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The use of bryophytes as an indicator of environmental quality has been addressed on numerous occasions and in different places of the world under a variety of conditions. However, in Latin America their use is still limited. In the study described here, the presence and distribution of the bioaccumulation of lead in bryophytes has been evaluated in both contaminated and uncontaminated sites in Villavicencio (Colombia) and its surroundings. Villavicencio is a medium-sized city that is similar in size to many other cities in Latin America. A total of 52 samples of bryophytes were collected, of which 43 belong to points distributed in urban areas of the city (residential, commercial, highway), and the remaining nine are from uncontaminated areas (reference) taken in the surroundings of the city. The samples were treated with acid (nitric and hydrochloric) and subsequently measured by atomic absorption spectrometry. It was found that Pb concentrations in the commercial sector are between 1 and 6 times higher than in the residential and highway sectors. Spatial distribution maps of lead over the sampled territory were created using Arc-GIS 10.1. It is noteworthy that the values obtained are higher than those found in European cities.

Vermicomposting is an efficient technology to treat organic wastes and recover nutrients for agricultural purposes. The aim of this work was to assess the feasibility of vermicomposting to treat onion waste and the resulting vermicompost as an agricultural input. Onion waste from the food industry was mixed with cow dump and vermicomposted for 154 days at the pilot scale. The evolution of temperature, moisture, pH, electrical conductivity and total nitrogen was monitored during the vermicomposting process. Finally, the vermicompost was characterized to assess its potential use in agriculture. The vermicomposting process was carried out at moisture around 85% and maximum temperature of 33 °C. The pH decreased throughout the process, while the electrical conductivity increased. Total nitrogen concentration decreased during the first days but then was constant. The final vermicompost was a mature material (C/N = 13), with considerable carbon content (15.7%), lightly basic and with low electrical conductivity. Nutrient equilibria were 1:8:3 with appreciable content of other nutrients such as Ca, Mg and S. Toxic elements were in low concentration and below the legal threshold. The vermicomposting of onion waste with cow dump is a feasible technology to treat this waste and produce a valuable agricultural input to close the nutrient circle.

The production of onion waste derived mainly from bulbs affected by fungal diseases, during onion classification and storage presents an important agro-environmental issue in onion production regions. Composting is an environmentally friendly strategy to recycle agricultural waste and produce organic fertilizers. Modifications of the microbial community in soil can affect the ability of pathogen propagules to survive, germinate and infect plant roots. Hence, the main objective of this work was to exploring the mechanisms involved on the presence of three soil-borne phytopathogenic fungi during the composting process of onion waste under the hypothesis if that the resulting compost effectively prevents or minimizes the dispersion of phytopathogenic fungi. To this end, three composting piles of 60 tonnes each were built by layering onion waste affected by phytopathogenic fungi and cow dung at 1:1 ratio. Temperature, moisture, pH, electrical conductivity (EC) and Aspergillus niger, Penicillium sp. and Fusarium sp. growth were monitored for 100 days. During the first 28 days of composting, the presence of phytopathogenic fungi increased significantly showing thereafter a downward trend. Final estimations of fungal populations densities indicated a predominance of A. niger and an effective reduction in the abundance of Fusarium sp. This pilot-scale work demonstrates the feasibility of composting onion waste contaminated with phytopathogenic fungi and highlights the positive environmental impact associated with this practice. Therefore, the composting of onion waste and cow dung is a feasible and sustainable procedure to recycle onion waste and to promote circular economy in onion production regions. Fil: Chorolque, A.. Universidad Nacional del Comahue; Argentina Fil: Pellejero, G.. Universidad Nacional del Comahue; Argentina Fil: Sosa, María Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Confluencia. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue. Instituto de Biotecnología Agropecuaria del Comahue | Universidad Nacional del Comahue. Facultad de Ciencias Agrarias. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue. Instituto de Biotecnología Agropecuaria del Comahue; Argentina Fil: Palacios, J.. Universidad Nacional del Comahue; Argentina Fil: Aschkar, Gabriela Marisa. Universidad Nacional del Comahue; Argentina Fil: García Delgado, C.. Universidad Autónoma de Madrid; España Fil: Jiménez Ballesta, R. Universidad Autónoma de Madrid; España

