Search

In this work, an InGaN/GaN multiple quantum well based Top-Hat Hot-Electron Light Emission and Lasing in a Semiconductor Heterostructure (Top-Hat HELLISH) is investigated. A heterojunction structure is designed based on an active InGaN quantum well placed in the n-type GaN region sandwiched by the n-and p-type GaN layers. The four quantum well structure of an InGaN/GaN heterojunction where the Indium ratio is 0.16 has been grown via Metal-Organic Chemical Vapor Deposition. In order to create an anisotropic potential distribution of the heterojunction, it is aimed to fabricate TH-HELLISH-GaN device in Top-Hat HELLISH (THH) geometry for four contacts with separate n-and p-channels. High-speed I-V measurements of the device reveal an Ohmic characteristic at both polarities of the applied voltage. Integrated EL measurements reveal the threshold of the applied electric field at around 0.25 kV/cm. The emission wavelength of the device is around 440 +/- 1 nm at room temperature. (c) 2021 Elsevier B.V. All rights reserved.

Background: The electrical and optical properties of nanoparticle-based devices depend on the shape, dimension and uniformity of these particles. Methods: In this work, we fabricated ordered Au nanodots using electron beam lithography and thermal evaporation. Au nanodot diameter and circularity varied with a changed exposure dose and resist thickness. Electron beam dose ranged from 5 fC to 200 fC for single dot patterns. Commonly used PMMA thin films of thicknesses 60 nm and 100 nm coated samples were used for investigating the resist thickness dependency with varying dose exposure. Results: The analyses of patterns show that the diameter and circularity of the Au nanodots ranged from smaller to larger diameters and from lower to higher circularities with increasing dose and resist thickness. Conclusion: The distributions of the nanodot diameter began to show Gaussian behavior at larger electron doses. Besides, single circularity value became dominant up to the medium doses and then a homogeneous distribution was observed with the increasing dose.

Pure GaAs and GaAs1−xBix alloys with different Bi ratios (1 %, 2.5 %, 3.5 %) fitted with silver contacts were measured with a dielectric spectroscopy device. Dielectric characterization was performed at room temperature in the frequency range of 0.1 Hz to 1 MHz. GaAs exhibits three relaxation regions corresponding to space-charge, dipolar and ionic polarizations in sequence with increasing frequency while GaAs1−xBix samples show only a broad dipolar polarization in the same frequency range. This result proves the filling of the lattice with Bi through making a new bonding reducing the influence of ionic polarization. This finding supports the previous results concerning optical properties of GaAs1−xBix, presented in the literature.

The band line-up and band offset calculations of GaAs0.978Bi0.022/GaAs single quantum well with spatial changes of Bi composition were reported. The spatial Bi profile and a certain amount of the Bi composition in the barrier layer were determined by HR-XRD measurements. Virtual Crystal Approximation and Valence Band Anti-Crossing models were used including strain effects to obtain conduction and valence band edge shifts with Bi incorporation. Photoluminescence (PL) measurements were performed at a low temperature of 8 K as a function of excitation intensity. The PL spectra have shown asymmetric line shapes, which were fitted with different Gaussian functions. Comparing experimental PL results with calculated band edge energies, it was found that optical transition is a type I under low intensity excitation while the optical transition is switched from type I to type II due to the spatial changes in Bi concentrations. The band offsets Δ E c / Δ E v were also determined.

An anisotropic etching of 1 eV Ga0.92In0.08N0.03As0.97 grown on (100) p-type GaAs substrate was investigated. Effects of the V-groove etching profile and metallization on the photovoltaic performance of the GaInNAs nipi solar cell with five periods are presented. Experimental results were supported by simulation studies considering the metal–semiconductor junction characteristics in the electrodes of nipi photovoltaic device. Standard wet etching processes at room temperature is applied using sulfuric acid based H2SO4: H2O2: H2O [1:8:8] solution to form the V-groove shape on the nipi sample. The etching characteristics in the [100] and $$\left\langle {011} \right\rangle$$ crystal directions are determined by using an interdigitated square spiral photolithographic mask. The scanning electron microscope (SEM) is used to analyze the V-groove etch profile. Two type of V-grooves achieved, one of them is in the $$\left[ {1\bar{1}1} \right]$$ direction and suitable to form metal electrodes for nipi layers and the second one is in $$\left[ {\bar{1}11} \right]$$ direction can be called a dovetail groove and not suitable for metal coating. Experimentally, the improvements observed in the short circuit current, open circuit voltage, and efficiency of the device despite some metallization failures. The effect of the metallization quality on the response to the spectrum can be clearly seen from the photovoltage spectrum. Essentially, these experimental results show that GaInNAs nipi devices have the potential to become high efficiency solar cells. Moreover, it can be possible to achieve high performance by integrating nipi devices into multijunction solar cells.

