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Cyclone Nilofar was the third-strongest cyclone in the Arabian Sea. It was a category 4 cyclone that arrived in last week of October 2014. It lingered in the Arabian Sea for 10 days and caused a si...

Colored dissolved organic matter (CDOM) is the main constituent of dissolved organic matter (DOM), also a key indicator of water quality conditions. Accurate estimation of CDOM is essential for understanding biogeochemical processes and ecosystems in marine waters. The use of remote sensing to derive the changes in CDOM is vital technology that can be used to dynamically monitor the marine environment and to document the spatiotemporal variations in CDOM over a large scale. In the present study, we develop a simple approach to estimate the CDOM concentrations based on the in situ datasets from four cruise surveys over the Bohai Sea (BS) and Yellow Sea (YS). Eight band combination forms (using Xi as a delegate, where i denotes the numerical order of band combination forms), including single bands, band ratios, and other band combinations by remote sensing reflectance, Rrs(λ), were trained to test the correlations with the CDOM concentrations. The obtained results indicated that X7, i.e., [Rrs(443) + Rrs(555)]/[Rrs(443)/Rrs(555)], was the optimal form, with correlation coefficient (R) values of 0.904 (p

Marine phytoplankton accounts for roughly half the planetary primary production, and plays significant roles in marine ecosystem functioning, physical and biogeochemical processes, and climate changes. Documenting phytoplankton assemblages' dynamics, particularly their community structure properties, is thus a crucial and also challenging task. A large number of in situ and space-borne observation datasets are collected that cover the marginal seas in the west Pacific, including Bohai Sea, Yellow Sea, and East China Sea. Here, a customized region-specific semi-analytical model is developed in order to detect phytoplankton community structure properties (using phytoplankton size classes, PSCs, as its first-order delegate), and repeatedly tested to assure its reliable performance. Independent in situ validation datasets generate relatively low and acceptable predictive errors (e.g., mean absolute percentage errors, MAPE, are 38.4%, 22.7%, and 34.4% for micro-, nano-, and picophytoplankton estimations, respectively). Satellite synchronization verification also produces comparative predictive errors. By applying this model to long time-series of satellite data, we document the past two-decadal (namely from 1997 to 2017) variation on the PSCs. Satellite-derived records reveal a general spatial distribution rule, namely microphytoplankton accounts for most variation in nearshore regions, when nanophytoplankton dominates offshore water areas, together with a certain high contribution from picophytoplankton. Long time-series of data records indicate a roughly stable tendency during the period of the past twenty years, while there exist periodical changes in a short-term one-year scale. High covariation between marine environment factors and PSCs are further found, with results that underwater light field and sea surface temperature are the two dominant climate variables which exhibit a good ability to multivariate statistically model the PSCs changes in these marginal seas. Specifically, three types of influence induced by underwater light field and sea surface temperature can be generalized to cover different water conditions and regions, and meanwhile a swift response time (approximately 1 month) of phytoplankton to the changing external environment conditions is found by the wavelet analysis. This study concludes that phytoplankton community structures in the marginal seas remain stable and are year-independent over the past two decades, together with a short-term in-year cycle; this change rule need to be considered in future oceanographic studies.

Satellite remote sensing of inland water body requires a high spatial resolution and a multiband narrow spectral resolution, which makes the fusion between panchromatic (PAN) and multi-spectral (MS) images particularly important. Taking the Daquekou section of the Qiantang River as an observation target, four conventional fusion methods widely accepted in satellite image processing, including pan sharpening (PS), principal component analysis (PCA), Gram-Schmidt (GS), and wavelet fusion (WF), are utilized to fuse MS and PAN images of GF-1. The results of subjective and objective evaluation methods application indicate that GS performs the best, followed by the PCA, the WF and the PS in the order of descending. The existence of a large area of the water body is a dominant factor impacting the fusion performance. Meanwhile, the ability of retaining spatial and spectral informations is an important factor affecting the fusion performance of different fusion methods. The fundamental difference of reflectivity information acquisition between water and land is the reason for the failure of conventional fusion methods for land observation such as the PS to be used in the presence of the large water body. It is suggested that the adoption of the conventional fusion methods in the observing water body as the main target should be taken with caution. The performances of the fusion methods need re-assessment when the large-scale water body is present in the remote sensing image or when the research aims for the water body observation.

During the weathering of marine-spilled oils, various types of oil pollution are formed that can harm marine and coastal environments. Thus, the remote detection, classification and quantification of spilled oils is important in marine environmental monitoring. Although multispectral images can be used to observe various spilled oils, due to confusion between the multispectral backscattered signals, distinguishing spilled oils from floating algae in the same image is challenging. The spectral features of carbon-hydrogen (-C-H) and oxygen-hydrogen (-O-H) groups, and pigments, are diagnostic absorption features and are different from the backscattering signal, they have not been used to improve detection independently. In this study, all the spectral features of the groups were clearly interpreted using reflectance spectra collected from an airborne visible infrared imaging spectrometer (AVIRIS). A reflectance peak-trough detection method to characterize the different spectral groups was used to determine the spectral features of Deepwater Horizon (DWH) oil emulsions and floating Sargassum in the Gulf of Mexico (GOM). The results show that the spilled oils and floating Sargassum can be clearly identified, and the various spilled oils (i.e., different oil emulsions and oil slicks) could also be determined from the differences in the spectral features of the above groups. Finally, we discuss the spectral requirements for the identification of these groups and we conclude that optical remote sensing, including imaging spectrometers, will play an increasingly important role in assessing marine oil spills.

