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International audience; Diagenetic models for silt-rich mudstone (siltstone) are less advanced than those for sandstone and clay-rich mudstone. In addition, the influences of diagenetic processes on reservoir quality in siltstone formations are poorly understood. Here we examine the roles of depositional facies, detrital composition, and diagenetic processes in the compositional evolution and reservoir quality of the Lower Triassic Montney Formation, a prominent siltstone-dominated reservoir in western Canada with very large reserves of oil, gas-liquids and natural gas. We applied advanced, high-resolution petrographic methods including SEM (SE, BSE, EDX and SEM-CL), XRD, and QEMSCAN technologies, as well as He-pycnometry on samples from 17 different locations within the basin that represent a range of depths and thermal maturities. Cross-cutting and overgrowth relationships and volumes of authigenic phases demonstrate massive precipitation of quartz, feldspar, dolomite, calcite and anhydrite cements at shallow burial depths, leading to compositional homogeneity among different lithofacies. We propose that the precipitation of large volumes of cement resulted from high fluid flux through the formation at shallow depth, possibly driven by reflux of concentrated seawater in nearshore saltpans. Siltstones preserve relatively high porosity and permeability at shallow burial depths, differing from clay-rich mudstones. In contrast to sandstones, deep burial diagenesis played a relatively minor role in the compositional evolution of the Montney Formation siltstone and is expressed in the form of pressure solution and minor amounts of fibrous illite precipitation.

Summer warming is driving a greening trend across the Arctic, with the potential for large-scale amplification of climate change due to vegetation-related feedbacks [Pearson et al., Nat. Clim. Chang. (3), 673–677 (2013)]. Because observational records are sparse and temporally limited, past episodes of Arctic warming can help elucidate the magnitude of vegetation response to temperature change. The Last Interglacial ([LIG], 129,000 to 116,000 y ago) was the most recent episode of Arctic warming on par with predicted 21st century temperature change [Otto-Bliesner et al., Philos. Trans. A Math. Phys. Eng. Sci. (371), 20130097 (2013) and Post et al., Sci. Adv. (5), eaaw9883 (2019)]. However, high-latitude terrestrial records from this period are rare, so LIG vegetation distributions are incompletely known. Pollen-based vegetation reconstructions can be biased by long-distance pollen transport, further obscuring the paleoenvironmental record. Here, we present a LIG vegetation record based on ancient DNA in lake sediment and compare it with fossil pollen. Comprehensive plant community reconstructions through the last and current interglacial (the Holocene) on Baffin Island, Arctic Canada, reveal coherent climate-driven community shifts across both interglacials. Peak LIG warmth featured a ∼400-km northward range shift of dwarf birch, a key woody shrub that is again expanding northward. Greening of the High Arctic—documented here by multiple proxies—likely represented a strong positive feedback on high-latitude LIG warming. Authenticated ancient DNA from this lake sediment also extends the useful preservation window for the technique and highlights the utility of combining traditional and molecular approaches for gleaning paleoenvironmental insights to better anticipate a warmer future.

The detrital grain size of siltstone reservoirs occupies a middle ground between sandstones and shales, both of which are better understood in terms of their petrophysical properties. Because siltstones can be important hydrocarbon reservoirs, we examine controls on petrophysical properties in the Lower Triassic Montney Formation in western Canada, which hosts world-class reserves of gas, gas liquids and oil. We focus on the effects of rock fabric (including grain size) and composition on pore system characteristics and permeability, drawing contrasts between the three reservoir types. The Montney Formation is an unconventional reservoir through most of its subcrop, with porosities ranging from ∼3 to 7.5% and permeabilities in the micro to nano Darcy range (6.5*10−6 mD to 5.6*10−2 mD). Shale reservoirs worldwide are characterized by similar porosity and permeability values, with porosity of up to 8% (rarely up to 15%) and permeability in the nano to micro-Darcy range. Quartz, clay, and organic matter abundance influence the petrophysical properties of the Montney siltstone. Quartz content exerts a positive control on both porosity and permeability by strengthening the rock framework and reducing porosity loss due to compaction. Elevated clay content is also associated with higher porosity and permeability, in part because of a depositional association with quartz, and in part because clays locally shelter interconnected primary porosity that promotes permeability. Organic matter content is negatively correlated to porosity and permeability despite the presence of organic matter porosity because relict oil (now solid bitumen) occludes primary pores and because other pore types contribute a greater fraction of the total pore volume. Lithofacies, characterized in four cores, are indistinguishable on the basis of petrophysical properties, due to their similar grain size and composition and the massive overprinting by shallow burial diagenesis. While the pore system evolution of sandstones is mainly controlled by the mechanical compaction of hard grains and cementation, pore system evolution of shales is primarily controlled by compaction of ductile grains and diagenesis of primary organic matter, in addition to cementation. Porosity and permeability values of the Montney siltstones are similar to those of shale formations, but the controls on pore system evolution of this intermediate grain size reservoir are predominantly controlled by processes similar to sandstones: compaction, cementation, and cement dissolution. Minor contribution from secondary porosity in bitumen affects some sections of the reservoir in a way that is similar, but not identical, to shale reservoirs.