OBJECTIVES This study aimed to analyze and compare the topographical, chemical, and osseointegration characteristics of a sandblasted acid-etched surface (SLA group), a sandblasted thermally oxidized surface (SO group), and a surface chemically modified by hydrofluoric (HF) acid (SOF group). MATERIALS AND METHODS Following the preparation and characterization of the relevant surfaces, 90 implants (30 for each group) were placed on the pelvic bone of six sheep. Resonance frequency analysis (RFA), insertion (ITV), removal torque value (RTV), and histomorphometric analyses (BIC%) were performed after three and 8 weeks of healing. The results were analyzed by nonparametric tests (p

In this work, optical properties of n- and p-type modulation doped GaAsBi/AlGaAs single quantum well (QW) heterostructures are investigated via temperature-and excitation power-dependent photoluminescence (PL) and integrated photoluminescence (IPL) studies and the results are compared to the nand p-type GaAs/AlGaAs QW structures to determine the influence of Bi and doping type on the optical properties. The results of the temperature dependent PL peak energy reveal that, as an effect of doping type, the temperature dependence of the PL peak energy exhibit different characteristic for n-and p-type samples. The temperature dependence of the PL peak energy reveals S-shaped trend for the n-type GaAsBi/AlGaAs QW sample. On the other hand, the characteristic follows Varshni law for the p-type GaAsBi/AlGaAs QW sample. The observed S-shaped behaviour for the n-type sample is explained by considering the contribution of the Bi-induced states above valence band (VB) to the PL. As for p-type sample, the localised states-related contribution to the PL signal is drastically diminished, resulting in an almost S-shape free temperature dependence of the optical transition energy, which can be explained by the compensation of acceptor-like states. The observed PL spectra of n-and p-type samples successfully reconstructed by two Gaussian peaks, which are assigned to optical transitions due to recombination of free and localised excitons. The localised exciton-related peak is observed to be very weak in p-type sample compared to that in n-type one. The allowed transitions in GaAsBi QW is calculated by selfconsistently solving the Schr_odinger-Poisson equation to identify the origin of the observed transitions. A comparison of the PL results of the Bi-containing samples with the results of the Bi-free ones is exhibited approximately 80 meV/Bi% decrease in the fundamental optical transition. Using the excitation-dependent IPL measurements, it is found that at low temperatures and under low excitations, recombination process is under the effect of Shockley-Read-Hall (SRH) non-radiative process. When the excitation power density increases, radiative recombination becomes dominant. At higher-temperatures and in the high-intensity regime, we observed Auger effect in recombination process for n-and p-type GaAsBi samples, but the effect of Auger loss is observed to be much less in the p-type GaAsBi sample due to enhanced spin orbit split-off energy as a result of incorporation of bismuth. Furthermore, when we compare the result for Bi-free and Bi-containing p-type samples, again, Auger recombination is found to be less effective for the Bi-containing sample. (C) 2017 Elsevier B.V. All rights reserved.

We have studied the temperature-dependent optical absorption and emission mechanisms of ternary chalcogenide TlSbS2 by carrying out sandwich and planar photoconductivity, and photoluminescence measurements in the temperature range 30 K to 300 K. Two main transitions were observed in the room temperature photoconductivity spectrum at energies of 1.74 and 1.84 eV, which are attributed to a native acceptor–donor transition and a band-to-band transition, respectively. A spectral anisotropy near the bandgap energy of TlSbS2 is observed between the sandwich and in-plane photoconductivity spectrum. In the photoluminescence spectrum, we observed deep-level broadband emission which is correlated with the native defect-related transition-based free-to-bound recombination between 30 K and 70 K. The Debye temperature of TlSbS2 was found to be 280 K, and the thermal expansion coefficient was determined as 1.62 × 10 - 3 e V / K from the analyses of its temperature-dependent photoconductivity spectra.