Spaceborne lidar (light detection and ranging) is a very promising tool for the optical properties of global atmosphere and ocean detection. Although some studies have shown spaceborne lidar’s potential in ocean application, there is no spaceborne lidar specifically designed for ocean studies at present. In order to investigate the detection mechanism of the spaceborne lidar and analyze its detection performance, a spaceborne oceanic lidar simulator is established based on the semianalytic Monte Carlo (MC) method. The basic principle, the main framework, and the preliminary results of the simulator are presented. The whole process of the laser emitting, transmitting, and receiving is executed by the simulator with specific atmosphere–ocean optical properties and lidar system parameters. It is the first spaceborne oceanic lidar simulator for both atmosphere and ocean. The abilities of this simulator to characterize the effect of multiple scattering on the lidar signals of different aerosols, clouds, and seawaters with different scattering phase functions are presented. Some of the results of this simulator are verified by the lidar equation. It is confirmed that the simulator is beneficial to study the principle of spaceborne oceanic lidar and it can help develop a high-precision retrieval algorithm for the inherent optical properties (IOPs) of seawater.

Over the past few years, oceanographic lidar was applied to many fields, and polarization lidar could provide extra information for marine particles. To retrieve the water properties, many simulation models and inversion methods were developed. However, few of them account for the depolarization effect of a rough sea surface. In this study, we develop a model to calculate reflection and transmission Mueller matrices, coupled with the lidar observation geometry. Compared with another operational method, our model has a satisfactory performance. This model also considers the shadowing effects of wave facets. Then, we analyze the polarized properties in different azimuth and zenith angles and find that the reflection of sea surface has a crucial effect on the polarization properties of lidar. For unpolarized light, the reflected light tends to be partially polarized. However, for lidar light that is completely polarized, there is an obvious depolarization owing to multiple scattering, and the depolarization is not negligible at small incident angles. The retrieval of properties of ocean constituents can be effectively improved, becoming more accurate by accounting for the depolarization effects of sea surfaces based on our method.

The coverage of valid pixels of remote-sensing reflectance (Rrs) from ocean color imagery is relatively low due to the presence of clouds. In fact, it is also related to the presence of high aerosol optical depth (AOD) and other factors. In order to increase the valid coverage of satellite-retrieved products, a layer removal scheme for atmospheric correction (LRSAC) has been developed to process the ocean color data. The LRSAC used a five-layer structure including atmospheric absorption layer, Rayleigh scattering layer, aerosol scattering layer, sea surface reflection layer, and water-leaving reflectance layer to deal with the relationship of the components of the atmospheric correction. A nonlinear approach was used to solve the multiple reflections of the interface between two adjoining layers and a step-by-step procedure was used to remove effects of each layer. The LRSAC was used to process data from the sea-viewing wide field-of-view sensor (SeaWiFS) and the results were compared with standard products. The average of valid pixels of the global daily Rrs images of the standard products from 1997 to 2010 is only 11.5%, while it reaches up to 30.5% for the LRSAC. This indicates that the LRSAC recovers approximately 1.65 times of invalid pixels as compared with the standard products. Eight-day standard composite images exhibit many large areas with invalid values due to the presence of high AOD, whereas these areas are filled with valid pixels wusing the LRSAC. The ratio image of the mean valid pixel of the LRSAC to that of the standard products indicates that the number of valid pixels of the LRSAC increases with an increase of AOD. The LRSAC can increase the number of valid pixels by more than two times in about 33.8% of ocean areas with high AOD values. The accuracy of Rrs from the LRSAC was validated using the following two in situ datasets: the Marine Optical BuoY (MOBY) and the NASA bio-Optical Marine Algorithm Dataset (NOMAD). Most matchup pairs are distributed around the 1:1 line indicating that the systematic bias of the LRSAC is relatively small. The global mean relative error (MRE) of Rrs is 7.9% and the root mean square error (RMSE) is 0.00099 sr−1 for the MOBY matchups. Similarly, the MRE and RMSE are 2.1% and 0.0025 sr−1 for the NOMAD matchups, respectively. The accuracy of LRSAC was also evaluated by different groups of matchups according to the increase of AOD values, indicating that the errors of Rrs were little affected by the presence of high AOD values. Therefore, the LRSAC can significantly improve the coverage of valid pixels of Rrs with a similar accuracy in the presence of high AOD.

The critical angle is the angle at which the contrast of oil slicks reverse their contrasts against the surrounding oil-free seawater under sunglint. Accurate determination of the critical angle ca...

The vertical distribution of subsurface phytoplankton in the ocean contains key information about not only ocean ecology but also water column optical properties relevant to remote sensing. The existing methods for measuring this vertical distribution are mainly field bio-optical and biogeochemical observations, which are time- and labor-intensive and do not provide sufficient spatial coverage. Passive satellite remote sensing provides global observations of phytoplankton but offers no information on subsurface vertical structure. In this study, we made the first quantitative measurements of vertical distribution of the subsurface phytoplankton layer (SPL) in the South China Sea (SCS) using airborne lidar. A total of five lidar flight experiments were conducted between 2017 and 2019 in the SCS, and approximately 2.5 terabytes of data were obtained. A hybrid retrieval method combining the Klett method for klidar and the perturbation method forβπ was developed. The lidar-retrieved chlorophyll-a concentrations and in situ data show good agreement (R2 greater than 0.8). The mean absolute percentage error for the lidar-retrieved chlorophyll-a concentrations is less than 15%. SPLs were observed both in Sanya Bay and in the open sea near Lingshui city, Hainan Province, China. The SPLs were observed at depths between 50 and 70 m in the open sea near Lingshui city, and between 5 and 30 m in Sanya Bay. The SPL depths have spatiotemporal variability, and we analyzed the possible factors (monsoon, seafloor depth, and sea surface temperature) that influence this spatiotemporal variability. The results show that lidar technology has a great potential for wide-range and long-term monitoring of SPLs, and is a good complement for discrete in situ observations and passive satellite remote sensing.