The aim of the work described here was to understand the pedogeochemical signature of five rare earth elements (REEs, Ce, Nd, La, Y, and Sc) in vineyard soils in Campo de Calatrava (a unique territory with calcareous, volcanic and metamorphic rocks). The mean contents in surface horizons of Ce, Nd, La, Y, and Sc were 65.7, 32.0, 35.5, 18.8, and 13.9 mg·kg–1, respectively. In subsurface horizons the contents were Ce 62.8, Nd 31.1, La 35.7, Y 17.9, and Sc 14.4 mg·kg–1. The results show that mean contents of REEs in the area under investigation are in the order Ce &gt, Nd &gt, La &gt, Y &gt, Sc. Ce has a very high range, with a value close to 150 mg·kg–1. On the other hand, concentrations of Ce, Nd, Y, and Sc are higher in soils on volcanic material than in soils on nonvolcanic material, while only La values are lower in soils on volcanic rocks. The distributional maps of REEs in surface and subsurface horizons suggest that parent material and pedogenesis such as argillization and calcium carbonate accumulation are more important factors than the use of REE-based fertilizers, except in certain exceptional cases (consistent with a possible specific human impact after continuous fertilization).

For the first time, the pedogeochemical contents of some rare earth elements, namely neodymium (Nd), cerium (Ce), lanthanum (La), yttrium (Y), scandium (Sc), and hafnium (Hf), have been investigated in soils and grapevines (leaves) of vineyards in the small municipality of Alcubillas (La Mancha, Central Spain). The content of the elements was determined using an X-ray fluorescence spectrometer in solid mode on a powdered aliquot of each sample (soil or leave). Soil REE concentrations were not as elevated as the territory close to the site under investigation, that are potentially affected by mining of these elements. The order of concentrations follows the general order Ce > La > Nd > Y > Sc > Hf. The bioaccumulation coefficient (BAC) is low, in the range 0.05–0.25, which suggests that leaves only take up rare earth elements in small amounts. The results provide pedogeochemical baseline data for vineyards (soil and plant) not only in the study area but also for similar vineyard zones, with similar environmental conditions.

In Panama City, the water supply sources for the population come mainly from surface waters, but in times of drought and extreme natural phenomena, the need to resort to underground sources is explored. This paper concerns an exploratory investigation with the aim of assessing the quality of groundwater in the southeastern part of the Province of Panama and to determine its possible use as drinking water during extreme natural phenomena. Monthly monitoring over a period of 15 months was carried out. The study included the sampling and analysis of groundwater by different physic-chemical, hydrochemical and biological parameters. The results showed that most of the parameters in the analysed groundwater conformed to the Panamanian drinking water norm and the water potability diagram, this is a convenient source of raw water for purification. As for other uses for this water source, it should be used with caution since it represents a medium risk of soil salinization for irrigation water; and it is a moderately hard water for industrial uses.

The mineralogical and geochemical patterns of calcareous vineyard soils located in Alcubillas (La Mancha, Central Spain) have been evaluated, also their variability has been studied. The information provided by this study supports the assessment of geochemical spatial variability, the origin of these soils, their elements and the factors that control their distribution. The presence of quartz, calcite, feldspar and, in particular, illite and kaolinite is due to their inheritance from surrounding lithologies (and pedological processes), which mostly include limestones, marls and other sedimentary rocks, as well as metasedimentary rocks of Hercynian origin. Furthermore, since the presence and accumulation of certain trace elements in vineyard soils is a relevant global hazard (in particular with respect to wine production quality), the spatial distributions of Ba, Cr, Cu, Pb, Rb, Sr, V and Zr (carried out using geostatistical techniques and geometry-based interpolation methods) were investigated in order to determine the origin of these trace elements. The presence of these elements can be interpreted as being due to geogenic, pedogenic and, in certain cases, anthropic influences. The nature of certain agricultural practices, including the use of fertilizers, phytosanitary products and machinery, could explain the local increases in some trace element contents.