Poly (3,4-ethylenedioxythiophene)-poly (styrene sulfonate (PEDOT:PSS) is a widely-known conductive polymer mixture that is mostly engaged as a hole transport layer (HTL) in organic and perovskite solar cells (PSCs). In this study, it has been demonstrated that the use of Zn as an additive in PEDOT:PSS solution improved the photovoltaic performance of the ambient air solution-based fabrication of methylammonium lead tri-iodide (MAPbI3) based devices. The short circuit current density (JSC) of the device increased from 15.4 to 17.2 mA/cm2, while the fill factor (FF) improved from 0.70 to 0.83 by using Zn-doped PEDOT:PSS as a hole transport layer (HTL), which is a record value for only γ-butyrolactone (GBL) based MAPbI3 PSCs. Additionally, open-circuit (VOC) value is boosted up from 890 to 925 mV by Zn-doping, which might be linked to the increased work function of the investigated HTLs. Moreover, the synergetic effect of improved electrical conductivity and hole mobility of PEDOT:PSS film and decreased the trap density of perovskite led to an increase of 37% in power conversion efficiency (PCE) and the stability of the inverted planar PSCs.

The temporal response characteristics of a GaInNAs-based vertical resonant cavity enhanced photodetector device are presented for operation at λ ≈ 1.3 μm. The absorption layers of the device are composed of nine 7-nm-thick Ga0.65In0.35N0.02As0.98 quantum wells and are sandwiched between top and bottom AlGaAs/GaAs distributed Bragg reflectors (DBRs). The temperature dependence of the transient photoconductivity (TPC) under different light intensities and bias voltages is reported. Photoluminescence measurements were also performed on structures with and without the top DBR to determine their optical response under continuous illumination. The response time was measured using excitation from a 1047-nm pulsed neodymium-doped yttrium lithium fluoride laser with pulse width of 500 ps and repetition rate of 1 kHz. The rise time of the TPC was 2.27 ns at T = 50 K, decreasing to 1.79 ns at T = 300 K. The TPC decay time was 25.44 ns at T = 50 K, decreasing to 16.58 ns at T = 300 K. With detectivity of $$ 2.28 \times 10^{10} \,{\hbox{cm}}\sqrt {\hbox{Hz}} / {\hbox{W}} $$ and noise-equivalent power of $$ 2.45 \times 10^{ - 11} \,{\hbox{W/}}\sqrt {\hbox{Hz}} $$ , the proposed device is faster and more sensitive with better signal-to-noise ratio compared with other GaInNAs-based resonant cavity enhanced photodetectors (RCEPDs) for operation at 1.3 μm.

We study structural properties and surface formation of undoped, n- and p-type doped GaAsBi alloys with various bismuth compositions using Micro-Raman, Fourier Transform (FT) Raman, Photoluminescence (PL) and Atomic Force Microscopy (AFM) techniques. PL is used to determine the suitable excitation source for Raman measurements and evaluate the Raman spectroscopy results. Room temperature PL results reveal that the bandgap energy of GaAsBi decreases with increasing bismuth composition at a rate of 82meV/%Bi. In micro-Raman spectra recorded using 532 nm laser line, a peak at around 185 cm(-1) and a broad peak located between 210 and 250 cm(-1) are observed. The absence of these peaks in the Raman spectrum of low temperature (LT) growth GaAs indicates that those peaks are bismuth-induced vibrations. Besides, the forbidden transverse optical (TO) mode (269 cm(-1)) becomes more pronounced for the samples as bismuth composition increases. FT-Raman spectra taken by 1064 nm laser line of the n- and p-type samples exhibit different characteristics; while TO and longitudinal optical (LO) peaks (291 cm(-1)) are present in n-type sample as sharp vibrational peaks, a broad peak located at slightly lower wavenumber than TO mode appears and LO peak is suppressed. The ionised acceptor and free hole system respond incident electromagnetic field as plasma oscillations. Moreover, the amplitude of the plasma oscillations enhances with higher doping density. Therefore, the appearance of the broad peak in FT-Raman spectrum of p-type GaAsBi is explained with an LO-plasmon coupling (LOPC). As for n-type samples, free electrons are compensated by free holes in GaAsBi that originate from Bi-induced acceptor-like defects. Therefore, we do not observe the effects of plasma oscillations in FT-Raman spectrum. AFM results reveal that all samples have surface droplets, and the size of the droplets is not affected from doping density or doping type, but bismuth composition. The surface droplets are removed by a chemical process to investigate the effect of the droplets on Raman spectrum. Our results reveal that removing surface droplets does not change the characteristic of Raman spectrum, but enhances the Raman intensity due to the reflected light by droplets decreases, leading to more photons penetrate and scattered from inside the sample. (C) 2017 Elsevier B.V. All rights reserved.