A novel remote sensing algorithm was developed based on Landsat 8 Operational Land Imager (OLI) data to separately recognize concurrent Sargassum and Ulva prolifera in the South Yellow Sea. This algorithm has three main steps: 1) classification of macroalgae-containing pixels from normal seawater pixels by means of a mature floating algae index (FAI) approach; 2) first-round separate recognition of the Sargassum and Ulva prolifera targets using a newly developed “Sargassum and Ulva prolifera Index I (SUI-I)” method; and 3) further fine identification of the algae by applying another new index (SUI-II) to the above output. The validation of our developed algorithm generated high and satisfactory predictive accuracies. The present study concludes that the Landsat 8 OLI data have great potential for detecting and distinguishing the mixed growth of Sargassum and Ulva prolifera, which will help in closely monitoring macroalgae blooms in oceanic waters.

The critical angle at which the brightness of oil slicks and oil-free seawater is reversed occurs under sunglint and is often shown as an area of uncertainty due to different roughness and surface Fresnel reflection parameters. Consequently, differentiating oil slicks from the seawater in these areas using optical sensors is a challenge. Polarized optical remote sensing techniques provide complementary information for intensity imagery with different physical properties and, thus, possess the ability to resolve this difficult problem. In the polarized reflectance model, the degree of linear polarization (DOLP) of sunglint depends on accurately knowing the Stokes parameter for the reflected light, and varies with the refractive index of the surface layer and the viewing angles. For the polarized detection of oil slicks, the highest sensitivity of the DOLP to the refractive index is located within the specular reflection direction where the sum of the solar and sensor zenith angles is 82.6°. The modeled results clearly indicate that the DOLP of oil slicks is weaker in comparison with oil-free seawater under sunglint. Using measurements from the space-borne Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar (PARASOL) over the Deepwater Horizon oil spill in the Gulf of Mexico, we illustrate that the PARASOL-derived DOLP difference between the oil spill and seawater is obvious and is in accordance with the modeled results. These preliminary results suggest that the potential of multi-angle measurement and feasibility of deriving refractive index of ocean surface from space-borne sensors need further researches.

Increasing hazy weather in the eastern area of China limits the potential application of high-resolution satellite data and poses a huge challenge for the atmospheric correction of remote sensing images. Consequently, it is necessary to find the most suitable atmospheric correction method under hazy condition. In this study, five kinds of atmospheric correction models, including 6S, COST, FLAASH, QUAC, and ATCOR2, are applied to the GaoFen-1 Wild Field Camera (GF-1 WFV1) data in the eastern area of China, and examined by both quantitative and qualitative analyses using the measured spectrum data. Experimental results indicated that ATCOR2 achieves the best performance among the atmospheric correction methods qualitatively and quantitatively. Hence, specifically for the study area and GF-1 WFV1 dataset, ATCOR2 is the most suitable atmospheric correction approach under hazy in the eastern area of China.

Thermal remote sensing is an effective technique for marine oil slick detection. However, many factors, such as the oil type, slick thickness, sensor capability, and the background environment, can together have an impact on the remotely sensed thermal imagery. These cross-coupling effects can usually be clarified by ground-based experiments. In this letter, four different types of oil slicks on water bodies were prepared and their brightness temperatures (BTs) measured periodically in an outdoor experiment. The results indicated that there are obvious differences in the BTs between the different types of oil, especially between crude and refined oil. Defined BT time-changing contrast coefficient of different type of oil slicks numerically displays these significant difference in different observed periods. These results imply that thermal sensors may be used to discern the type of oil slick and that time series of thermal observations will be able to help with oil-type detection in the future. Moreover, the optimal strategy is to make a series of observations covering the cooling period from noon (the optimal detection time) to around sunset.

The potential for a ship-mounted laser fluorometer to provide rapid, non-intrusively measurements in both coastal and lake conditions are investigated. The instrument consists of a high pulse repetition frequency (10-kHz) microchip laser for fluorescence excitation, a broadband hyperspectral micro spectrometer for spectral detection, and a confocal reflective fluorescent probe for signal collection; it weighs only about 1.7kg. Chlorophyll a (chl-a) and colored dissolved organic matter (CDOM) measured by the new instrument were observed to agree well with those measured by traditional time-consuming laboratory methods in Hangzhou Bay seawater and Qiandao Lake inland water. Subsequently, laser fluorescence distribution and characteristics of chl-a and CDOM in these regions were analyzed, which will improve our understanding of biogeochemical processes in these optically complex aquatic systems. The portable system is promising for water environment monitoring, especially in coastal and inland water.

Off the Yangtze River Estuary and its adjacent waters (the YRE) are one of the fastest changing regions in the world in terms of the effects of anthropogenic disturbance. Here we address quantitative analysis whether reducing river to sea sediment may cause declining water turbidity then a better light available condition for the algal growth, therefor increasing phytoplankton bloom magnitude in the YRE in the bloom season. An area of high phytoplankton productivity zone is estimated by theoretical and satellite data analysis, which matches well with the spatial distribution of accumulative times of the reported algal bloom events at the decadal time scale. We present 17-year (1998–2014) satellite and hydrological data to reveal an increasing trend in Chlorophyll-a concentration (Chl-a) in the spring bloom season (May to June), which has strong correlation with the decreasing in the sediment discharge from the Yangtze river to the East China Sea. Changes in Chl-a and the sediment load are inversely related in terms of both temporal variation and their corresponding magnitudes (R 2 =0.38, p=0.008, n=17). Furtherly, this relationship is not sensitivity to one-year time lag analysis. On the other hand, euphotic depth in the bloom period shows no significant change, which reflects a balance between the increasing phytoplankton biomass enhancing water turbidity and declining riverine sediment decreasing turbidity. Finally, a stepwise multiple linear regression is used to determine which of the five relatively independent environmental variables most significantly contribute to the interannual variability of the bloom magnitude. The most significant effect (p=0.00007) is also found in the riverine sediment load. Therefor, our results suggest that anthropogenic derived riverine sediment change has been significantly impacted spring phytoplankton production in the YRE.