The aim of this study was to determine the concentrations of Cu and Zn in soils in the vineyards of La Rioja and to calculate reference values for the two elements. Samples were taken from the surface horizon (0&ndash, 20 cm) and the subsurface horizon (40&ndash, 60 cm) in 106 locations. Some physico-chemical properties were analyzed along with the total and bioavailable contents of these elements. Various statistical parameters were calculated, and distribution maps were then created using the ordinary-Kriging method. The Cu content was in the range of 2.46&ndash, 121.52 mg kg&ndash, 1, and the Zn content was 9.05&ndash, 125.67 mg kg&ndash, 1. These values fell within the normal ranges in comparison with other areas of Spain and the rest of Europe. The concentrations in the surface and in the subsurface were compared, in the case of Cu, the concentration was higher at the surface, whereas significant differences in the vertical distribution of Zn were not observed. Both metals had a heterogeneous distribution across the entire area of study. In the case of Zn, the similarity of the maps between surface and depth was verified, while the case of Cu was different. The main source of these metals was the parent material from which the soil had been formed, but in the case of Cu, maps showed increased Cu at the surface, which was especially marked at certain points and seemed to indicate the presence of an exogenous contribution at these locations. That means that the copper concentrations in the topsoil resulted from the yearlong grapevine protection with copper-based agents. Reference values were calculated to be 85.28 and 48.88 mg kg&ndash, 1 of Cu and 83.69 and 72.05 mg kg&ndash, 1 for Zn at the surface and at depth, respectively.

Monazite ((Ce, La, Nd, Th) PO4) is a rare and strategic mineral that occurs naturally as an accessory and minor mineral in diverse igneous and metamorphic rocks. This mineral does not frequently form mineable ore deposits and it has different typologies, including those formed by endogenous processes (generally “yellow monazite” mineralizations) and those formed by exogenous processes (“gray monazite” mineralizations). The mineral is an important ore of Rare Earth Elements (REEs), which have been identified by the European Union as critical raw materials. Monazite can be considered a weathering-resistant mineral, and the mobility of the REE and associated elements is low. The study reported here concerns a mineralogical and geochemical assessment of the occurrence and risks associated with the presence of concentrations of monazite in a typical, well-developed, and representative red Mediterranean soil, in order to establish the associated risk with their future mining. The results confirmed that monazite ore is particularly poor in radioactive elements, and it is concentrated in the most surficial soil horizons. The chemical mobility of REEs present in the soil, as assessed by selective extraction with ammonium acetate in acidic media, follows the order Y > Dy > U > Tb > Gd > Eu > Sm > La > Th > Ce. The mobility of REEs contained in monazite proved to be higher than that of the REE compounds in the upper horizons of the soil profile suggesting the immobilization in other REE-containing minerals, while light REEs show lower mobility rates than heavy REEs, due to an immobilization of LREE by sorption with iron oxy-hydroxides. Further studies are required in order to obtain better speciation data for REEs in soils aimed to identify soluble and insoluble compounds.

Urbanization-induced land-use changes cause several environmental problems, especially in developing countries due to a lack of sufficient urban planning. This study was performed in a medium-size city of Villavicencio, Colombia. Copper, lead, nickel, zinc, chromium, manganese, and cadmium in road-deposited sediment (RDS) from different land uses were determined. Multiple geo- and statistical approaches of geographic information system mapping, Pearson correlation, Kruskal–Wallis H, hierarchical cluster analysis (HCA), and principal component analyze (PCA) were employed to assess the influence of land use on the metals’ spatial distribution. The enrichment of given metals in RDS was evaluated by geo-accumulation (Igeo) and pollution load (PLI) indexes. The exposure human health risk was assessed by hazard index (HI). Results show that the average contents of the given metals decreased in the order of commercial > residential > highway > government institutions and public parks areas. Commercial areas thereafter always have the highest metals enrichment (Igeo) and pollution level (PLI). HI assessment indicates that child has a higher health risk than adult due to the exposure to metals in RDS. HCA analysis reveals that surface roughness had a more direct influence than land-use type on metals’ distribution. Kruskal–Wallis H test further suggests land-use type had a significant influence on certain metals’ spatial variation. Two potential (group) sources of geochemical and vehicular sources, along with leaded petrol and paintings, were inferred to be the main contributors to metals in RDS by PCA analysis.

In the last decade, diseases of bacterial origin in onions have increased and this has led to significant losses in production. These diseases are currently observed in both the Old and New Worlds. The present study aimed to evaluate whether the irrigation method influences the incidence of diseases of bacterial origin.; Results: In cases where the inoculum was natural, the initial incidence of soft bacterial rot did not manifest in any treatment in the first year, whereas, at the end of the conservation period, all treatments had increased incidences of infection. Sprinkler irrigation (8%) was statistically differentiated from the other treatments, for which the final incidence was similar (4.5%). For all irrigation treatments, the final incidence of bacterial soft rot decreased or remained stable towards the end of the cycle, with the exception of sprinkler irrigation in 2015, which increased.; Conclusion: From the results of the present study, it can be inferred that the irrigation method does have an influence on the incidence of diseases of bacterial origin in the post-harvest stage for onions. © 2018 Society of Chemical Industry.; © 2018 Society of Chemical Industry.

