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1. Nitrogen Oxides and Nitric Acid Enable the Sustainable Hydroxylation and Nitrohydroxylation of Benzenes under Visible Light Irradiation

Author

Leonard Mach, Laura Elena Hofmann, and Markus R. Heinrich

Subjects
Denitrification, 010405 organic chemistry, Organic Chemistry, Visible light irradiation, 010402 general chemistry, Photochemistry, 01 natural sciences, 0104 chemical sciences, Hydroxylation, chemistry.chemical_compound, chemistry, Nitric acid, Organic chemistry, Waste recycling, Nitrogen oxides
Abstract

A new type of waste recycling strategy is described in which nitrogen oxides or nitric acid are directly employed in photocatalyzed hydroxylations and nitrohydroxylations of benzenes. Through these transformations, otherwise costly denitrification can be combined with the synthesis of valuable compounds for various applications.

Published
2017

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