A new bio-optical algorithm based on the green and red bands of the Medium Resolution Imaging Spectrometer (MERIS) is developed to differentiate the harmful algal blooms of Prorocentrum donghaiense Lu (P. donghaiense) from diatom blooms in the East China Sea (ECS). Specifically, a novel green-red index (GRI), actually an indicator for a(510) of bloom waters, is retrieved from a semi-analytical bio-optical model based on the green and red bands of phytoplankton-absorption and backscattering spectra. In addition, a MERIS-based diatom index (DIMERIS) is derived by adjusting a Moderate Resolution Imaging Spectroradiometer (MODIS) diatom index algorithm to the MERIS bands. Finally, bloom types are effectively differentiated in the feature spaces of the green-red index and DIMERIS. Compared with three previous MERIS-based quasi-analytical algorithm (QAA) algorithms and three existing classification methods, the proposed GRI and classification method have the best discrimination performance when using the MERIS data. Further validations of the algorithm by using several MERIS image series and near-concurrent in-situ observations indicate that our algorithm yields the best classification accuracy and thus can be used to reliably detect and classify P. donghaiense and diatom blooms in the ECS. This is the first time that the MERIS data have been used to identify bloom types in the ECS. Our algorithm can also be used for the successor of the MERIS, the Ocean and Land Color Instrument, which will aid the long-term observation of species succession in the ECS. This article is protected by copyright. All rights reserved.

Using ten years (2003–2012) of satellite Chlorophyll-a data, we report that annual phytoplankton bloom climax in the Northwest Pacific marginal seas (17°–58°N) delays northward at a rate of 22.98 ± 2.86 km day−1. The spring bloom is a dominant feature of the phytoplankton seasonal cycle in this region, except for the northern South China Sea, which features a winter bloom. The sea surface hourly Photosynthetically Available Radiation (PAR) intensity averaged over the bloom peak duration is nearly uniform (1.04 ± 0.10 W m−2 h−1) among the four sub-regions (i.e. the northern South China Sea, the Kuroshio waters, the Sea of Japan and the Sea of Okhotsk), although different algal species in these four distinct ecological provinces could adapt to a much larger change in other environmental parameters (including total daily PAR, day length, sea surface temperature, net surface heat flux, mixed layer depth, wind speed and euphotic depth). The differences of the hourly PAR intensity between the four provinces during their bloom periods are smaller than those during non-bloom seasons. In contrast, an increasing total daily PAR (W m−2 day−1), due to the longer day length at higher latitudes, may balance decreasing sea surface temperature and induce algal flowering. Our results point to an optimal hourly light intensity for the annual phytoplankton bloom peak timing in this entire region, which could potentially become an indicator for the requirement of these annual bloom peaks.

Knowledge about the spatiotemporal distribution of sea surface salinity (SSS) provides valuable and important information for understanding various marine biogeochemical processes and ecosystems, especially for those coastal waters significantly affected by human activities. Remote-sensing techniques have been used to monitor salinity in the open ocean with their advantages of wide-area surveys and real-time monitoring. However, potential challenges remain when using satellite data with coarse spatiotemporal resolutions, leading to a loss of valuable information. In the current study, based on the local dataset collected over the southern Yellow Sea (SYS), a region-customized algorithm was developed to estimate SSS by using the remote sensing reflectance. The model evaluations indicated that our algorithm yielded good SSS estimation, with a root-mean-square error (RMSE) of 0.29 psu and a mean absolute percentage error (MAPE) of 0.75%. Satellite-derived SSS results compared well with those derived from in situ observations, further suggesting the good performance of our developed algorithm for the study regions. We applied this algorithm to Geostationary Ocean Color Imager (GOCI) data for the month of August from 2011 to 2018 in the SYS, and produced the spatial distribution patterns of the SSS for August of each year. The SSS values were high in offshore waters and lower in coastal waters, especially in the Yangtze River estuary. The negative correlation between the monthly Changjiang River discharge (CRD) and SSS (R = −0.71, p < 0.001) near the Yangtze River estuary was observed, suggesting that the SSS distribution in the Yangtze River estuary was potentially influenced by the CRD. In offshore waters, the correlation between SSS and CRD was weak (R < 0.2), suggesting that the riverine discharge’s effect might be weak.

Marine oil slicks show brighter or darker than surrounding oil-free seawater under different sunglint, which can be observed by satellite optical sensors. Although this has been interpreted using a critical angle concept and simulated using the Cox-Munk model, it has not been demonstrated in high spatial resolution images from airborne sensors. In this study, an AISA (airborne imaging spectrometer for applications) image was used to determine the characteristics of non-emulsion oil slicks under sunglint in high spatial resolution images. Although a similar positive or negative contrast between non-emulsion oil slicks and oil-free seawater can be observed, it is difficult to directly model sunglint reflectance due to the different remote sensing scale effect. There are many sun glitter pepper noise produced by various micro-mirror facets of ocean surface in high spatial resolution images. Based on the optical image characteristics, a normalized noise index (ξ) was designed to evaluate the pepper noise in 1830 band-difference results. Then a level segmentation method was used to delineate the oil slicks under various sunglint from a minimum pepper noise image. Our study provides a preliminary reference for airborne optical remote sensing of oil slicks under various levels of sunglint.