In Castilla-La Mancha region (Spain) there are more than 500,000 ha of vineyards. The soils in the area of maximum culture intensity of wine grapes have a medium to high content in calcium carbonate. In these areas, the appearance of chlorosis symptoms is usually related to iron deficiency, but this is not the only element that is involved in these nutritional problems. Data from 110 soil profiles selected from Castilla-La Mancha region were taken following the procedure described in FAO-ISRIS-ISS. X-ray fluorescence was used to measure both soil and leaf concentrations of mineral elements. From the data obtained, the mean contents of topsoils (A and B horizons) in Ca, Fe, Mn and Zn were studied and compared with leaf contents in these elements. The data were geo-referenciated and displayed in spatial distribution maps. Concentration in soil of the considered elements were: 108.0 ± 28.8 g kg −1 for Ca; 22.1 ± 1.4 g kg −1 for Fe; 380.0 ± 740.0 mg kg −1 for Mn and 32.6 ± 14.0 mg kg −1 for Zn. Leaf concentration measured for the same elements were: 24.4 ± 49.4 g kg −1 for Ca; 440.0 ± 742.0 mg kg −1 for Fe; 130.0 ± 136.0 mg kg −1 for Mn and 20.3 ± 12.9 mg kg −1 for Zn. As average, Zn levels are more critical than Fe levels in soil and leaves for plant nutrition. Critical concentrations in micronutrients should be considered in order to explain and prevent symptoms of deficiency that could decrease the quantity and quality of wine grapes.

Purpose Farming production in the lower part of Río Negro Valley (Argentina) has increased considerably during recent years, causing soil degradation and, specifically, decreasing the organic matter contents. This fact requires recovery measures, as organic amendments for soils, to improve its quality. The marked objectives for the present research is to evaluate compost as organic fertilizer, based on a mix of onion waste and bovine manure. Methods The experiment was carried out in a completely randomized design, involving five treatments and one control, with ten copies of each one. Tests were performed in a greenhouse, using flowerpots and experimental plots, in a typical soil of the region (Aridisol), pH 8.3 and 2.2% of organic matter, mixed with different compost dosages (20, 40, 60 and 80 Mg ha−1) and the chemical treatment, Urea (0.26 Mg ha−1). A horticultural farming of 1 lettuce was sowed (Lactuca sativa). A conventional handling was carried out for the whole cultivation period, and at the end was harvested. Ten plants per plot were taken and were determined total fresh weight, aerial part fresh weight, root part fresh eight. In the dry controls total dry weight, aerial dry weight and root dry weight was determined. Results Results show, with an error (p

The Choghakhor Wetland in Chaharmahal and Bakhtiari Province (Iran) has a significant role in maintaining water and sediment quality, because the wetland acts as a sink for contaminants that can pollute the aquatic ecosystem and affect human health. The present study uses a simple geostatistical technique to investigate the spatial variability of Cd and Pb in the Choghakhor Wetland to link the spatial variations of sediments to heavy metal contents in Myriophyllum spicatum. It was hypothesized that the heavy metal contents in the Choghakhor Wetland sediments impacted the concentration values in macrophytes. The value of heavy metals in sediments ranges from 0.54- to 1.84-μg/g dry weight (dw) for Cd, and from 1.32- to 2.46-μg/g dw for Pb, with a mean value of 1.12- and 1.82-μg/g dw, respectively. The mean value of Cd and Pb was 1.14- and 1.67-μg/g dw, respectively, in the aquatic macrophyte Myriophyllum spicatum, with corresponding ranges of 0.9-1.83-μg/g dw and 1.33-1.95-μg/g dw. There was a spatial structure in the Cd and Pb contents in the wetland sediments, with lower contents in the northern zone despite the values quantified in the south. We observed a direct spatial relationship between the Cd content in sediments and the Cd concentration in M. spicatum, and confirmed an effect of plant uptake for Cd. However, there were no significant differences between Pb in sediments and Pb in samples of M. spicatum, which implied that other factors like discharged industrial waste could also affect the accumulation of metals in plants. It can be concluded that spatial patterns indicated differences in the territory of the sediment Cd content at the Choghakhor Wetland localization in association with sediment enrichment. However, it was surprising that Pb did not show this pattern despite anthropic pressure., This work was funded by the Shahrekord University, Shahrekord, Iran. The authors appreciate the assistance provided by the Spanish Ministry (Project CGL2013-43675-P).

