of the ex-vessel wall is expected to rise quickly and this is simulated by increasing the ex-vessel wall temperature. The RPV is found to fail near the beltline due to a phenomenon known as focusing effect when the ex-vessel wall temperature rises above 1200 K.

In a sodium-cooled fast reactor, a sodium-water reaction (SWR) could be occurred at pressure boundaries between the two separated systems, the steam Rankine cycle and the sodium coolant system, which results in a serious problem in the system. Since it has been a design challenge for researchers, as an alternative system, the supercritical CO 2 (S-CO 2 ) Brayton cycle was suggested. To utilize the S-CO 2 Brayton cycle to a SFR, a series of studies on the coupled system have been conducted at Korea Atomic Energy Research Institute (KAERI). The studies were mainly focused on the pressure boundary failure events and their consequences including Na-CO 2 reactions. Prior to the experimental studies, the authors classified the reaction behaviors of Na-CO 2 reaction based on the possible scenarios that could take place at pressure boundaries. Through experimental studies, it was found that the reaction follows typical chemical formulas and it is essentially dependent on the reaction temperature. More importantly, the reaction rate changed drastically at the specific temperatures and the reaction became flammable exceeding a certain temperature. To specify the design conditions of the SFR system coupled with the S-CO 2 Brayton cycle, by means of a dedicated set-up the self-ignition temperature has been evaluated. Exceeding this threshold temperature a significant increase in the reaction speed is observed. We setup an experimental apparatus and a test matrix based on one of possible scenarios where the flammable Na-CO 2 reaction takes place and we installed a visualized chemical reactor to watch reaction phenomenon around the self-ignition temperature. The experimental apparatus was designed to be easy to control heaters, to regulate gas supply, and to measure reaction temperature. Through the experiment, it was found that the flammable temperature of Na-CO 2 reaction lies between 598.3˚C and 599.9˚C and how liquid sodium reacts with gaseous carbon dioxide at these temperatures. The results will be help to set design criteria for the pressure boundary and it will take long time but an appropriate safety system would be introduced.

A structural model for stress distributions of coated Zircaloy subjected to realistic incore pressure difference, thermal expansion, irradiation-induced axial growth, and creep has been developed in this study. In normal operation, the structural integrity of coating layers is anticipated to be significantly challenged with increasing burnup. Strain mismatch between the zircaloy and the coated layer, due to their different irradiation-induced axial growth, and creep deformation are found to be the most dominant causes of stress. This study suggests that the compatibility of the high temperature irradiation-induced strains (axial growth and creep) between zircaloy and the coating layer and the capability to undergo plastic strain should be taken as key metrics, along with the traditional focus on chemical protectiveness.

Organic wrinkle structures are investigated as an internal scattering layer for the fabrication of highly efficient organic light-emitting diodes (OLEDs). The solution-processed wrinkle structures are planarized with a high-index layer, resulting in a reduced surface roughness and optical haze simultaneously. The OLED device including the wrinkle structures achieved external quantum efficiency (EQE) of 24.2%, corresponding to a 1.24 time enhancement with respect to that of a control device having no internal scattering layer. By attaching a micro lens array (MLA) or a half ball lens (HBL) on the external surface of the substrate, the proposed device exhibits an EQE of 30.5% (1.56 time enhancement) and 41.8% (2.14 time enhancement), respectively. Randomness of the distributed wrinkle structures is shown to provide additional benefits of reduced angular spectral distortion and Lambertian-like emission properties. Trans-scale optical simulation combining wave-optics and the geometrical effect are used for the quantitative analysis of the emission characteristics of the device.

Spontaneously wrinkled films can be easily obtained from UV-crosslinkable liquid prepolymers under special UV-curing conditions. They vary wrinkle structures of the UV-cured films and, however, cannot be precisely controlled. Here, five different UV-crosslinkable prepolymers are synthesized to study the chemical structure effect of prepolymers on wrinkle formation and modulation of the UV-cured films irrespective of the UV-curing conditions. Both wavelength and amplitude of the wrinkles are tuned with the different liquid prepolymers from 4.10 to 5.63 µm and from 1.00 to 1.66 µm, respectively. The wrinkle structures of the UV-cured films are faded by adding a solid prepolymer to a liquid prepolymer due to interference from it in the shrinkage of the liquid prepolymer layer. The wrinkles completely disappear in the UV-cured films fabricated from the formulated prepolymers containing over 50 wt% of the solid prepolymer.

Various research organizations have performed feasibility studies for applying the supercritical CO2 (S-CO2) Brayton cycle to the Sodium-cooled Fast Reactor (SFR) system and the studies revealed several technical challenges. The preceding studies are reviewed to identify the current status of overcoming the identified challenges and highlight knowledge gaps. One of the most challenging issues is to comprehend the CO2 leak mechanism initiated from the pressure boundary failure in a Na-CO2 heat exchanger. Thus, an isentropic critical flow model expanding from supercritical phase to gas phase was evaluated. To validate the selected critical flow model, an experiment of CO2 critical flow under supercritical condition was performed and the experimental and numerical results correspond to each other reasonably. Another identified technical issue is removing Na-CO2 reaction product from the system to improve the system economics and plant availability. In this study, candidates that can form eutectic with Na-CO2 reaction product was newly identified. As a result, it was found that Li2CO3-Na2CO3 or Li2CO3-Na2CO3-K2CO3 eutectic systems can act as a potential cleaning agent to eliminate Na-CO2 reaction product within the operating temperature range of SFR. The performance was confirmed with simple experiments.