Accurate calibration of oceanic LiDAR signals is essential for the accurate retrieval of ocean optical properties. Nowadays, there are many methods for aerosol LiDAR calibration, but fewer attempts have been made to implement specific calibration methods for oceanic LiDAR. Oceanic LiDAR often has higher vertical resolution, needs greater signal dynamic range, detects several orders of magnitude lower less depth of penetration, and suffers from the effects of the air-sea interface. Therefore the calibration methods for aerosol LiDAR may not be useful for oceanic LiDAR. In this paper, we present a new simple and feasible approach for oceanic LiDAR calibration via comparison of LiDAR backscatter against calculated scatter based on iteratively bio-optical models in clear, open ocean, Type 1 water. Compared with current aerosol LiDAR calibration methods, it particularly considers geometric losses and attenuation occurring in the atmosphere-sea interface. The mean relative error percentage (MREP) of LiDAR calibration constant at two different stations was all within 0.08%. The MREP between LiDAR-retrieved backscatter, chlorophyll after using LiDAR calibration constant with inversion results of measured data were within 0.18% and 1.39%, respectively. These findings indicate that the bio-optical methods for LiDAR calibration in clear ocean water are feasible and effective.

Aerosol is an essential parameter for assessing the atmospheric environmental quality, and accurate monitoring of the aerosol optical depth (AOD) is of great significance in climate research and environmental protection. Based on Landsat 8 Operational Land Imager (OLI) images and MODIS09A1 surface reflectance products under clear skies with limited cloud cover, we retrieved the AODs in Nanjing City from 2017 to 2018 using the combined Dark Target (DT) and Deep Blue (DB) methods. The retrieval accuracy was validated by in-situ CE-318 measurements and MOD04_3K aerosol products. Furthermore, we analyzed the spatiotemporal distribution of the AODs and discussed a case of high AOD distribution. The results showed that: (1) Validated by CE-318 and MOD04_3K data, the correlation coefficient (R), root mean square error (RMSE), and mean absolute error (MAE) of the retrieved AODs were 0.874 and 0.802, 0.134 and 0.188, and 0.099 and 0.138, respectively. Hence, the combined DT and DB algorithms used in this study exhibited a higher performance than the MOD04_3K-obtained aerosol products. (2) Under static and stable meteorological conditions, the average annual AOD in Nanjing was 0.47. At the spatial scale, the AODs showed relatively high values in the north and west, low in the south, and the lowest in the center. At the seasonal scale, the AODs were highest in the summer, followed by spring, winter, and autumn. Moreover, changes were significantly higher in the summer than in the other three seasons, with little differences among spring, autumn, and winter. (3) Based on the spatial and seasonal characteristics of the AOD distribution in Nanjing, a case of high AOD distribution caused by a large area of external pollution and local meteorological conditions was discussed, indicating that it could provide extra details of the AOD distribution to analyze air pollution sources using fine spatial resolution like in the Landsat 8 OLI.

Combined studies of latitudinal and interannual variations of annual phytoplankton bloom peak in East Asian marginal seas (17°–58°N, including the northern South China Sea (SCS), Kuroshio waters, the Sea of Japan and the Okhotsk Sea) are rarely. Based on satellite-retrieved ten-year (2003–2012) median timing of the annual Chlorophyll a concentration (Chl a) climax, here we report that this annual spring bloom peak generally delays from the SCS in January to the Okhotsk Sea in June at a rate of (21.20±2.86) km/d (decadal median±SD). Spring bloom is dominant feature of the phytoplankton annual cycle over these regions, except for the SCS which features winter bloom. The fluctuation of the annual peak timing is mainly within ±48 d departured from the decadal median peak date, therefore this period (the decadal median peak date ±48 d) is defined as annual spring bloom period. As sea surface temperature rises, earlier spring bloom peak timing but decreasing averaged Chl a biomass in the spring bloom period due to insufficient light is evident in the Okhotsk Sea from 2003 to 2012. For the rest of three study domains, there are no significant interannual variance trend of the peak timing and the averaged Chl a biomass. Furthermore this change of spring phytoplankton bloom timing and magnitude in the Okhotsk Sea challenges previous prediction that ocean warming would enhance algal productivity at high latitudes.

The concentration of total suspended matter (TSM) at the sea surface is derived from satellite data using a complex proxy TSM model in East China Sea from 1997 to 2008. The structure of the mean TSM image is similar to that of the topography, indicating that the distribution of the surface concentration is strongly related to the water depth. A dynamic sediment model (DSM) is constructed to relate the TSM concentration at the sea surface with suspended sediment at the benthic boundary layer, the Rouse number, and the water depth. The DSM model is improved through iteration with a convergence identified by the mean relative difference between two adjacent bottom TSM images which becomes smaller with the more iterations and the value is less than 1% after 50 iterations. The performance of the DSM model is validated by satellite-measured concentration with a mean relative error of 5.2% for the monthly mean images. The DSM model is used to deduce the bottom TSM concentration at the benthic boundary layer and the distribution of the Rouse number. The spatial distribution of the sea surface TSM concentration is determined predominately by both the bottom suspended sediment concentration and water depth. The temporal variation of the sea surface concentration mainly depends upon the Rouse number in the water column. Our result shows that the discharge of the Changjiang River can change the distribution of the Rouse number to form a band-shaped region in the Changjiang Estuary. The DSM model provides a framework for understanding some of the mechanisms of the formation and variation of the primary TSM plume and the secondary plume in the ECS. The primary TSM plume corresponds approximately to the region with depth shallower than 20 m and the secondary plume corresponds to the region with depths between 20 and 50 m.

Polarization response is an important factor influencing the accuracy of radiance measurement for satellite ocean color sensors, which would change with on-orbit time. In this paper, a practical method is proposed for on-orbit estimation of polarization response. First, the linear polarization components of the Stokes vector entering the sensor are estimated by a vector radiative transfer model of the coupled ocean–atmosphere system. Second, the real radiance entering the sensor is estimated by another high-accuracy ocean color sensor using the cross-calibration method. Finally, based on the estimated linear polarization components and real radiance, the polarization response coefficients are derived by the least squares method. The proposed method is tested by applying it to the Moderate Resolution Imaging Spectroradiometer on board the Aqua satellite, and the derived polarization factors are consistent with the prelaunch values, indicating the reliability of the proposed method. In addition, our results reveal that the contribution of aerosol scattering should be included in the estimation of the linear polarization components of the Stokes vector at the top of atmosphere, particularly for long wavelengths.

