Search

Laboratory experiments show that sand grain saltation in a Mars-like environment can result in the ionization of argon. This suggests that saltation can be a mechanism for the destruction of methane (CH4) on Mars given the ionization energy of argon is higher than the energy required to ionize methane to a reactive cation. The ionization energy is also higher than the energy to dissociate methane to highly reactive species like CH3, CH2, and CH. The feasibility of capturing the resulting emission glow on a windy Martian night is discussed.

Numerous studies have demonstrated that the martian surface environment is hostile to life because of its rough radiation climate and the reactive chemistry of the regolith. Physical processes such as erosion and transport of mineral particles by wind-driven saltation have hitherto not been considered as a life hazard. We report a series of experiments where bacterial endospores (spores of Bacillus subtilis) were exposed to a simulated saltating martian environment. We observed that 50% of the spores that are known to be highly resistant to radiation and oxidizing chemicals were destroyed by saltation-mediated abrasion within one minute. Scanning electron micrographs show that the spores were not only damaged by abrasion but were eradicated during the saltation process. We suggest that abrasion mediated by wind-driven saltation should be included as a factor that defines the habitability of the martian surface environment. The process may efficiently protect the martian surface from forward contamination with terrestrial microbial life-forms. Abrasion mediated by wind-driven saltation should also be considered as a major challenge to indigenous martian surface life if it exists/existed.

The only organic compounds that have been detected in the Martian soil are simple chlorinated compounds released from heated surface material. However, the sources of the organic carbon are in dispute. Wind abraded silicates, which are widespread on the Martian surface, can sequester atmospheric methane which generates methylated silicates and thus could provide a mechanism for accumulation of reduced carbon in the surface soil. In this study we show that thermal volatilization of methylated silicates in the presence of perchlorate leads to the production of chlorinated methane. Thus, methylated silicates could be a source of the organic carbon released as chlorinated methane upon thermal volatilization of Martian soil samples. Further, our experiments show that the ratio of the different chlorinated compounds produced is dependent on the mass ratio of perchlorate to organic carbon in the soil.

The results of the Labeled Release and the Gas Exchange experiments conducted on Mars by the Viking Landers show that compounds in the Martian soil can cause oxidation of organics and a release of oxygen in the presence of water. Several sources have been proposed for the oxidizing compounds, but none has been validated in situ and the cause of the observed oxidation has not been resolved. In this study, laboratory simulations of saltation were conducted to examine if and under which conditions wind abrasion of silicates, a process that is common on the Martian surface, can give rise to oxidants in the form of hydrogen peroxide ( H 2 O 2 ) and hydroxyl radicals (⋅OH). We found that silicate samples abraded in simulated Martian atmospheres gave rise to a significant production of H 2 O 2 and ⋅OH upon contact with water. Our experiments demonstrated that abraded silicates could lead to a production of H 2 O 2 facilitated by atmospheric O 2 and inhibited by carbon dioxide. Furthermore, during simulated saltation the silicate particles became triboelectrically charged and at pressures similar to the Martian surface pressure we observed glow discharges. Electrical discharges can cause dissociation of CO 2 and through subsequent reactions lead to a production of H 2 O 2 . These results indicate that the reactions linked to electrical discharges are the dominant source of H 2 O 2 during saltation of silicates in a simulated Martian atmosphere, given the low pressure and the relatively high concentration of CO 2 . Our experiments provide evidence that wind driven abrasion could enhance the reactivity of the Martian soil and thereby could have contributed to the oxidation of organic compounds and the O 2 release observed in the Labeled Release and the Gas Exchange experiments. Furthermore, the release of H 2 O 2 and ⋅OH from abraded silicates could have a negative effect on the persistence of organic compounds in the Martian soil and the habitability of the Martian surface.