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Journal of materials chemistry / A 9(8), 4831-4840 (2021). doi:10.1039/D0TA11096E, Published by Royal Soceity of Chemistry, London [u.a.]

The deep water overflow at three gaps in the Heng-Chun Ridge of the Luzon Strait is investigated based on long-term continuous mooring observations. For the first time, these observations enable us to assess the detailed structure and variability in the deep water overflow directly spilling into the South China Sea (SCS). The strong bottom-intensified flows at moorings WG2 and WG3 intrude into the deep SCS with maximum along-stream velocities of 19.2 ± 9.9 and 15.2 ± 6.8 cm s−1, respectively, at approximately 50 m above the bottom. At mooring WG1, the bottom current revealed spillage into the Luzon Trough from the SCS. The volume transport estimates are 0.73 ± 0.08 Sv at WG2 and 0.45 ± 0.02 Sv at WG3, suggesting that WG2 is the main entrance for the deep water overflow crossing the Heng-Chun Ridge into the SCS. By including the long-term observational results from previous studies, the pathway of the deep water overflow through the Luzon Strait is also presented. In addition, significant intraseasonal variations with dominant time scales of approximately 26 days at WG2 and WG3 have been revealed, which tend to be enhanced in spring and may reverse the deep water overflow.

One of the necessary prerequisites to advance the electrochemical performance of Li7La3Zr2O12 (LLZ) based all-solid-state lithium batteries is the manufacturing of dense composite cathodes from cathode active material (CAM) and the LLZ ceramic solid electrolyte. However, free co-sintering of LLZ and CAM mixtures requires temperatures above 1000 °C which often leads to decomposition and secondary phase formation, especially for high energy CAMs. In our study we present a completely dry processing route which is fast, free of any sintering additives and coatings and suitable to fabricate dense mixed cathodes, pure LLZ separators and multilayers of the two. Through application of high mechanical pressure during Field-Assisted Sintering we were able to reduce the sintering temperature down to 675–750 °C with dwell times as low as 10 min, while still obtaining 95% theoretical density for LCO/LLZ mixtures. The low sintering temperature is suitable for high energy CAMs, but leads to a significant effect of surface impurities, especially from powder handling in air, and affects the crystallinity of the CAM/LLZ interface. In the present paper we investigate the impact of resulting interfaces on the ionic conductivity, the interfacial impedance and the cycling stability of produced cells and propose the optimization strategy.

Several hydrophilic ionic liquids dissolved in water with different molalities are studied as “water-in-ionic liquid” supporting electrolytes. They exhibit wide electrochemical stability window from 3 to 4.4 V, high ionic conductivities and good flowability, making them promising supporting electrolytes for aqueous high-voltage rechargeable batteries. In such supporting electrolytes, enhanced redox activities of lithium insertion/extraction in anodic TiO2 film at low negative potential and Fe3+/Fe2+ couple at moderate positive potential were observed. Cyclability of an aqueous TiO2/Fe2+ hybrid battery is demonstrated with a voltage of 1.7 V.

The South China Sea (SCS) is the largest marginal sea in the northwest Pacific Ocean. In this study, deep circulation in the SCS is investigated using results from eddy-resolving, regional simulations using the Hybrid Coordinate Ocean Model (HYCOM) verified by continuous current-meter observations. Analysis of these results provides a detailed spatial structure and temporal variability of the deep circulation in the SCS. The major features of the SCS deep circulation are a basin-scale cyclonic gyre and a concentrated deep western boundary current (DWBC). Transport of the DWBC is ∼ 2 Sv at 16.5° N with a width of ∼53 km. Flowing southwestward, the narrow DWBC becomes weaker with a wider range. The model results reveal the existence of 80- to 120-day oscillation in the deep northeastern circulation and the DWBC, which are also the areas with elevated eddy kinetic energy. This intraseasonal oscillation propagates northwestward with a velocity amplitude of ∼ 1.0 to 1.5 cm s-1. The distribution of mixing parameters in the deep SCS plays a role in both spatial structure and volume transport of the deep circulation. Compared with the northern shelf of the SCS with the Luzon Strait, deep circulation in the SCS is more sensitive to the large vertical mixing parameters of the Zhongsha Island Chain area.

Various dismutative structures of the form [E(EX)(EX2)]2 with E being C, Si, and/or Ge and X being some side group (H, CH3, F, or Cl) were studied with the special purpose of identifying signals for aromaticity in those compounds. Also a dismutative analogue of pyridine was studied. In order to identify signals of aromaticity we focused on the total energy, the HOMO–LUMO energy gap, the variation of the nearest-neighbour bond lengths along the backbone, and NICS and NICSzz as functions of the distance along a normal to a plane of the molecule. In many cases, strong distortions from a nearly-planar structure were observed. Only in few cases, the bond lengths could suggest the existence of aromaticity or anti-aromaticity. On the other hand, in many cases NICS and NICSzz give signals that suggest the existence of aromaticity similar to that of spherical cluster compounds.

The utilization of intermittent renewable energy sources needs low-cost, reliable energy storage systems in the future. Among various electrochemical energy storage systems, redox flow batteries (RFBs) are promising with merits of independent energy storage and power generation capability, localization flexibility, high efficiency, low scaling-up cost, and excellent long charge/discharge cycle life. RFBs typically use metal ions as reacting species. The most exploited types are all-vanadium RFBs (VRFBs). Here, we discuss the core components for the VRFBs, including the development and application of different types of membranes, electrode materials, and stack system. In addition, we introduce the recent progress in the discovery of novel electrolytes, such as redox-active organic compounds, polymers, and organic/inorganic suspensions. Versatile structures, tunable properties, and abundant resources of organic-based electrolytes make them suitable for cost-effective stationary applications. With the active species in solid form, suspension electrolytes are expected to provide enhanced volumetric energy densities.