The evaluation of the wavelength parameters of spaceborne oceanic lidar is of great importance to ensure that the lidar system can provide more information of ocean and can be realized in engineering. In this paper, the optimum wavelengths of spaceborne oceanic lidar for purposes of ocean detection at coastal and global scales are analyzed mainly in terms of the penetration depth. The global distribution of ocean penetration depth and the corresponding optimum wavelength bands are calculated by using the oceanic optical properties data from Moderate Resolution Imaging Spectroradiometer (MODIS). Ocean with optimum penetration wavelength of 488 nm covers 61.82% of the global ocean and the optimum wavelength of 443 nm with ocean area share of 14.81% is a good complement for 488 nm. The penetration depths of 96.26% of the global ocean are deeper than 0.8 times the euphotic zone depths by using wavelengths of 488 nm and 443 nm, simultaneously. More importantly, taking advantage of the characteristic of solar Fe Fraunhoferline (438.355 nm) and H-β Fraunhoferline (486.134 nm), 70% of the background light can be suppressed by a filter with bandwidth of 0.1 nm and the penetration depth can be increased by approximately 5.0%. In conclusion, we propose that 486.134 nm is the optimum wavelength of single-wavelength spaceborne oceanic lidar and the combination of 486.134 nm and 438.355 nm is a good choice for dual-wavelength lidar for purpose of global ocean detection.

The global coverage of Chlorophyll-a concentration (Chl-a) has been continuously available from ocean color satellite sensors since September 1997 and the Chl-a data (1997–2019) were used to produce a climatological dataset by averaging Chl-a values at same locations and same day of year. The constructed climatology can remarkably reduce the variability of satellite data and clearly exhibit the seasonal cycles, demonstrating that the growth and decay of phytoplankton recurs with similarly seasonal cycles year after year. As the shapes of time series of the climatology exhibit strong periodical change, we wonder whether the seasonality of Chl-a can be expressed by a mathematic equation. Our results show that sinusoid functions are suitable to describe cyclical variations of data in time series and patterns of the daily climatology can be matched by sine equations with parameters of mean, amplitude, phase, and frequency. Three types of sine equations were used to match the climatological Chl-a with Mean Relative Differences (MRD) of 7.1%, 4.5%, and 3.3%, respectively. The sine equation with four sinusoids can modulate the shapes of the fitted values to match various patterns of climatology with small MRD values (less than 5%) in about 90% of global oceans. The fitted values can reflect an overall pattern of seasonal cycles of Chl-a which can be taken as a time series of biomass baseline for describing the state of seasonal variations of phytoplankton. The amplitude images, the spatial patterns of seasonal variations of phytoplankton, can be used to identify the transition zone chlorophyll fronts. The timing of phytoplankton blooms is identified by the biggest peak of the fitted values and used to classify oceans as different bloom seasons, indicating that blooms occur in all four seasons with regional features. In global oceans within latitude domains (48°N–48°S), blooms occupy approximately half of the ocean (50.6%) during boreal winter (December–February) in the northern hemisphere and more than half (58.0%) during austral winter (June–August) in the southern hemisphere. Therefore, the sine equation can be used to match the daily Chl-a climatology and the fitted values can reflect the seasonal cycles of phytoplankton, which can be used to investigate the underlying phenological characteristics.

Phytoplankton community is an important organism indicator of monitoring water quality, and accurately estimating its composition and biomass is crucial for understanding marine ecosystems and biogeochemical processes. Identifying phytoplankton species remains a challenging task in the field of oceanography. Phytoplankton fluorescence is an important biological property of phytoplankton, whose fluorescence emissions are closely related to its community. However, the existing estimation approaches for phytoplankton communities by fluorescence are inaccurate and complex. In the present study, a new, simple method was developed for determining the Chlorophytes, Chrysophytes, Cryptophytes, Diatoms, Dinoflagellates, and Prymnesiophytes based on the fluorescence emission spectra measured from the HOBI Labs Hydroscat-6P (HS-6P) in the Bohai Sea, Yellow Sea, and East China Sea. This study used single bands, band ratios, and band combinations of the fluorescence signals to test their correlations with the six dominant algal species. The optimal band forms were confirmed, i.e., X1 (i.e., fl(700), which means the fluorescence emission signal at 700 nm band) for Chlorophytes, Cryptophytes, Dinoflagellates, and Prymnesiophytes (R = 0.947, 0.862, 0.911, and 0.918, respectively) and X7 (i.e., [fl(700) + fl(550)]/[fl(550)/fl(700)], where fl(550) denotes the fluorescence emission signal at 550 nm band) for Chrysophytes and Diatoms (R = 0.893 and 0.963, respectively). These established models here show good performances, yielding low estimation errors (i.e., root mean square errors of 0.16, 0.02, 0.06, 0.36, 0.18, and 0.03 for Chlorophytes, Chrysophytes, Cryptophytes, Diatoms, Dinoflagellates, and Prymnesiophytes, respectively) between in situ and modeled phytoplankton communities. Meanwhile, the spatial distributions of phytoplankton communities observed from both in situ and fluorescence-derived results agreed well. These excellent outputs indicate that the proposed method is to a large extent feasible and robust for estimating those dominant algal species in marine waters. In addition, we have applied this method to three vertical sections, and the retrieved vertical spatial distributions by this method can fill the gap of the common optical remote sensing approach, which usually only detects the sea surface information. Overall, our findings indicate that the proposed method by the fluorescence emission spectra is a potentially promising way to estimate phytoplankton communities, in particular enlarging the profiling information.

