1. Appropriately hydrophilic/hydrophobic cathode enables high-performance aqueous zinc-ion batteries
- Author
-
Yongchun Zhu, Huaisheng Ao, Xiaotan Zhang, Chengming Wang, Jiangxu Li, Dongyan Liu, Lei Shi, and Yitai Qian
- Subjects
Battery (electricity) ,Materials science ,Aqueous solution ,Renewable Energy, Sustainability and the Environment ,Electrochemical kinetics ,Energy Engineering and Power Technology ,Organic radical battery ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,Cathode ,0104 chemical sciences ,law.invention ,Contact angle ,Chemical engineering ,law ,Electrode ,General Materials Science ,0210 nano-technology - Abstract
Organic batteries with improved electrode wettability will exhibit a better electrochemical performance. How about the relationship between electrode wettability and battery performance in aqueous batteries? Here the effect of cathode wettability in aqueous zinc-ion batteries (AZIBs) on the zinc-ion diffusion and charge transfer based on a research platform of cellulose nanowhiskers (CNWs)/graphene/MnO2 wire-in-scroll nanowires with water contact angles turning from 64.70 ± 3.72° to 115.85 ± 3.36° as cathodes for AZIBs has been investigated, where the corresponding battery performance shows a parabola trend with the peak in 103.04 ± 2.91°. The cathode achieves a high capacity of 384 mAh g−1 at 1 C and features an ultra-long lifetime of over 5000 cycles at 20 C, representing excellent Zn storage performance. A combination of experimental measurements and density functional theory calculations suggests that increased cathode hydrophobicity forces hydrated Zn2+ desolvation at electrode-electrolyte interface, facilitating zinc-ion insertion into host materials, yet extremely hydrophobic cathode leads to sluggish electrochemical kinetics. This study opens a new idea in the design of promising candidates for developing low cost and long lifespan batteries for aqueous systems.
- Published
- 2020
- Full Text
- View/download PDF