We report the characteristics of the temperature dependent operation of a GaInNAs-based resonant-cavity-enhanced photodetector (RCEPD), designed to be operated at the dispersion minimum optical communication window of 1.3 μm. A Transfer-Matrix Method (TMM) was used to design the structure of the device. The absorption layer of the photodetector is comprised of nine 7 nm-thick Ga 0.733 In 0.267 N 0.025 As 0.975 (Sb)/ GaN 0.035 As 0.965 quantum wells, and 15 and 10 pairs of GaAs/AlAs distributed Bragg reflectors (DBRs) grown as the bottom and top mirrors, to form the cavity of the device. All electrical and optical measurements were carried out over a temperature range from 10 to 40 °C in order to investigate the characteristic of the device. The quantum efficiency is determined to be in the range of 16% (at 10 °C) and 31% (at 40 °C). An excellent wavelength selectivity is observed which changed from 3.7 nm (at 10 °C) to 5.4 nm (at 40 °C). The dark current of the device is measured as 11 nA at 10 °C and 19 nA at 40 °C without bias. The photocurrent at −0.5 V is measured to be 1.5 mA at 25 °C. The high dark current of the device is attributed to weak confinement of the electrons in GaInNAs QW surrounded by the strain-compensator GaNAs barrier layers. The temperature dependent cavity wavelength was analytically calculated and compared with that of experimental results. The temperature dependent linear shifts of the resonance wavelength ( d λ / d T ) is calculated as 0.077 nm/°C, which is in good agreement with the experimental result, 0.080 nm/°C. Our results reveal that the characteristics of a RCEPD, such as quantum efficiency, FWHM etc., are quite sensitive to temperature changes due to the temperature dependence of the refractive index of the DBRs.

Effect of thermal annealing on quantum transport properties have been investigated on as-grown and annealed n-type modulation doped GaInNAs/GaAs quantum well (QW) structures with various nitrogen concentration in low (B

We report on the power loss mechanisms of hot carries in as-grown and annealed n- and p-type modulation-doped GaAs/Ga0.68In0.32NyAs1-y (y = 0.009, and 0.012) quantum well structures considering acoustic phonon interactions via the deformation potential (non-polar) and piezoelectric (polar) scatterings. By analysis of the applied electric field dependent amplitude of the Shubnikov de Haas oscillations, it has been revealed that incorporation of N atom into Ga0.68In0.32As switches the dominant power loss mechanism from non-polar to polar mechanism. The piezoelectricity of n- and p-type Ga0.68In0.32NyAs1-y alloys is at least three times higher than N-free samples. A comparison between as-grown n- and p-type samples depicts that the p-type sample's piezoelectricity is higher than that of n-type samples. After thermal annealing, there is a slight decrement and increment in piezoelectric stress constant for n-type the sample with 0.9% and 1.2% N, respectively.