In recent years, airborne lidar has been used in a wide range of oceanic applications, including detection of bathymetry, bubbles, internal waves, and schools of fish. However, it has not yet been extensively applied in Chinese seas. For example, there have been no studies to detect subsurface plankton layers in the South China Sea (SCS) by airborne lidar. In this study, we investigated this technology’s applicability for identifying subsurface plankton layers in Sanya Bay, SCS. Three airborne lidar flight experiments were carried out in March 2018 and in September 2017. Shipboard synchronous measurements were carried out in March 2018 to validate the lidar measurements. The method that is presented here can be used to detect a subsurface plankton layer, which is characterized by depth, thickness, and intensity. Compared with chlorophyll-a profile synchronously measured by shipborne fluorometer, there was a consistent relationship. The subsurface plankton layer depth error was less than 0.7 m. Next, the spatial distribution and seasonal variation of lidar measured subsurface plankton layers in Sanya Bay, SCS, was analyzed. The results showed that airborne lidar can potentially detect subsurface plankton layer within 50 meters deep in relatively clear water. This will enhance our understanding of biogeochemical processes in these optically complex aquatic systems.

The bulk refractive index (np) of suspended particles, an apparent measure of particulate refraction capability and yet an essential element of particulate compositions and optical properties, is a critical indicator that helps understand many biogeochemical processes and ecosystems in marine waters. Remote estimation of np remains a very challenging task. Here, a multiple-step hybrid model is developed to estimate the np in the Bohai Sea (BS) and Yellow Sea (YS) through obtaining two key intermediate parameters (i.e., particulate backscattering ratio, Bp, and particle size distribution (PSD) slope, j) from remote-sensing reflectance, Rrs(&lambda, ). The in situ observed datasets available to us were collected from four cruise surveys during a period from 2014 to 2017 in the BS and YS, covering beam attenuation (cp), scattering (bp), and backscattering (bbp) coefficients, total suspended matter (TSM) concentrations, and Rrs(&lambda, ). Based on those in situ observation data, two retrieval algorithms for TSM and bbp were firstly established from Rrs(&lambda, ), and then close empirical relationships between cp and bp with TSM could be constructed to determine the Bp and j parameters. The series of steps for the np estimation model proposed in this study can be summarized as follows: Rrs (&lambda, ) &rarr, TSM and bbp, TSM &rarr, bp &rarr, cp &rarr, j, bbp and bp &rarr, Bp, and j and Bp &rarr, np. This method shows a high degree of fit (R2 = 0.85) between the measured and modeled np by validation, with low predictive errors (such as a mean relative error, MRE, of 2.55%), while satellite-derived results also reveal good performance (R2 = 0.95, MRE = 2.32%). A spatial distribution pattern of np in January 2017 derived from GOCI (Geostationary Ocean Color Imager) data agrees well with those in situ observations. This also verifies the satisfactory performance of our developed np estimation model. Applying this model to GOCI data for one year (from December 2014 to November 2015), we document the np spatial distribution patterns at different time scales (such as monthly, seasonal, and annual scales) for the first time in the study areas. While the applicability of our developed method to other water areas is unknown, our findings in the current study demonstrate that the method presented here can serve as a proof-of-concept template to remotely estimate np in other coastal optically complex water bodies.

In estuarine and coastal ecosystems, the majority of previous studies have considered coupled nitrification-denitrification (CND) processes to be exclusively sediment based, with little focus on suspended particulate matter (SPM) in the water column. Here, we present evidence of CND processes in the water column of Hangzhou Bay, one of the largest macrotidal embayments in the world. Spearman’s correlation analysis showed that SPM was negatively correlated with nitrate (rho = −0.372, P = 0.018) and marker genes for nitrification and denitrification in the water column were detected by quantitative PCR analysis. The results showed that amoA and nir gene abundances strongly correlated with SPM (all P amoA/nir strongly correlated with nitrate (rho = −0.454, P = 0.003). Furthermore, aggregates consisting of nitrifiers and denitrifiers on SPM were also detected by fluorescence in situ hybridization. Illumina MiSeq sequencing further showed that ammonia oxidizers mainly belonged to the genus Nitrosomonas, while the potential denitrifying genera Bradyrhizobium, Comamonas, Thauera, Stenotrophomonas, Acinetobacter, Anaeromyxobacter, Sulfurimonas, Paenibacillus and Sphingobacterium showed significant correlations with SPM (all P

Optical identification and quantification of various marine-spilled oils play an important role in oil spill monitoring, assessment, and response. Through weathering processes, oil may become emulsified in two forms of oil-water mixture: water in oil (WO) and oil in water (OW). These two forms of oil emulsion are significantly different in their volume concentration (oil/water ratio), physical properties (viscosity, density, thickness), and optical properties (spectral reflectance (Ru(λ), sr−1), and spectral absorption (a(λ), m−1)). In this study, the optical properties of both types of oil emulsion, with different volumetric concentrations, are determined from carefully prepared oil emulsion samples, with the aim of helping to interpret optical remote sensing imagery. The concentrations of stable WO and OW emulsions range from 45% to 95% and from 0.025% to 3%, respectively. They exhibit different Ru spectral shapes in the near-infrared and shortwave-infrared wavelengths, with five “-CH” molecular bonds evident in the WO emulsion spectra. Ru (600–1400 nm) of OW emulsions increases with volume concentrations from 0% to 3.0%, but Ru (600–2400 nm) of the WO emulsions decreases with volume concentrations from 45% to 100%. On the other hand, for a fixed concentration (80%), Ru (600–2400 nm) of WO emulsions increases monotonically with thicknesses of up to ~0.4 mm, beyond which Ru (600–2400 nm) no longer increases with oil thickness. The difference between the Ru spectral shapes of OW and WO emulsions, as well as the statistical relationships between volume concentrations and Ru (NIR-SWIR) and between oil thickness and Ru (NIR-SWIR), provide the basis for developing optical models to classify oil emulsion types and for quantifying oil volume from remote sensing imagery. The potential of such an application is demonstrated using hyperspectral AVIRIS imagery collected over the Deepwater Horizon (DWH) oil spill in the Gulf of Mexico (GoM).