The essential features of the soils of a pilot zone in La Mancha (Central Spain), namely the Alcubillas municipability, have been characterized. The soil properties that may contribute to a better understanding of the impact of soil on grape production have also, been evaluated. For this, several soil profiles have been described and analyzed and the profiles have been mapped. The soils are mainly Entisols, Inceptisols and Alfisols, with their evolution controlled by the action of a xerophytic Mediterranean climate. Most of these soils have a loamy clay texture, with medium clay contents and sufficient nutrient contents (despite the low content in organic matter 1.39% and 1.04%, and the high concentrations of calcium carbonate 23.7% and 26.9% in the surface and subsurface horizons, respectively). Drainage problems were not observed and it can therefore be stated that the Alcubillas vineyards are based on a &lsquo, terroir&rsquo, term for the production of high quality grapes. In general, the soils are not subjected to treatments to control possible diseases or pests and we have therefore postulated that the soils represent the ideal scenario to establish a distinctive zone and for the increasingly valued ecological and natural viticulture.

(1) Background: The purpose of this study was to investigate zinc contents in leaves and soils of the Valdepeñas Protected Designation of Origin (PDO), situated in central Spain. Zn distribution maps of leaves and soils were obtained. (2) Methods: Ninety soil profiles were described, sampled and analyzed. Furthermore, vineyard leaves were collected randomly in each of the analyzed soil vineyard profiles. Soil and leaf samples were analyzed by X-ray fluorescence. (3) Results: The mean total Zn concentrations in vineyard soils were in the range of 16.2–153.7 mg·kg−1, with a mean of 47.5 mg·kg−1. The obtained values above the 95th percentile (between 81.3 and 153.7 mg·kg−1) could be affected by different parent materials or Zn agricultural treatments in vineyards. Contents in different soils follow the order Entisol &gt, Alfisol &gt, Inceptisol. The average Zn content value in leaves was 23.8 mg·kg−1 and oscillated between 11.5 and 93.3 mg·kg−1, minor differences were detected between soil types, with the highest value in plants grown on soils without carbonates. (4) Conclusions: The obtained values are optimal for vine cultivation. The bioaccumulation factors in leaves were lower than unity (0.24–0.53 range). This means that the Zn bioaccumulation process is relatively low in the soil–grapevine system. This study serves as a reference to identify areas that present Zn deficiencies or risk of contamination.

Contamination of aquatic systems with potentially toxic trace elements (PTEs) is a major problem throughout the world. The National Park Tablas de Daimiel (NPTD) is considered to make up one of the two most important wetlands in the Biosphere Reserve called “Wet Spot.” Since PTEs are good indicator of the prevailing environmental conditions and possible contamination, soil samples collected from 43 sites were analyzed in order to investigate the levels and its distribution of these elements, in the inundated floodplain area of the NPTD wetland. In addition, some physicochemical parameters such as pH, electrical conductivity and organic matter were measured. The total concentrations of 32 trace elements were determined by X-ray fluorescence. The results show that there was accumulation of lead (Pb), tin (Sn), selenium (Se), antimony (Sb), copper (Cu), vanadium (V), nickel (Ni), zinc (Zn), arsenic (As), strontium (Sr) and zirconium (Zr)—in some cases at high concentrations. The interpolated maps showed that the distributions of some of these elements and in some cases the trend in spatial variability are pronounced and decrease from the inlet to the outlet. The values for some elements are higher than the reference values, which is consistent with contamination (some values are higher by a factor of more than 10 compared to the reference). In the case of iodine (I), the levels at some sample points are significantly more than ten times the reference; Se appears in the range from 1.0 to 9.8 mg/kg, with an average value of 3.1 mg/kg, and these can be considered as seleniferous soils. The concentrations found are consistent with the introduction in the wetland of pollution by human activities, such as agricultural non-point sources, uncontrolled fertilization over many years, treatment with urban wastewater and other possible sources., Departamento de Geología y Geoquímica, Universidad Autónoma de Madrid, España, Escuela de Ingenieros Agrónomos, Universidad de Castilla La Mancha, España, Instituto Geológico y Minero de España, España