Hot electrons relax by interacting with phonons, so information about the electron-phonon interaction mechanisms are obtained by examining the cooling processes of hot electrons. In this study, the effect of annealing time on the electron temperature and energy relaxation rates in as-grown and annealed n-type modulation-doped Ga0.68In0.32N0.017As0.983/GaAs quantum well (QW) samples were investigated by comparing the relative amplitudes of Shubnikov-de Haas oscillations as a function of temperature and electric field. The samples were grown by molecular beam epitaxy (MBE) and annealed at 700 °C for 60 s and 600 s. Experiments were carried out by applying an electric field between 0.165 and 5.276 kV/m at a temperature range between 1.8 and 40 K under magnetic up to 11 T. The energy-relaxation mechanism is found to be a mixing of piezoelectric and deformation potential scatterings of hot electrons in the low-temperature regime up to 40 K electron temperature. The electron power loss by interacting with phonons is characterized with exponential term γ, which is found to be in the range from 3.42 to 4.97. The change of γ showed that the scattering mechanisms are affected by the annealing time. The piezoelectric stress constant (e14) chosen as a fit parameter in the theoretical power loss calculations, which was found between 0.129 and 0.134. The crystal quality at low temperatures has been observed to be effective on energy relaxation times.

We report on the power loss mechanisms of hot electrons in as-grown and annealed n-type modulation-doped Al0.15Ga0.85As/GaAs1-xBix (x = 0 and 0.04) quantum well structures considering acoustic phonon interactions via the deformation potential (non-polar) and piezoelectric (polar) scatterings. The two-dimensional (2D) electron gas is heated by applying various electric fields under a steady-state magnetic field, and the effect of the applied electric field on the Shubnikov de Haas (SdH) oscillations is analyzed to investigate the power loss mechanism. The temperature of hot electrons (T e) has been obtained by comparing the lattice temperature and applied electric field dependencies of the SdH oscillation amplitude. The hot electron temperature is almost the same for both Bi-free and Bi-containing samples except for the sample annealed at a higher temperature (700 °C) than the growth temperature of GaAsBi. The electron temperature dependence of power loss is analyzed using current theoretical analytic models derived for 2D semiconductors. We find that energy relaxation occurs in the intermediate temperature regime, including mixing of piezoelectric and deformation potential scattering. The power loss of hot electrons is found to be proportional to (Teγ-TLγ) with γ in the range from 2.4 to 4.2, which indicates that the hot electron relaxation is due to acoustic phonon scatterings via unscreened deformation potential and piezoelectric scattering. It is found that deformation potential scattering is dominant over piezoelectric scattering in the Bi-free sample, while the incorporation of Bi into the GaAs lattice makes these processes comparable. After thermal annealing at lower than growth temperature (350 °C), the scattering mechanism switches from deformation potential to piezoelectric scattering. After thermal annealing at higher than growth temperature (700 °C), the theoretical model does not fit to the experimental results due to degradation of the sample. acceptedVersion

A non-volatile floating gate memory device containing well-ordered Au nanoparticles (NPs) is fabricated as a metal-oxide-semiconductor capacitor structure. With superior control on the size, shape and position of nanoparticles, the presented nano-floating gate memory (NFGM) device possesses almost perfect precision of device geometry. The well-ordered Au NPs embedded within the memory device exhibit large memory window at low operation voltages (8.8V @ ± 15V), fast operation time (

Resonant cavity LEDs (RCLEDs) are a viable and low-cost alternative light source to lasers for optical communication systems in the 1.3 µm O-band. Most work in this area has been conducted on InP-based material, which is inherently costly, devices often require cooling and the refractive index contrast for constructing mirrors is low. Here, we demonstrate a high-performance GaAs-based RCLED using a dilute nitride GaInNAs active layer emitting in the 1.3 μm wavelength window. While previous 1.3 µm RCLEDs have used metallic mirrors on the back of the device, we exploit the high refractive index contrast of the GaAs/AlAs system to place Distributed Bragg mirrors on both sides of the active layer and achieve superior performance. The external quantum efficiency of the devices is 20% and the full width at half maximum of the emission spectrum is 5.2 nm at room temperature, into a narrow angular cone. The emission power from an 88 μm diameter aperture is 0.5 mW, which, together with the narrow spectral linewidth, makes the device suitable for deployment in a coarse Wavelength Division Multiplexing (WDM) communications system.