To realize transparent organic light-emitting diodes (OLEDs), a top electrode should have excellent optical, electrical, and mechanical properties. Conventionally, transparent conductive oxides and semitransparent metal have been widely used for transparent top electrodes, but they have several fundamental drawbacks. We herein report efficient large-area inverted transparent OLEDs using a vacuum-laminated top electrode with an embedded metal mesh. The laminated device with 1 mm pitch exhibits superior optical properties including a high transmittance of 75.9% at 550 nm, a low reflectance of 12.0% at 550 nm, and spectrally flat characteristics over the entire visible region and shows nearly ideal Lambertian angular emission characteristics with little angular color shift in both directions. Moreover, the lowered sheet resistance of 4 Ω/sq originating from the embedded metal mesh (1 mm pitch) led to efficient and uniform emission characteristics. As a result, the device shows a relatively high maximum curre...

The supercritical CO 2 (S-CO 2 ) power cycle is receiving worldwide attention as one of the promising advanced future electricity generation technologies. Since the S-CO 2 power cycle can achieve high efficiency with simple system configuration, the role of compact heat exchanger becomes more important to achieve smaller system footprint. As an example of successful compact heat exchanger, the printed circuit heat exchanger (PCHE) was recently suggested for the S-CO 2 power cycle application due to the capability of enduring high pressure difference while providing large heat transfer area within a small volume. However, the S-CO 2 precooler operates very close to the critical point of CO 2 where the conventional design methodology may not be suitable due to substantial variation of the thermo-physical properties near the critical point. Thus, in this paper the design and operation issues of PCHE as the precooler are addressed. In this study, the verification of developed PCHE core design code and experimental test results are presented. The test conditions were 26–43 °C and 7.3–8.6 MPa in temperature and pressure, respectively. In terms of non-dimensional numbers, the Reynolds number range is 15,000–100,000 and the Prandtl number range is 2–33. Friction factor and heat transfer correlations were developed with the experimental data and computational analysis for the future PCHE design as a precooler in the S-CO 2 power cycle.

We have developed down-conversion outcoupling films to enhance the light outcoupling efficiency in white organic light-emitting diodes (OLEDs). The down-conversion outcoupling films consist of outcoupling structures and color conversion materials, which are prepared by a simple solution-based micro-imprint process and are adopted into OLEDs. The down-conversion films successfully realize white light by converting blue rays from blue phosphorescent OLED. The OLEDs based on the down-conversion films with outcoupling structures show a great improvement of power efficiency by a factor of 1.32 compared to the reference OLED based on down-conversion films without outcoupling structures. Furthermore, the influence of a concentration of color conversion materials on color rendering index of OLEDs is investigated. The results strongly indicate that readily fabricated down-conversion light outcoupling films by a simple micro-imprint process are highly promising for enhanced light extraction performance and high color rendering index of white OLEDs.

A parametric study that demonstrates a methodology for determining the optimum bilayer composition in a duplex SiC cladding is discussed. The structural performance of multi-layer SiC cladding design is significantly affected by radial thickness fraction of each layer. This study shows that there exists an optimal composite/monolith radial thickness fraction that minimizes failure probability for a duplex SiC cladding in steady-state operation. An exemplary reference case study shows that the duplex cladding with the inner composite fraction ∼0.4 and the outer CVD-SiC fraction ∼0.6 is found to be the optimal SiC cladding design for the current PWRs with the reference material choice for CVD-SiC and fiber reinforced composite. A marginal increase in the composite fraction from the presented optimal designs may lead to increase structural integrity by introducing some unquantified merits such as increasing damage tolerance. The major factors that affect the optimum cladding designs are temperature gradients and internal gas pressure. Clad wall thickness, thermal conductivity, and Weibull modulus are among the key design parameters/material properties.

As potential lighting-emitting devices, electrochemiluminescence (ECL) devices are promising in terms of device structure and fabrication and involve low processing cost compared to organic light-emitting devices (OLEDs). Herein, liquid electrolyte-based multi-colored ECL devices (ECLDs) were prepared with organic materials dissolved in electrolyte solution, which generated red, yellow, green, and blue emissions under an applied square-wave AC bias voltage. Among the four different emissive colors, yellow showed a strong and stable emission, which enabled quantitative measurements, including a luminance of 12 cd m−2 at 4.5 V.