The atmospheric correction of satellite observations is crucial for both land and ocean remote sensing. However, the optimal approach for each area is different due to the large spectra difference in the ground reflectance between land and ocean. A unified atmospheric correction (UAC) approach based on a look-up table (LUT) of in situ measurements is developed to remove this difference. The LUT is used to select one spectrum as the in situ ground reflectance needed to obtain the initial aerosol reflectance, which in turn is used for determining the two closest aerosol models. The aerosol reflectance, obtained from these aerosol models, is then used to deduce the estimated ground reflectance. This UAC model is then used to process the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) data, and its performance is validated with a large number of in situ measurements. The mean bias of the land reflectance for this model is 6.59% with a root mean square error (RMSE) of 19.61%. The mean bias and RMSE of the water-leaving reflectance are 7.59% and 17.10% validated by the in situ measurements using the above-water method, while they are 13.60% and 22.53% using the in-water method. The UAC model provides a useful tool for correcting the satellite-received reflectance without separately having to deal with land and ocean pixels. Further, it can seamlessly expand the satellite ocean color data for terrestrial use and improve quantitative remote sensing over land.

The diurnal variation of the suspended sediment concentration (SSC) in Hangzhou Bay, China has been investigated using remotely-sensed SSC derived from the Geostationary Ocean Color Imager (GOCI) in combination with a coupled hydrodynamic-ecological model for regional and shelf seas (COHERENS). The SSC maps were inferred through a UV-AC atmospheric correction algorithm and an empirical inversion algorithm from the GOCI Level-1B data. The sediment transport model was initialized from maps of the GOCI-derived SSC and the model results were validated through a comparison with remotely-sensed data. The comparison demonstrated that the model results agreed well with the observations. The relationship between SSC distribution and hydrodynamic conditions was analyzed to investigate the sediment transport dynamics. The model’s results indicate that the action of tidal currents dominate the sediment deposition and re-suspension in the coastal waters of the East China Sea. This is especially the case in Hangzhou Bay where the tidal currents are strongest. The satellite-derived sediment data product can not only dramatically improve the specification of the initial conditions for the sediment model, but can also provide valuable information for the model validation, thereby improving the model’s overall performance.

This study proposed a green–red band quasianalytical algorithm, QAA-GRI, and evaluates its performance using an in situ dataset from Lake Qiandaohu, a drinking water source, in China. First, by shifting the reference wavelength from 555 to 510 nm, a green–red index (GRI) can be calculated from remote sensing reflectance at 510, 560, and 620 nm, and the index was then used to retrieve the total absorption coefficients at the reference band, a ( 510 ) . Second, a semianalytical model based on a ( 510 ) and the GRI was deduced to establish the QAA-GRI, replacing the empirical model in quasianalytical algorithm version 5 (QAA-v5). The QAA-GRI was applied to retrieve absorption coefficients from an in situ dataset of Lake Qiandaohu, and the QAA-GRI’s performance was compared with that of QAA-v5 and another red–green QAA-based approach (QAA-RGR). The results demonstrate that, for this dataset, the QAA-GRI exhibited better performance (R2 = 0.81, mean absolute percentage error, MAPE = 15.7 % ), which indicated a clear improvement in the accuracy of absorption coefficient retrieval, compared with QAA-v5 (R2 = 0.56, MAPE = 21.2 % ) and QAA-RGR (R2 = 0.67, MAPE = 22.6 % ). In addition, to illustrate the QAA-GRI’s assumptions and its applicability, the QAA-GRI was also applied to an in situ dataset from Taihu Lake, a highly turbid and eutrophic water source. As predicted, when applied to Taihu Lake, the QAA-GRI did not perform as well as it did when applied to Lake Qiandaohu because of the former’s extremely high turbidity, which can cause greater uncertainty with regard to backscattering coefficients. This study suggests that the QAA-GRI is better suited to the retrieval of absorption coefficients from drinking water resources. Our algorithm will also have potential applications to satellite data from the Medium Resolution Imaging Spectrometer or Ocean and Land Color Instrument.

Light absorption by phytoplankton, non-algal particles (NAP) and chromophoric dissolved organic matter (CDOM) was investigated at 90 sites of a clear, deep artificial lake (Lake Qiandaohu) to study natural variability of absorption coefficients. Our study shows that CDOM absorption is a major contributor to the total absorption signal in Lake Qiandaohu during all seasons, except autumn when it has an equivalent contribution as total particle absorption. The exponential slope of CDOM absorption varies within a narrow range around a mean value of 0.0164 nm−1 ( s d = 0.00176 nm−1). Our study finds some evidence for thIS autochthonous production of CDOM in winter and spring. Absorption by phytoplankton, and therefore its contribution to total absorption, is generally greatest in spring, suggesting that phytoplankton growth in Lake Qiandaohu occurs predominantly in the spring. Phytoplankton absorption in freshwater lakes generally has a direct relationship with chlorophyll-a concentration, similar to the one established for open ocean waters. The NAP absorption, whose relative contribution to total absorption is highest in summer, has a spectral shape that can be well fitted by an exponential function with an average slope of 0.0065 nm−1 ( s d = 0.00076 nm−1). There is significant spatial variability present in the summer of Lake Qiandaohu, especially in the northwestern and southwestern extremes where the optical properties of the water column are strongly affected by the presence of allochthonous matter. Variations in the properties of the particle absorption spectra with depths provides evidence that the water column was vertically inhomogeneous and can be monitored with an optical measurement program. Moreover, the optical inhomogeneity in winter is less obvious. Our study will support the parameterization of the Bio-optical model for Lake Qiandaohu from in situ or remotely sensing aquatic color signals.