1. On the volatility of nihonium (Nh, Z = 113)
- Author
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I. V. Shirokovsky, Maksim V. Shumeiko, Grigory K. Vostokin, Y. A. Popov, F. S. Abdullin, Yury Tsyganov, R. N. Sagaidak, A. V. Sabelnikov, A. A. Voinov, Robert Eichler, Sergey N. Dmitriev, Patrick Steinegger, O. V. Petrushkin, Vyacheslav Ya. Lebedev, Viktor I. Chepigin, Yury V. Albin, A. N. Polyakov, G. A. Bozhikov, Alexander Sh. Madumarov, A. V. Yeremin, V. K. Utyonkov, O. N. Malyshev, Gennadii Ya. Starodub, and N. V. Aksenov
- Subjects
Physics ,Nuclear and High Energy Physics ,Isotope ,Hadron ,Analytical chemistry ,010402 general chemistry ,01 natural sciences ,Recoil separator ,0104 chemical sciences ,Chromatographic separation ,Adsorption ,0103 physical sciences ,Nuclear fusion ,Density functional theory ,Atomic physics ,Nuclear Experiment ,010306 general physics ,Volatility (chemistry) - Abstract
Gas-phase chromatography studies of nihonium (Nh, $Z=113$ ) were carried out at the one-atom-at-a-time level. For the production of nihonium, the heavy-ion-induced nuclear fusion reaction of 48Ca with 243Am was used. This leads to isotopes 284,285Nh, as the direct descendants of the $\alpha$ -decaying precursors 288,289Mc. Combining the Dubna Gas-Filled Recoil Separator with gas-phase chromatographic separation, the experiment was sensitive to elemental nihonium and its adsorption behavior on Teflon, theoretically predicted by modern relativistic density functional theory. The non-observation of any decays of Nh after the chemical separation indicates a larger than expected retention of elemental Nh on a Teflon surface.
- Published
- 2017
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