Heavy minerals are typically rare but important components of siliciclastic sediments and rocks. Their abundance, proportions, and variability carry valuable information on source rocks, climatic, environmental and transport conditions between source to sink, and diagenetic processes. They are important for practical purposes such as prospecting for mineral resources or the correlation and interpretation of geologic reservoirs. Despite the extensive use of heavy mineral analysis in sedimentary petrography and quite diverse methods for quantifying heavy mineral assemblages, there has never been a systematic comparison of results obtained by different methods and/or operators. This study provides the first interlaboratory test of heavy mineral analysis. Two synthetic heavy mineral samples were prepared with considerably contrasting compositions intended to resemble natural samples. The contributors were requested to provide (i) metadata describing methods, measurement conditions and experience of the operators and (ii) results tables with mineral species and grain counts. One hundred thirty analyses of the two samples were performed by 67 contributors, encompassing both classical microscopic analyses and data obtained by emerging automated techniques based on electron-beam chemical analysis or Raman spectroscopy. Because relatively low numbers of mineral counts (N) are typical for optical analyses while automated techniques allow for high N, the results vary considerably with respect to the Poisson uncertainty of the counting statistics. Therefore, standard methods used in evaluation of round robin tests are not feasible. In our case the 'true' compositions of the test samples are not known. Three methods have been applied to determine possible reference values: (i) the initially measured weight percentages, (ii) calculation of grain percentages using estimates of grain volumes and densities, and (iii) the best-match average calculated from the most reliable analyses following multiple, pragmatic and robust criteria. The range of these three values is taken as best approximation of the 'true' composition. The reported grain percentages were evaluated according to (i) their overall scatter relative to the most likely composition, (ii) the number of identified components that were part of the test samples, (iii) the total amount of mistakenly identified mineral grains that were actually not added to the samples, and (iv) the number of major components, which match the reference values with 95% confidence. Results indicate that the overall comparability of the analyses is reasonable. However, there are several issues with respect to methods and/or operators. Optical methods yield the poorest results with respect to the scatter of the data. This, however, is not considered inherent to the method as demonstrated by a significant number of optical analyses fulfilling the criteria for the best-match average. Training of the operators is thus considered paramount for optical analyses. Electron-beam methods yield satisfactory results, but problems in the identification of polymorphs and the discrimination of chain silicates are evident. Labs refining their electron-beam results by optical analysis practically tackle this issue. Raman methods yield the best results as indicated by the highest number of major components correctly quantified with 95% confidence and the fact that all laboratories and operators fulfil the criteria for the best-match average. However, a number of problems must be solved before the full potential of the automated high-throughput techniques in heavy mineral analysis can be achieved. info:eu-repo/semantics/publishedVersion

International audience; This study focuses on the Lower–Middle Triassic Montney, Sunset Prairie, Doig and Halfway formations from the foreland basin of the Canadian Cordillera (Alberta and British Columbia). Based on core and outcrop descriptions, the correlation of 400 wells, and on mineralogical analyses, this study interprets the basin-scale, 3D-stratigraphic architecture of these formations and discusses the controls on its evolution.Well correlation highlights four sequences (1–4) interpreted to occur in two second-order cycles (A and B). In this work, the Early Triassic Montney Formation and the early Middle Triassic Sunset Prairie Formation are interpreted to consist of three third-order sequences (1–3) related to the first second-order cycle (cycle A). The Middle Triassic Doig and Halfway formations are interpreted to consist of a fourth sequence (4) related to a second second-order cycle (cycle B). Integration of the stratigraphic surfaces with previously published biostratigraphic analyses emphasizes a major time gap of c. 2 myr between these two cycles, interpreted to record a major reorganization of the basin. Mineralogical analyses suggest that during cycle A, sediments were delivered from the east (Canadian Shield); whereas in cycle B, additional sources from the west (proto-Canadian Cordillera) occurred. This study shows that the stratigraphic architecture evolution was affected by the structural heritage of the basin and continental geodynamic evolution. This study provides a large-scale understanding on the controls of the stratigraphic architecture of the Lower and Middle Triassic strata, suggesting local and regional controls on the reservoir extension and unconventional play configuration within these strata.

Arctic shrubification is an observable consequence of climate change, already resulting in ecological shifts and global-scale climate feedbacks including changes in land surface albedo and enhanced evapotranspiration. However, the rate at which shrubs can colonize previously glaciated terrain in a warming world is largely unknown. Reconstructions of past vegetation dynamics in conjunction with climate records can provide critical insights into shrubification rates and controls on plant migration, but paleoenvironmental reconstructions based on pollen may be biased by the influx of exotic pollen to tundra settings. Here, we reconstruct past plant communities using sedimentary ancient DNA (sedaDNA), which has a more local source area than pollen. We additionally reconstruct past temperature variability using bacterial cell membrane lipids (branched glycerol dialkyl glycerol tetraethers) and an aquatic productivity indicator (biogenic silica) to evaluate the relative timing of postglacial ecological and climate changes at a lake on southern Baffin Island, Arctic Canada. The sedaDNA record tightly constrains the colonization of dwarf birch (Betula, a thermophilous shrub) to 5.9 ± 0.1 ka, ~3 ka after local deglaciation as determined by cosmogenic 10 Be moraine dating and >2 ka later than Betula pollen is recorded in nearby lake sediment. We then assess the paleovegetation history within the context of summer temperature and find that paleotemperatures were highest prior to 6.3 ka, followed by cooling in the centuries preceding Betula establishment. Together, these molecular proxies reveal that Betula colonization lagged peak summer temperatures, suggesting that inefficient dispersal, rather than climate, may have limited Arctic shrub migration in this region. In addition, these data suggest that pollen-based climate reconstructions from high latitudes, which rely heavily on the presence and abundance of pollen from thermophilous taxa like Betula, can be compromised by both exotic pollen fluxes and vegetation migration lags.