Following the occurrence of a fire at a tire landfill in the surrounding area of Madrid City (Spain), polycyclic aromatic hydrocarbons (PAHs) and trace elements present in soils were analyzed to assess the impact of the fire. The capacity of the soils’ clay mineral fraction to reflect this air pollution incident was studied. Fourteen soil samples were collected at different distances under the smoke plume, and they were subjected to high-performance liquid chromatography–photodiode array detection, inductively coupled plasma mass spectrometry and X-ray diffraction analyses. Clay minerals content showed a strong correlation with the pollutants potentially released in the tire fire, acenaphthene, pyrene, benzo(a)pyrene and benzo(a)fluoranthene. Trace metals Zn and Se were related to the proximity of the tire fire without any relationship with clay minerals content. This work suggests the use of natural clay minerals as potential PAHs geo-indicators in response to air pollution, complementary to current air and biological analyses, This work has been economically supported by the Ministry of Economy and Competitiveness of Spain, Project AGL2016-78490-R

In the Tablas de Daimiel National Park (TDNP) wetlands, a semi-arid wetland system in Spain that is of international importance, it is believed that pollutants from a variety of sources accumulate. In the study reported here, we evaluated soils from the flooded part of this wetland in an effort to establish relationships between the abundance/structure of microbial communities (mainly cyanobacteria) and certain soil properties (redox potential, dissolved oxygen, organic matter, soil reaction, electrical conductivity, calcium carbonate, total nitrogen, soluble phosphorus and total phosphorus). This objective was achieved by establishing one transect from the entrance to exit of the flood plain, including sampling from potentially polluted sites. Substantial variations between sampling sites were found in soil in terms of salinity, dissolved oxygen (DO), organic matter (OM), total phosphorus (TP) and nitrogen (TN). The presence of primary producers was more evident in contaminated samples. In addition to calcium, high levels of oxidizable organic matter, traces of dissolved oxygen, and considerable amounts of nitrate and phosphates probably stimulated the growth of cyanobacteria, these latter characteristics can be explained as being due to the influence of wastewaters from urban, industrial and agricultural activities that run off directly into this unique wetland. In the future it will be necessary to understand the synergic effects of other soil properties., The authors are grateful to the Autonomous Organism Parques Naturales of Spain (OAPN) for providing financial assistance

The distribution of Mn and Ni in soils of one of the most famous winegrowing regions of Spain, Rioja D.O.Ca (Denomination of origin, Spain's top category), was studied in detail according to its geographical location. There were background concentrations of 288.81 mg kg−1 total Mn in the surface horizon and 296.06 mg kg−1 in the subsoil; and a total Ni content of 17.89 mg kg−1 in the surface horizon and 24.76 mg kg−1 in the subsoil. The amounts of Mn bio- or phytoavailable were 5.28 mg kg−1 in the upper horizon and 4.70 mg kg−1 in the subsurface horizon; and for Ni bio- or phytoavailable, the amounts were 0.14 mg kg−1 in the upper horizon and 0.13 mg kg−1 in the deeper horizon. Spatial distribution patterns were established using GIS contour maps for the two elements, showing significant variations within and between the sites. The local contamination is generally associated with the quantities that are added to the soil or water from man-made sources such as industrial discharge and volatile emissions, s...

SPRINGER: "The final publication is available at link.springer.com”, Wetland pollution and other changes have led to the serious degradation of wetlands worldwide. The Tablas de Daimiel National Park (TDNP) wetland is a unique wetland in a semi-arid region of Mediterranean climate (Central Spain) and it has suffered significant degradation. In an effort to evaluate the magnitude of this degradation, a total of 43 soil sampling stations were selected in the flood plain area of this wetland. Parameters such as pH, electrical conductivity (EC), dissolved oxygen (DO), calcium carbonate and nutrients (N, P, S, C, S) in the soil were measured along with other trace elements (Br and I). The results were analyzed and a significant spatial variability of the parameters was found. The results of the analysis indicate that the TDNP wetland has a significant capacity to retain and sequester carbon. The elements Br and I had the highest anthropogenic proportions in certain soils in the study area; Br was present in the range 7.7–375.7 mg/kg, with an average value of 74.8 mg/kg, whereas I was present in the range 20.0–277.0 mg/kg, with an average value of 39.4 mg/kg. Both of these average values are much higher than the reference levels in the region. N and P were also present and in some cases these also had higher values than the reference. Wastewaters from urban/industrial activities and from agricultural runoff are the cause of these anomalous levels released into this unique wetland and these concentrations may be harmful to living organisms., Support for this research was provided by the Autonomous Organization for Natural Parks of Spain. The authors thank the Director of this organization, Basilio Rada, and the Director of the NPTD, Carlos Ruiz, for their support