Simulated and experimental properties of a Ga(1-x)In(x)As(1-y)N(y)nipi solar cell involving V-grooves for contact formation are reported. In particular, using a drift-diffusion model, we simulate the conversion efficiency, the short-circuit current density (J(SC)), and the open-circuit voltage (V-OC) as a function of the number of nipi junctions. Based on the modelling results, optimized nipi solar cell incorporating five n-p junction pairs was grown on a p-type GaAs (100) substrate using molecular beam epitaxy (MBE). The bandgap of the nipi structure was determined to be 1eV. The metal contacts of the nipi solar cell structure were processed in the form of mesa and V-groove. These shapes enable both vertical and horizontal carrier transport within the solar cell. The effect of thermal annealing on J-V characteristics of both type of devices is finally assessed. The results point out that the V-groove sample has better photovoltaic characteristics than the mesa structure sample.

In this work, the electronic bandstructure of GaAs 1-x Bi x /GaAs single quantum well (QW) samples grown by molecular beam epitaxy is investigated by photomodulated reflectance (PR) measurements as a function of Bi content (0.0065 ? x ? 0.0215) and substrate orientation. The Bi composition is determined via simulation of high-resolution x-ray diffraction measurement and is found to be maximized in the 2.15%Bi and 2.1%Bi samples grown on (100) and (311)B GaAs substrates. However, the simulations indicate that the Bi composition is not only limited in the GaAsBi QW layer but extends out of the GaAsBi QW towards the GaAs barrier and forms a GaAsBi epilayer. PR spectra are fitted with the third derivative function form (TDFF) to identify the optical transition energies. We analyze the TDFF results by considering strain-induced modification on the conduction band (CB) and splitting of the valence band (VB) due to its interaction with the localized Bi level and VB interaction. The PR measurements confirm the existence of a GaAsBi epilayer via observed optical transitions that belong to GaAsBi layers with various Bi compositions. It is found that both Bi composition and substrate orientation have strong effects on the PR signal. Comparison between TDFF and calculated optical transition energies provides a bandgap reduction of 92 meV/%Bi and 36 meV/%Bi and an interaction strength of the isolated Bi atoms with host GaAs valence band (C BiM ) of 1.7 eV and 0.9 eV for (100) and (311)B GaAs substrates, respectively. © 2018 IOP Publishing Ltd. Fundação de Amparo à Pesquisa do Estado de São Paulo: 14/ 50513-7, 16/10668-7 Firat University Scientific Research Projects Management Unit: FYD-2016-20128, ONAP-52321 115F063 Academy of Finland: 259111 695116 European Research Council This work was partially supported by the Scientific Research Projects Coordination Unit of Istanbul University (ONAP-52321 and FYD-2016-20128) and supported by The Scientific and Technical Research Council of Turkey (TUBITAK) under Grant No. 115F063. YGG acknowledges the financial support from FAPESP ( grants numbers 16/10668-7 and 14/ 50513-7). JP, JH and MC acknowledge the financial support from European Research Council (ERC AdG AMETIST, #695116) and the Academy of Finland (TransPhoton, #259111).

We investigate electronic transport properties of as-grown and annealed n-type modulation-doped Al0.15Ga0.85As/GaAs1-xBix (x = 0 and 0.04) quantum well (QW) structures using magnetotransport measurements in the temperature range 4.2 K and 60 K and at magnetic fields up to 18 T. Thermal annealing process was applied at two different temperatures, 700 degrees C and 350 degrees C during 60 s and 180 s, respectively. We find that electron effective mass and 2D electron density in as-grown Bi-containing sample are slightly lower than that in Bi-free one. Furthermore, quantum electron mobility and quantum scattering time are observed to be decreased in Bi-containing samples. The annealing process at 700 degrees C causes a slight increase in electron effective mass and 2D electron density. A negligible decrease in electron effective mass and an increase in 2D electron density are determined following annealing at 350 degrees C. The observed change in electron effective mass following thermal annealing process is attributed to changing 2D electron density in the samples. No improvement on quantum electron mobility and quantum scattering time are observed following thermal annealing at both process temperatures. We determine that one electron subband (e1) for as-grown and annealed (at 700 degrees C for 60 s) Bi-containing QWs and two electron subbands (e1 and e2) for the annealed (at 350 degrees C for 180 s) GaAsBi QW sample and the Bi-free QW sample contribute to electronic transport. Our results reveal that there is no significant direct effect of Bi on effective electron mass, but an indirect effect, in which Bi can provoke changes in 2D electron density and hence causes not to observe actual band-edge electron mass but a deviation from its band-edge value. Therefore, it can be concluded that dispersion curve of conduction band does not change as an effect of Bi incorporation in GaAs.