In this paper, a new light-adaptable display (LAD) structure with minimum power consumption is proposed for the future advertising service, and the demonstrated results are reported. An organic light-emitting diode with color reflection (colored OLED) was applied for the reflective- and emissive-mode device, and a guest-host liquid-crystal device (GH-LC) was adopted for the light shutter device. The current efficiency and reflectance of the colored OLED were 35.15 cd/A at 457 cd/m2 luminance and 63% for the yellow color, respectively. The measured contrast ratio of GH-LC was 15.5:1 at dark-room conditions, respectively. Transparent oxide thin-film transistors were used for the backplane, and their average mobility was 9.08 cm2/V s, with a 0.5 standard deviation. Through the optimization of the fabrication process and the structures of each device, the LAD adaptively operating according to the environmental illuminance from dark to 10,000 nits was successfully demonstrated. Moreover, a new LAD driv...

To overcome the degradation of the cycle efficiency of a supercritical carbon dioxide (S-CO2) Brayton cycle with dry cooling, this study proposes an improved design of an S-CO2 centrifugal compressor. The conventional air centrifugal compressor can achieve higher efficiency as backsweep angle increases. However, the structural issue restricts the maximum allowable angle (&minus, 50~&minus, 56&deg, ). In this study, an S-CO2 centrifugal compressor performance was examined while changing the backward sweep angle at impeller exit to study if the previous optimum backsweep angle for an air centrifugal compressor is still valid when the fluid has changed. It is shown through an analysis that an S-CO2 centrifugal compressor can achieve the highest efficiency at &minus, 70&deg, backsweep angle, which is greater than the typical design value. The S-CO2 centrifugal compressor is less restricted from a structural integrity issue because it has low relative Mach number regardless of the low sound speed near critical point (Tc = 304.11 K, Pc = 7377 kPa). It is also shown in the paper that the variation of compressibility factor does not impact on its total to total efficiency since its Mach number is still lower than unity. Finally, it is also shown that a backward sweep impeller can achieve higher pressure ratio and operate stably in wider range as the mass flow rate is decreased. As further works, the suggested concept will be validated by the structural analysis and the compressor performance test.

This study explores heat transfer behaviour in mixed convection of a fluid with internal heat generation, a situation found in chemical and nuclear engineering contexts. Computational fluid dynamics is used to simulate laminar ascending mixed convection flow of a heat-generating fluid in a vertical cylinder with uniformly cooled wall, based on a liquid nuclear fuel concept. A new non-dimensional parameter, the IHG-flux number Ω , is developed to express the balance of axial convection versus radial conduction heat transfer. It was found that heat transfer behaviour depends on this parameter, and it can be used as the transition criterion to categorise the simulated results into three distinct heat transfer regimes. A heat transfer correlation using Ω was also developed for Regime I with small values of Ω , where convection and conduction effects are balanced in a stable flow. In Regime II at intermediate Ω , stronger convection gives rise to flow instability. In Regime III with large Ω , convection dominates and the temperature profile inverts so that the maximum temperature occurs at the wall, while instability remains likely.

Passive cooling has become an important factor in safety of nuclear reactors. Many ideas were proposed for the passive cooling of the containment but most are limited in application on existing power plants. A passive containment cooling system using PCM (Phase Change Material) is introduced in this study. Among various PCMs, one organic PCM is selected based on melting temperature and volumetric heat capacity. The cooling capability of the PCM condenser with the selected material was analyzed using CAP code. It showed that even without the active spray system, the PCM condenser can successfully cool the containment under certain conditions. Experiments were performed to test the actual heat transfer performance of the condenser. Results showed that even with simple design of heat exchanger as implemented in the experiment, the PCM condenser can successfully cool the containment for a Loss Of Coolant Accident.

Due to the lack of test data of a supercritical CO2 compressor operating under supercritical CO2 conditions, the work of loss model validation for supercritical CO2 compressor could not be conducted successfully before. Therefore, as the first step, this study gathers the existing accessible experiment data as much as possible while conducting additional supercritical CO2 compressor performance experiments to validate the loss models for the supercritical CO2 compressor. To evaluate the reliability of test results, the measurement uncertainty is estimated from the experiment data. Then, three different combinations of loss models based on the mean streamline method are compared with six available experimental cases to find the most suitable combination of loss models for the supercritical CO2 compressor design and analysis. The combination of loss models proposed by Lee was found to predict pressure ratio and isentropic efficiency of supercritical CO2 compressors operating both on-design and off-design conditions successfully. It is expected that the set of loss models presented herein can be utilized as a conceptual design tool in the preliminary design stage of supercritical CO2 compressors.

As more supercritical CO2 (S-CO2) power systems are operating around the world, long term operability and reliability of the system will become salient issues in the near future. In this research, the performance degradation of an S-CO2 compressor is investigated experimentally, and degradation models are developed to explain the performance degradation of the S-CO2 compressor at first. The investigated degradation is damaged on the impeller caused by foreign object approximately 3 mm size. The damage caused the shape change of the impeller. From the comparison of the performances of the damaged impeller to the intact impeller, it is confirmed that the performance degradation does not affect the surge margin. The correction model for the degradation of gas compressor performances has a limitation when the pressure ratio was used for measuring the performance. However, it is also shown that the correction model works well if the enthalpy rise is utilized instead of the pressure ratio. This study experimentally shows the possibility that the performance degradation of the S-CO2 compressor can be modeled through a linear model based on enthalpy. Further research is needed to validate the model for wider operating conditions and more severe degraded conditions.