Wetlands are complex ecosystems that play multiple roles. &lsquo, Las Tablas de Daimiel National Park&rsquo, (TDNP) undoubtedly plays a role in several ecosystem services and provides a connection between nature, farmers, scientists, residents, and other stakeholders. The state of degradation and/or vulnerability of this ecosystem (with a series of socio-economic implications) have led the publication of numerous articles. The work reported here provides a description of the growing importance of this wetland within the rural landscapes of La Mancha and emphasizes its state of degradation, mainly since pedological point of view. In this way, particular attention is required to assure the conservation of the Tablas of Daimiel Wetland, thus, several measures are proposed to improve the conservation of this area as to control and prohibit any dumping of any type of waste in the park or in its vicinity.

Globally, it is estimated that 20 million hectares of arable land are irrigated with water that contains residual contributions from domestic liquids. This potentially poses risks to public health and ecosystems, especially due to heavy metals, which are considered dangerous because of their potential toxicity and persistence in the environment. The Villavicencio region (Colombia) is an equatorial area where rainfall (near 3000 mm/year) and temperature (average 25.6 °C) are high. Soil processes in tropical conditions are fast and react quickly to changing conditions. Soil properties from agricultural fields irrigated with river water polluted by a variety of sources were analysed and compared to non-irrigated control soils. In this study, no physico-chemical alterations were found that gave evidence of a change due to the constant use of river water that contained wastes. This fact may be associated with the climatic factors (temperature and precipitation), which contribute to fast degradation of organic matter and nutrient and contaminants (such as heavy metals) leaching, or to dilution of wastes by the river.

Castilla-La Mancha (central Spain) is a region characterized by significant agricultural production aimed at high-quality food products such as wine and olive oil. The quality of agricultural products depends directly on the soil quality. Soil geochemistry, including dispersion maps and the recognition of baselines and anomalies of various origins, is the most important tool to assess soil quality. With this objective, 200 soil samples were taken from agricultural areas distributed among the different geological domains present in the region. Analysis of these samples included evaluation of edaphological parameters (reactivity, electrical conductivity, organic matter content) and the geochemistry of major and trace elements by X-ray fluorescence. The dataset obtained was statistically analyzed for major elements and, in the case of trace elements, was normalized with respect to Al and analyzed using the relative cumulative frequency (RCF) distribution method. Furthermore, the geographic distribution of analytical data was characterized and analyzed using the kriging technique, with a correspondence found between major and trace elements in the different geologic domains of the region as well as with the most important mining areas. The results show an influence of the clay fraction present in the soil, which acts as a repository for trace elements. On the basis of the results, of the possible elements related with clay that could be used for normalization, Al was selected as the most suitable, followed by Fe, Mn, and Ti. Reference values estimated using this methodology were lower than those estimated in previous studies.

Soil pollution is a key component of the land degradation process, but little is known about the impact of soil pollution on human health in the urban environment. The heavy metals Pb, Zn, Cu, Cr, Cd and Ni were analyzed by acid digestion (method EPA 3050B) and a total of 15 dust samples were collected from streets of three sectors of the city with different land uses; commercial, residential and a highway. The purpose was to measure the concentrations of heavy metals in road sediment samples taken from urban sites under different land uses, and to assess pollution through pollution indices, namely the ecological risk index and geoaccumulation index. Heavy metals concentrations (mg/kg) followed the following sequences for each sector: commercial sector Pb (1289.4) > Cu (490.2) > Zn (387.6) > Cr (60.2) > Ni (54.3); highway Zn (133.3) > Cu (126.3) > Pb (87.5) > Cr (9.4) > Ni (5.3); residential sector Zn (108.3) > Pb (26.0) > Cu (23.7) > Cr (7.3) > Ni (7.2). The geoaccumulation index indicated that the commercial sector was moderately to strongly polluted while the other sectors fell into the unpolluted category. Similarly, using the ecological risk index the commercial sector fell into the considerable category while the other sectors classified as low risk. Road dust increased along with city growth and its dynamics, additionally, road dust might cause a number of negative environmental impacts, therefore the monitoring this dust is crucial.