The structural and photovoltaic properties of the GaAs/GaAsBi pin solar cell with GaAs0.983Bi0.017 active layer are investigated by optical and electrical measurement techniques. The bandgap of GaAsBi active layer is determined to be 1.3 eV at room temperature. Current density-voltage (J-V) under AM 1.5G spectrum and spectral response measurements are carried out to determine photovoltaic properties of the solar cell. The presence of a midgap trap levels in GaAsBi active layer is identified by deep level transient spectroscopy (DLTS). J-V characteristics is analysed by using Sah-Noyce-Shockley (SNS) theory which includes the midgap trap found in DLTS measurement. The observed deviation between experimental and calculated J-V results is ascribed for metallic cluster formation at the interface between GaAs emitter and GaAsBi intrinsic active layer. Interface metallic clusters create local Schottky junction between emitter and active layers. The best fit to the experimental J-V characteristic of the solar cell is obtained by considering the presence of GaBi metallic cluster at the interface between GaAs emitter and GaAsBi active layer of the solar cell. We showed that work function of interface clusters have a significant effect on the open circuit voltage and filling factor.

International audience; We report on an investigation of optical and structural properties of as-grown and thermal annealed GaBixAs1−x (x = 0.012, 0.018 and 0.03) epilayers by photomodulated reflectance (PR) spectroscopy, atomic force microscopy (AFM) and micro-Raman spectroscopy. PR spectra are analyzed by third derivative functional form (TDFF) lineshape. Optical transition energies are calculated using strain-included valence band anticrossing (VBAC) model. According to the results, optical transitions are from conduction bandedge to heavy hole bandedge and to light hole bandedge, which are affected by compressive strain and effect of strain is clearly seen when Bi concentration exceeds 2%. We also determine the band-anticrossing interaction parameter CBiM as 1.33 eV. TDFF analysis of as-grown and thermal annealed samples reveal that thermal annealing causes an unexpectedly large redshift of ∼22 meV/Bi% in the bandgap that corresponds to the increase of Bi composition by ∼25% in the GaAs lattice. The origin of this redshift is analyzed by AFM and Raman spectroscopy. Surface morphology of the GaBiAs samples show that droplets appear on the GaBiAs surface and their sizes increase with increasing Bi concentration, but tend to decrease following thermal annealing process and some surface droplets leave pits in their locations. Raman spectroscopy and AFM results give hints of diffusion of some Bi atoms from surface into the epilayer that causes an increase in Bi concentration of the alloy. This increase explains the observed annealing-induced redshift of the bandgap in PR measurement.

The humidity-sensing properties of ZnO nanowires synthesized by carbothermal catalyst-free vapor solid (VS) technique were studied. The morphology and the crystal structure were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The humidity adsorption and desorption kinetics of the synthesized ZnO nanowires were investigated via quartz crystal microbalance (QCM) measurements. The observed positive frequency shift of ZnO nanowires when loaded on the QCM crystal under varying relative humidity conditions can be explained in terms of visco-elastic variations in their mechanical stiffness., Istanbul University (2526 and UDP 6728); State Planning Organization of Turkey (DPT2003K120390); Scientific and Technological Research Council of Turkey (TBAG 109T240)

