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In this paper, ultralong ZnO nanowires were prepared on the surfaces of nickel foams and zinc foils by a hydrothermal method. The photocatalytic activities of ZnO nanowires grown on nickel foams have been tested by the degradation of Rhodamine B solution and using ZnO nanowires grown on zinc foils as the reference. The results indicate that the photocatalytic performance of ZnO nanowires grown on nickel foams is better than those grown on zinc foils. The results are mainly due to the fact that nickel foam is a three-dimensional scaffold structure, which provides large surface area for ZnO nanowire growth. More importantly, the photocatalytic circulation experiments indicate that ZnO nanowires grown on nickel foams are stable and reusable. In addition, the photocatalytic reaction rates can be enhanced by the use of multi-layer of nickel foams with ZnO nanowires grown on their surfaces.