We present the results of longitudinal carrier transport under a high electrical field in n- and p-type modulation-doped Ga0.68In0.32NyAs1−y/GaAs (y = 0.009, 0.017) quantum well (QW) structures. Nitrogen composition-dependent drift velocities of electrons are observed to be saturated at and at 77 K for the samples with y = 0.009 and y = 0.017, respectively, while the drift velocities of holes do not saturate but slightly increase at the applied electric field in the range of interest. The hole drift velocity is observed to be higher than the electron drift velocity. The electron mobility exhibits an almost temperature-independent characteristic. On the other hand, the hole mobility exhibits a conventional temperature dependence of modulation-doped QW structures. As the temperature increases, the drift velocity of the electrons exhibits an almost an temperature-insensitive characteristic, but, on the other hand, for holes, drift velocity decreases approximately from 107–106 cm s−1. It is observed that the drift velocities of electrons and holes are N-dependent and suppressed at higher electric fields. Furthermore, experimental results show that there is no evidence of negative differential velocity (NDV) behaviour for both n- and p-type samples. To explore the observed electron and hole drift velocity characteristic at high electric fields, we use a simple theoretical model for carrier transport, which takes into account the effect of non-drifting hot phonons. The mobility mapping technique (comparison method) is used to extract hot hole temperature in order to employ it in the non-drifted phonon distribution and to obtain the drift velocity–electric field curves. Then hot electron temperatures are obtained from the drift velocity–electric field curves as a fit parameter using non-drifted hot phonon dynamics. The analytical model is well-matched to the experimental –E curves, indicating that carrier-hot phonon scattering is the main reason for suppressing the NDV mechanism in GaInNAs/GaAs QW structures with a carrier density higher than 1017 cm−3.

WOS: 000312586500001, PubMed ID: 23075073, We report on the Mg-doped, indium-rich Ga (x) In1-x N (x < 30). In the undoped material, the intrinsic electron density is very high and as a result there is no detectable photoconductivity (PC) signal within the range of temperatures of 30 < T < 300 K. In the Mg-doped material however, where the conductivity is reduced, there is a strong PC spectrum with two prominent low-energy peaks at 0.65 and 1.0 eV and one broad high-energy peak at around 1.35 eV. The temperature dependence of the spectral photoconductivity under constant illumination intensity, at T > 150 K, is determined by the longitudinal-optical phonon scattering together with the thermal regeneration of non-equilibrium minority carriers from traps with an average depth of 103 +/- 15 meV. This value is close to the Mg binding energy in GaInN. The complementary measurements of transient photoluminescence at liquid He temperatures give the e-A(0) binding energy of approximately 100 meV. Furthermore, Hall measurements in the Mg-doped material also indicate an activated behaviour with an acceptor binding energy of 108 +/- 20 meV., TUBITAK Ankara [EEEAG-105E076]; Istanbul University [9571]; COST Action [MP 0805], We are grateful to WJ Schaff for the samples, to TUBITAK Ankara for the funding (project number EEEAG-105E076) and to Istanbul University for the funding (project number 9571). We also acknowledge the COST Action MP 0805 for funding the international scientific collaboration.

WOS: 000315516800001, PubMed ID: 23146126, In this study, photomodulated reflectance (PR) technique was employed on two different quantum well infrared photodetector (QWIP) structures, which consist of n-doped GaAs quantum wells (QWs) between undoped Al (x) Ga1-x As barriers with three different x compositions. Therefore, the barrier profile is in the form of a staircase-like barrier. The main difference between the two structures is the doping profile and the doping concentration of the QWs. PR spectra were taken at room temperature using a He-Ne laser as a modulation source and a broadband tungsten halogen lamp as a probe light. The PR spectra were analyzed using Aspnes' third derivative functional form. Since the barriers are staircase-like, the structure has different ground state energies; therefore, several optical transitions take place in the spectrum which cannot be resolved in a conventional photoluminescence technique at room temperature. To analyze the experimental results, all energy levels in the conduction and in the valance band were calculated using transfer matrix technique, taking into account the effective mass and the parabolic band approximations. A comparison of the PR results with the calculated optical transition energies showed an excellent agreement. Several optical transition energies of the QWIP structures were resolved from PR measurements. It is concluded that PR spectroscopy is a very useful experimental tool to characterize complicated structures with a high accuracy at room temperature., Scientific and Technological Research Council of Turkey (TUBITAK) [108T721]; COST Action [MP0805]; Scientific Research Projects Coordination Unit of Istanbul University [3587, UDP 16607]; Ministry of Development of Turkey [2010K121050], We are grateful to Dr. Bulent Aslan and Dr. Ugur Serincan from Anadolu University for growing the ANA samples with MBE. This work was partially supported by The Scientific and Technological Research Council of Turkey (TUBITAK; project number 108T721), COST Action MP0805, Scientific Research Projects Coordination Unit of Istanbul University (project numbers 3587 and UDP 16607), and the Ministry of Development of Turkey (project number 2010K121050).